LAMPIRAN A TABEL DATA PENGUJIAN TRUE DENSITY, POROSITAS, BULK DENSITY, FLUX DENSITY, DAN PERMEABILITAS

L-1

LAMPIRAN A

TABEL DATA PENGUJIAN TRUE DENSITY, POROSITAS, BULK DENSITY, FLUX DENSITY, DAN PERMEABILITAS

Universitas Sumatera Utara

Tabel L.1 Data true density serbuk Ba-ferrite digiling selama 0, 12,24, dan 48 jam, dan true density Ba-ferrite dengan penambahan B2O3 sebanyak 0, 0.2, 0.5, 1.0, dan 2.0 % berat digiling selama 48 jam. True Density (g/cm3)

Waktu Milling (jam)

0%

0

4.37

12

4.40

24

4.71

48

4.76

0.5 %

1.0 %

2.0 %

4.82

4.89

4.97

Tabel L.2 Nilai porositas dari bahan magnet Ba-ferrite dengan penambahan B2O3 sebanyak 0, 0.5, 1.0, dan 2.0 % berat digiling selama 48 jam yang disinter pada suhu: 1100, 1150, dan 1200oC porosity

B2O3 ( % berat)

1100oC

1150oC

1200oC

0

7.5

6.8

7.5

0.5

5.0

5.2

5.7

1

8.2

7.7

7.8

2

8.7

7.6

8.8

Tabel L.3 Nilai

bulk density dari

bahan

magnet

Ba-ferrite

dengan

penambahan B2O3 sebanyak 0, 0.2, 0.5, 1.0, dan 2.0 % berat digiling selama 48 jam yang disinter pada suhu: 1100, 1150, dan 1200oC. B2O3 ( % berat)

Bulk Density (g/cm3) 1100oC 1150oC 1200oC 4.63 4.56 4.55

0

4.76

0.5

4.82

4.86

4.63

4.66

1

4.89

4.66

4.62

4.65

2

4.97

4.57

4.57

4.60


Tabel L.4 Data Flux density magnetic dari bahan magnet Ba-ferrite dengan penambahan B2O3 sebanyak 0, 0.2, 0.5, 1.0, dan 2.0 % berat digiling selama 48 jam yang disinter pada suhu: 1100, 1150, dan 1200oC, masing-masing ditahan selama 1 jam. Flux Density (Gauss) B2O3 o ( % berat) 1100 C 1150oC 1200oC 0 798.5 603.2 714 0.5 832.5 618.3 723.1 1 699.6 598.1 622.8 2 604.2 463.9 439.9 Tabel L.5 Data perbandingan permeabilitas dan susespbilitas bahan Barium heksaferit. Komposisi BaFe12O19

Br (kG) 2.26

BaFe12O19 + B2O3 (0 % berat)

H

CB

(kOe)

µ Br/H m(

CB)

2.9

0.77

1,63

2.18

2.85

0.76

1,65

BaFe12O19 + B2O3 (0.5 % berat)

2.28

2.43

0.93

1,35

BaFe O + B O (1.0 % berat)

1.87

2.8

0.66

1,90

BaFe12O19 + B2O3 (2.0 % berat)

1.64

2.11

0.77

1,63

12

19

2

3

dimana μo = 1,256 G.cm/A


L-2

LAMPIRAN B

HASIL PENGUJIAN MAGNETIK DENGAN MENGGUNAKAN PERMAGRAPH


LEMBAGA ILMU PENGETAHUAN INDONESIA

PUSAT PENELITIAN FISIKA

RESEARCH CENTER FOR PHISICS – INDONESIA INSTITUTE OF SCIENCES KAWASAN PUSPITEK SERPONG TANGERANG 15314 Tel. (021) 7560570 = 750556 JALAN SANGKURIANG KOMPLEKS LIPI BANDUNG 40135 No telp (022) 2504832 e-mail : [email protected] http//www.fisika.lipi.go.id


















L-2

LAMPIRAN C HASIL PENGUJIAN MIKROSTRUKTUR MENGGUNAKAN SCANNING ELECTRON MICROSCOPE (SEM)-EDX





Sampel

BaFe12O19

Keterangan

Komersil CHINA (serbuk)

Operator

Dr. Toto Sudiro

Pembesaran

4000 x





Sampel

BaFe12O19 Komersil CHINA milling 48 jam

Keterangan (serbuk) Operator

Dr. Toto Sudiro

Pembesaran

4000 x





Sampel

BaFe12O19 Komersil CHINA + B2O3 milling 48 jam

Keterangan (serbuk) Operator

Dr. Toto Sudiro

Pembesaran

4000 x





Sampel

BaFe12O19

Keterangan

Komersil CHINA (pelet)

Operator

Dr. Toto Sudiro

Pembesaran

1000 x





Sampel

BaFe12O19 Komersil CHINA milling 48 jam

Keterangan (pelet) Operator

Dr. Toto Sudiro

Pembesaran

4000 x





Sampel

BaFe12O19 Komersil CHINA + B2O3 milling 48

Keterangan jam (pelet) Operator

Dr. Toto Sudiro

Pembesaran

4000 x





Sampel

BaFe12O19

Keterangan

EDX Komersil CHINA (Serbuk)

Operator

Dr. Toto Sudiro

Pembesaran

4000 x









Sampel

BaFe12O19 EDX Komersil CHINA milling 48

Keterangan jam (serbuk) Operator

Dr. Toto Sudiro

Pembesaran

4000 x









Sampel

BaFe12O19 EDX Komersil CHINA + B2O3

Keterangan milling 48 jam (serbuk) Operator

Dr. Toto Sudiro

Pembesaran

4000 x










L-4

LAMPIRAN D

HASIL PENGUJIAN PARTICLE SIZE ANALYSIS (PSA)


Barium hexaferrite original

Element

Line

App. Conc

O

K_SERIES

57.58

Fe

K_SERIES

69.98

Sr

L_SERIES

1

Ba

L_SERIES

14

Totals

Element O Fe Sr Ba

Line K_SERIE S K_SERIE S L_SERIE S L_SERIE S Totals

k ratio 0.206 68 0.699 83 0.009 27 0.130 65

sp4 Intensity corrn.

Weight %

Weight% sigma

Atomic%

1.6118

28.05

0.12

60.24

0.9296

59.09

0.14

36.36

0.6163

1.27

0.08

0.5

0.9479

11.59

0.1

2.9

Standard SiO2 1-Jun-1999 12:00 AM Fe 1-Jun-1999 12:00 AM SrF2 1-Jun-1999 12:00 AM BaF2 1-Jun-1999 12:00 AM

100 Barium hexaferrite original millig 48 jam

App. Conc 50,29 65,01 0,94 12,79

k ratio 0,1804 9 0,6500 9 0,0087 2 0,1193 7

Sp8 Intensity corrn.

Weight %

Weight% sigma

Atomic %

1,6015

27,04

0,13

58,99

0,9318

60,06

0,15

37,54

0,6152

1,31

0,09

0,52

0,9502

11,59

0,11

2,94


100 Barium hexaferrite original milling 48 jam + B2O3

Element O Fe Sr Ba Totals

Line K_SERIE S K_SERIE S L_SERIE S L_SERIE S

App. Conc 81,62 83,37 1,88 12,71

k ratio 0,2929 2 0,8337 3 0,0174 4 0,1186 9

Sp4 Intensity corrn.

Weight %

Weight% sigma

Atomic %

1,6195

32,06

0,11

64,3

0,9234

57,43

0,13

32,99

0,6257

1,91

0,08

0,7

0,941

8,59

0,09

2,01


100
















L-4

LAMPIRAN E HASIL PENGUJIAN X-RAY DIFRACTION (XRD) DAN MATCH REPORT


Match! Phase Analysis Report Sample: C-cina_Theta_2-Theta Sample Data File name File path Data collected Data range Number of points Step size Rietveld refinement converged Alpha2 subtracted Background subtr. Data smoothed 2theta correction Radiation Wavelength

C-cina_Theta_2-Theta.rd D:/punya dol/TESIS DELOVITA USU 4-6-2014/DATA PENGUJIAN TESIS DELOVITA 20-5-2014/DATA XRD DELOVITA/CHINA ORIGIN Jul 7, 2014 02:15:40 9.930º - 79.930º 3501 0.020 No Yes Yes Yes -0.07º X-rays 1.540598 Å

Matched Phases Index Amount (%) Name A 100.0 Barium dodecairon(III) oxide 103.5 Unidentified peak area

Formula sum Ba Fe12 O19

A: Barium dodecairon(III) oxide

(100.0 %) Formula sum Entry number Figure-of-Merit (FoM) Total number of peaks Peaks in range Peaks matched Intensity scale factor Space group Crystal system Unit cell I/Icor Calc. density Reference

Ba Fe12 O19 96-100-9039 0.742763 186 185 82 1.02 P 63/m m c hexagonal a= 5.8890 Å c= 23.1820 Å 4.27 3.850 g/cm³ Bertaut F, Deschamps A, Pauthenet R, "Etude de la substitution de Fe par Al, Ga et Cr dans l'hexaferrite de baryum, Ba O, (Fe2 O3)6", Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences (1884 - 1965) 246, 2594-2597 (1958)

Candidates Name Barium dodecairon(III) oxide

Formula Ba Fe12 O19

Entry No. 96-100-9039

FoM 0.7194

Search-Match Settings Reference database used COD-Inorg REV107951 2014.03.25 Automatic zeropoint adaptation Yes Minimum figure-of-merit (FoM) 0.60 Parameter/influence 2theta 0.50 Parameter/influence intensities 0.50 Parameter multiple/single phase(s) 0.50

Selection Criteria Elements: Elements that must be present: Elements that must NOT be present:

O, Fe, Ba All elements not mentioned above

Crystal structure data: Entries containing full crystal structure data only

Peak List No. 2theta [º] 1 13.75 2 13.89 3 14.29 4 14.49 5 14.62 6 14.82 7 14.90 8 15.23 9 15.35 10 15.53 11 15.76 12 16.06 13 16.18 14 16.37 15 16.60

d [Å] 6.4368 6.3693 6.1942 6.1088 6.0538 5.9747 5.9389 5.8121 5.7687 5.7024 5.6183 5.5155 5.4723 5.4108 5.3363

I/I0 236.83 228.34 256.57 228.11 245.21 258.59 303.21 260.90 286.39 266.29 320.62 257.54 282.90 287.03 315.35

FWHM Matched 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 A 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200


16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106

16.73 16.92 17.07 17.19 17.40 17.57 17.67 17.83 17.95 18.16 18.31 18.41 18.61 18.72 18.94 19.14 19.35 19.55 19.69 19.81 20.00 20.15 20.35 20.49 20.69 20.89 21.08 21.28 21.47 21.63 21.73 21.92 22.02 22.19 22.30 22.47 22.58 22.99 23.34 23.52 23.71 23.86 24.06 24.23 24.39 24.57 24.76 24.87 25.17 25.39 25.60 25.78 25.92 26.11 26.22 26.37 26.51 26.72 26.92 27.14 27.44 27.54 27.71 27.84 28.06 28.22 28.33 28.46 28.64 28.79 29.01 29.25 29.52 29.82 30.24 30.37 30.56 30.81 31.02 31.13 31.31 31.50 31.64 31.84 32.17 32.48 32.66 32.85 33.03 33.23 33.40

5.2936 5.2366 5.1911 5.1544 5.0933 5.0433 5.0148 4.9715 4.9389 4.8824 4.8424 4.8162 4.7637 4.7375 4.6817 4.6325 4.5827 4.5375 4.5044 4.4782 4.4354 4.4033 4.3614 4.3309 4.2895 4.2483 4.2116 4.1711 4.1347 4.1057 4.0866 4.0518 4.0330 4.0021 3.9827 3.9536 3.9338 3.8659 3.8085 3.7801 3.7499 3.7267 3.6961 3.6703 3.6463 3.6202 3.5924 3.5769 3.5352 3.5058 3.4764 3.4524 3.4352 3.4101 3.3961 3.3765 3.3593 3.3341 3.3099 3.2828 3.2483 3.2363 3.2171 3.2016 3.1776 3.1597 3.1473 3.1334 3.1146 3.0987 3.0752 3.0507 3.0238 2.9940 2.9528 2.9410 2.9229 2.9001 2.8804 2.8710 2.8545 2.8374 2.8259 2.8084 2.7799 2.7547 2.7397 2.7243 2.7097 2.6938 2.6809

253.21 315.71 337.24 327.31 378.83 363.08 358.96 353.42 354.90 312.34 324.57 352.94 385.33 414.36 447.43 371.35 415.42 395.78 440.09 378.72 434.53 432.99 478.00 433.39 486.36 423.05 381.46 400.85 428.54 380.02 390.59 395.65 354.78 388.16 386.49 479.16 452.22 654.10 453.14 398.16 407.05 389.34 350.97 377.01 322.24 414.40 374.76 375.21 366.29 340.45 378.00 368.38 319.81 279.22 324.45 295.74 305.02 316.78 325.71 321.51 294.37 299.29 317.32 282.10 294.11 289.79 257.32 297.46 320.73 281.48 295.86 312.26 292.50 301.25 441.49 591.68 353.19 583.66 361.58 285.30 346.45 315.08 268.94 309.28 1000.00 358.94 320.23 228.45 267.29 290.04 283.56

0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200

A A

A

A

A A

A

A

A A A

A


107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153

33.55 33.71 34.11 34.53 34.71 35.01 35.21 35.44 35.63 35.83 35.93 36.74 36.89 37.10 37.30 38.00 38.36 38.78 39.04 39.66 40.19 40.39 41.79 42.05 42.25 42.44 47.07 47.52 49.35 50.09 54.74 55.02 55.30 55.45 56.30 56.45 56.63 56.82 57.23 57.51 62.66 62.90 63.03 63.15 65.54 72.49 72.81

2.6693 2.6569 2.6268 2.5954 2.5822 2.5609 2.5465 2.5305 2.5181 2.5039 2.4971 2.4445 2.4344 2.4210 2.4090 2.3661 2.3446 2.3202 2.3051 2.2708 2.2420 2.2314 2.1596 2.1471 2.1372 2.1282 1.9292 1.9119 1.8450 1.8196 1.6756 1.6675 1.6598 1.6556 1.6328 1.6288 1.6239 1.6190 1.6084 1.6012 1.4815 1.4764 1.4736 1.4711 1.4232 1.3029 1.2979

284.46 286.28 741.28 272.56 254.89 317.40 339.85 287.36 272.47 255.46 262.06 232.03 271.01 423.72 261.89 231.92 262.78 252.67 229.44 280.47 245.67 293.59 255.69 226.22 243.40 296.31 240.37 235.75 234.82 243.87 248.17 369.10 312.14 245.93 270.34 304.97 401.42 257.16 247.46 255.32 233.15 245.57 266.54 237.57 236.45 227.90 234.64

0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200 0.9200

A

A A A A A A A A A

A A A A A A A A A A A A A A A A A A A

Rietveld Refinement using FullProf Calculation was not run or did not converge.

Integrated Profile Areas Based on calculated profile Profile area Overall diffraction profile Background radiation Diffraction peaks Peak area belonging to selected phases Unidentified peak area

Counts 122222 36071 86151 86151 126529

Amount 100.00% 29.51% 70.49% 70.49% 103.52%

Peak Residuals Peak data Overall peak intensity Peak intensity belonging to selected phases Unidentified peak intensity

Counts 17751 2025 15727

Amount 100.00% 11.41% 88.59%



Match! Phase Analysis Report Sample: BaFeO-milled 48 h Sample Data File name File path Data collected Data range Number of points Step size Rietveld refinement converged Alpha2 subtracted Background subtr. Data smoothed 2theta correction Radiation Wavelength

BaFeO-milled 48 h.ras G:/TESIS DELOVITA USU 4-6-2014/DATA PENGUJIAN TESIS DELOVITA 20-5-2014/DATA XRD DELOVITA/CHINA MILLING 48 JAM HEM Jun 4, 2014 13:49:46 10.120º - 80.085º 3501 0.020 No Yes No Yes 0.12º X-rays 1.540598 Å

Matched Phases Index Amount (%) A 58.0 B 42.0 20.1

Name Barium dodecairon(III) oxide Hematite Unidentified peak area

Formula sum Ba Fe12 O19 Fe2 O3


(58.0 %) Formula sum Entry number Figure-of-Merit (FoM) Total number of peaks Peaks in range Peaks matched Intensity scale factor Space group Crystal system Unit cell I/Icor Calc. density Reference B: Hematite (42.0 %) Formula sum Entry number Figure-of-Merit (FoM) Total number of peaks Peaks in range Peaks matched Intensity scale factor Space group Crystal system Unit cell I/Icor Calc. density Reference

Ba Fe12 O19 96-100-9039 0.776425 186 114 61 1.39 P 63/m m c hexagonal a= 5.8890 Å c= 23.1820 Å 4.27 3.850 g/cm³ Bertaut F, Deschamps A, Pauthenet R, "Etude de la substitution de Fe par Al, Ga et Cr dans l'hexaferrite de baryum, Ba O, (Fe2 O3)6", Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences (1884 - 1965) 246, 2594-2597 (1958) Fe2 O3 96-900-9783 0.661775 33 19 14 0.83 R -3 c rhombohedral a= 5.4200 Å α= 55.280º 3.58 5.291 g/cm³ Pauling L., Hendricks S. B., "Crystal structures of hematite and corundum", Journal of the American Chemical Society 47, 781-790 (1925)

Candidates Name Magnetite Magnetite Hematite Goethite Goethite Goethite Magnetite Fe3O4 Wuestite Goethite Goethite Lepidocrocite Hematite Magnetite Magnetite Iron(III) oxide - $-alpha (Hematite) Magnetite Hematite Lepidocrocite Magnetite Magnetite Magnetite Iron diiron(III) oxide (Magnetite) Iron(III) oxide (Hematite) Hematite

Formula Fe3 O4 Fe3 O4 Fe4 O5 Fe2 O3 Fe O2 Fe O2 Fe O2 Fe3 O4 Fe3 O4 Fe4 O5 Fe0.99 O Fe O2 Fe O2 Fe O2 Fe2 O3 Fe3 O4 Fe3 O4 Fe2 O3 Fe3 O4 Fe2 O3 Fe O2 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe2 O3 Fe2 O3

Entry No. 96-900-5840 96-900-2319 96-901-4244 96-901-5504 96-901-5697 96-901-1413 96-901-6179 96-900-2321 96-900-2027 96-901-4236 96-900-2671 96-901-6407 96-901-6060 96-901-5157 96-901-6458 96-900-2322 96-901-0942 96-591-0083 96-900-2323 96-900-0140 96-901-5232 96-900-5816 96-901-0941 96-900-5817 96-101-1033 96-101-1268 96-901-4881

FoM 0.7578 0.7531 0.7445 0.7431 0.7414 0.7397 0.7384 0.7349 0.7283 0.7259 0.7258 0.7218 0.7217 0.7150 0.7147 0.7133 0.7109 0.7109 0.7102 0.7078 0.7063 0.7043 0.7043 0.7042 0.7037 0.6968 0.6951


Fe2 O3 Fe2 O3 Fe2 O3 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe2 O3 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4 Fe3 O4

iron oxide Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite Iron(III) oxide (Hematite) Magnetite Magnetite Magnetite Magnetite Magnetite Magnetite and 26 others...

96-210-1168 96-210-1169 96-210-1170 96-151-3305 96-210-1927 96-900-2324 96-900-5839 96-900-7707 96-900-6190 96-900-6195 96-900-6200 96-900-6185 96-900-6243 96-900-6253 96-900-6266 96-901-3530 96-900-2317 96-900-0927 96-101-1241 96-901-0940 96-900-5837 96-900-7645 96-900-6921 96-900-5841 96-900-5814

0.6919 0.6919 0.6919 0.6891 0.6883 0.6876 0.6876 0.6873 0.6872 0.6872 0.6872 0.6871 0.6871 0.6871 0.6871 0.6870 0.6868 0.6855 0.6853 0.6846 0.6844 0.6838 0.6837 0.6832 0.6824



O, Fe All elements not mentioned above

Peak List No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42

2theta [º] 12.98 13.36 13.81 14.02 14.11 14.23 14.41 14.60 14.68 14.87 15.08 15.22 15.49 15.72 15.82 15.96 16.09 16.21 16.41 16.57 16.74 16.87 17.06 17.25 17.32 17.44 17.59 17.86 17.98 18.06 18.35 18.56 18.63 18.75 19.01 19.10 19.29 19.61 19.72 19.92 20.05 20.17

d [Å] 6.8130 6.6218 6.4093 6.3098 6.2709 6.2200 6.1413 6.0632 6.0292 5.9517 5.8688 5.8158 5.7144 5.6330 5.5963 5.5479 5.5047 5.4633 5.3981 5.3449 5.2925 5.2509 5.1939 5.1357 5.1151 5.0803 5.0368 4.9638 4.9298 4.9067 4.8322 4.7762 4.7597 4.7278 4.6635 4.6432 4.5967 4.5233 4.4992 4.4544 4.4254 4.3981

I/I0 298.60 305.96 309.31 331.46 388.69 342.89 401.03 326.97 364.16 358.03 442.25 434.46 448.67 506.46 468.11 463.83 511.66 510.81 531.08 440.15 534.97 538.93 594.97 540.07 569.63 545.32 614.65 695.91 608.01 670.45 682.31 678.36 728.40 714.69 796.76 770.12 697.74 780.52 815.71 838.75 776.02 861.07

FWHM Matched 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600


43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133

20.37 20.59 20.75 21.05 21.18 21.30 21.46 21.58 21.71 21.81 22.03 22.22 22.34 22.53 22.65 22.88 22.99 23.16 23.32 23.45 23.60 23.83 23.93 24.12 24.29 24.49 24.71 24.88 24.99 25.19 25.42 25.61 25.81 26.00 26.14 26.33 26.52 26.75 27.02 27.15 27.35 27.57 27.75 27.89 28.00 28.17 28.31 28.51 28.69 28.90 29.19 29.35 29.54 29.73 29.97 30.15 30.26 30.44 30.63 30.84 30.96 31.16 31.43 31.55 31.74 31.90 32.23 32.32 32.47 32.67 32.95 33.15 33.32 33.44 33.66 33.88 34.21 34.55 34.75 34.87 35.14 35.30 35.43 35.55 35.69 35.89 36.13 36.41 36.70 36.88 37.05

4.3558 4.3105 4.2781 4.2171 4.1920 4.1690 4.1379 4.1153 4.0896 4.0710 4.0309 3.9971 3.9772 3.9437 3.9218 3.8843 3.8653 3.8370 3.8112 3.7908 3.7674 3.7316 3.7150 3.6873 3.6616 3.6315 3.6005 3.5758 3.5602 3.5326 3.5015 3.4760 3.4486 3.4239 3.4067 3.3816 3.3586 3.3294 3.2974 3.2816 3.2579 3.2331 3.2117 3.1964 3.1837 3.1656 3.1500 3.1278 3.1087 3.0865 3.0573 3.0409 3.0220 3.0030 2.9793 2.9621 2.9510 2.9342 2.9162 2.8969 2.8859 2.8681 2.8438 2.8334 2.8171 2.8032 2.7752 2.7676 2.7551 2.7389 2.7160 2.7004 2.6872 2.6772 2.6601 2.6440 2.6191 2.5941 2.5798 2.5708 2.5516 2.5406 2.5315 2.5231 2.5136 2.5001 2.4842 2.4654 2.4468 2.4351 2.4245

811.80 825.78 804.29 835.05 755.15 805.57 803.18 813.37 830.37 818.91 805.31 824.34 802.86 724.86 807.47 755.14 827.83 744.30 778.60 710.89 751.39 709.07 706.56 776.17 714.02 754.90 772.85 700.54 728.99 735.40 795.55 630.98 777.18 600.19 694.61 706.90 714.56 649.08 680.98 675.53 675.47 617.91 590.29 695.20 645.24 569.65 591.73 610.35 630.31 623.02 678.06 552.26 654.81 631.89 642.40 665.22 794.44 757.12 732.07 694.75 701.00 606.40 641.84 602.79 512.75 604.42 947.54 913.18 819.05 558.83 552.57 584.64 514.40 560.41 539.08 602.82 1000.00 550.41 495.18 566.87 566.72 674.17 627.99 697.24 667.44 549.23 520.39 457.19 476.89 527.79 515.49

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A

A A

B

A

A

A A A

A

B

A

A A A B A

Universitas Sumatera Utara A

134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207

37.20 37.45 37.70 37.89 38.13 38.37 38.54 38.75 38.94 39.13 39.33 39.52 39.69 39.89 40.02 40.34 40.56 40.86 41.11 41.37 41.58 41.79 42.00 42.18 42.35 42.54 42.73 42.86 43.02 43.18 43.53 43.75 44.11 44.41 44.69 44.93 45.16 45.41 45.64 46.37 46.74 46.99 47.68 49.71 49.95 50.15 50.41 50.67 51.27 52.30 52.50 53.26 53.99 54.29 54.60 54.82 55.13 55.38 55.89 56.10 56.39 56.62 56.90 57.26 57.91 58.71 62.82 63.04 63.23 63.58 69.00 69.93 72.66 77.60

2.4153 2.3997 2.3842 2.3723 2.3584 2.3442 2.3342 2.3219 2.3113 2.3002 2.2892 2.2783 2.2691 2.2581 2.2513 2.2340 2.2226 2.2070 2.1937 2.1809 2.1704 2.1596 2.1493 2.1407 2.1324 2.1233 2.1145 2.1082 2.1010 2.0932 2.0773 2.0674 2.0513 2.0383 2.0262 2.0160 2.0062 1.9957 1.9860 1.9565 1.9421 1.9322 1.9060 1.8327 1.8242 1.8175 1.8087 1.8001 1.7803 1.7479 1.7418 1.7184 1.6970 1.6883 1.6795 1.6732 1.6646 1.6576 1.6439 1.6381 1.6305 1.6241 1.6169 1.6077 1.5911 1.5712 1.4780 1.4735 1.4694 1.4623 1.3600 1.3442 1.3003 1.2293

691.88 447.61 472.55 390.64 471.21 456.55 433.93 361.42 482.98 406.67 410.79 409.94 375.32 401.07 374.86 512.86 434.00 418.78 431.88 422.30 459.78 361.24 358.70 312.37 466.88 367.04 369.97 337.21 381.62 321.09 416.66 390.58 329.46 331.88 302.20 326.77 391.74 374.59 334.24 361.61 379.22 357.86 316.79 304.34 358.71 302.94 314.00 301.41 293.14 317.18 300.50 403.74 400.60 376.81 318.12 361.83 414.67 357.62 300.82 357.86 456.20 424.80 415.08 372.59 315.18 305.05 358.47 310.96 442.02 322.15 302.94 295.44 341.28 300.06

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A A A A B

A B

A A B A

A A A A,B A A A A A B A A A B A A A A,B B A A,B A A A A B A,B A



Counts 1035440 802350 233090 24788 208302

Amount 100.00% 77.49% 22.51% 2.39% 20.12%




Match! Phase Analysis Report Sample: BAFe-0,5% Sample Data File name File path Data collected Data range Number of points Step size Rietveld refinement converged Alpha2 subtracted Background subtr. Data smoothed 2theta correction Radiation Wavelength

BAFe-0,5%.ras G:/tesis/PENGUJIAN DAN KARAKTERISASI/DATA XRD DELOVITA/delovita Jun 16, 2014 09:09:57 10.000º - 79.965º 3501 0.020 No No No Yes 0.11º X-rays 1.540598 Å

Matched Phases Index Amount (%) A 48.9 B 26.8 C 24.3 20.6

Name Barium dodecairon(III) oxide Hematite Unidentified peak area

Formula sum Ba Fe12 O19 Fe2 O3 B2 Ba O4



Ba Fe12 O19

96-100-8329 0.776402

186 107 66 1.35 P 63/m m c hexagonal a= 5.8650 Å c= 23.0990 Å

2.88 5.363 g/cm³ Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~-

W", Journal of Magnetism and Magnetic Materials 62, 57-67 (1986) B: Hematite (26.8 %) Formula sum Entry number Figure-of-Merit (FoM) Total number of peaks Peaks in range Peaks matched Intensity scale factor Space group Crystal system Unit cell I/Icor Calc. density Reference

Fe2 O3

96-901-5066 0.739597 34 19 13 1.04 R -3 c trigonal (hexagonal axes) a= 5.0249 Å c= 13.7163 Å

4.01 5.304 g/cm³ Finger L. W., Hazen R. M., "Crystal structure and isothermal compression of Fe2O3, Cr2O3, and V2O3 to 50 kbars Note: P = 15.4 kbar",

Journal of Applied Physics 51, 5362-5367 (1980) C: B2 Ba O4 (24.3 %) Formula sum Entry number Figure-of-Merit (FoM) Total number of peaks Peaks in range Peaks matched Intensity scale factor Space group Crystal system Unit cell I/Icor Calc. density Color

88 65 1.43 R3c

Reference

Pan Shilie, Smit Jared P., Lanier Courtney H., Marvel Michael R., Marks Laurence D., Poeppelmeier Kenneth R., "Optical Floating Zone

B2 Ba O4

96-450-4286 0.760421

163

rhombohedral a= 8.3824 Å α= 96.860º

6.09 3.862 g/cm³

colorless Growth of \b-BaB2O4from a LiBa2B5O10-Based Solvent", 7(8), 1561 (2007)



Selection Crit

eria


Elements: Elements that must be present: Elements that must NOT be present:

O, Fe All elements not mentioned above

Peak List No. 2theta [º] 1 21.52 2 21.79 3 21.97 4 22.14 5 22.33 6 22.50 7 22.61 8 22.79 9 22.91 10 23.10 11 23.34 12 23.44 13 23.67 14 23.85 15 23.98 16 24.09 17 24.26 18 24.56 19 24.75 20 24.88 21 25.06 22 25.17 23 25.29 24 25.50 25 25.60 26 25.83 27 26.01 28 26.14 29 26.34 30 26.47 31 26.58 32 26.68 33 26.86 34 27.02 35 27.22 36 27.39 37 27.63 38 27.74 39 27.91 40 28.12 41 28.23 42 28.42 43 28.56 44 28.70 45 28.87 46 29.12 47 29.28 48 29.68 49 29.88 50 30.05 51 30.22 52 30.40 53 30.55 54 30.70 55 30.94 56 31.04 57 31.25 58 31.43 59 31.56 60 31.72 61 31.92 62 32.13 63 32.31 64 32.48 65 32.69 66 33.00 67 33.24 68 33.42 69 33.57 70 33.75 71 34.02 72 34.21 73 34.44 74 34.65 75 34.88 76 35.15 77 35.35 78 35.49 79 35.67 80 35.88 81 36.06

d [Å] 4.1259 4.0760 4.0433 4.0120 3.9787 3.9492 3.9294 3.8993 3.8782 3.8473 3.8084 3.7920 3.7560 3.7285 3.7073 3.6914 3.6657 3.6217 3.5941 3.5762 3.5508 3.5354 3.5183 3.4897 3.4763 3.4459 3.4225 3.4058 3.3815 3.3640 3.3514 3.3383 3.3168 3.2968 3.2732 3.2534 3.2263 3.2134 3.1944 3.1708 3.1589 3.1376 3.1232 3.1076 3.0905 3.0636 3.0481 3.0077 2.9884 2.9717 2.9549 2.9375 2.9235 2.9102 2.8879 2.8785 2.8602 2.8436 2.8322 2.8186 2.8017 2.7837 2.7682 2.7542 2.7371 2.7121 2.6934 2.6793 2.6675 2.6538 2.6328 2.6193 2.6020 2.5867 2.5704 2.5512 2.5373 2.5272 2.5150 2.5011 2.4888

I/I0 437.85 505.07 440.14 516.14 462.32 462.18 462.94 494.54 561.78 557.19 625.46 515.60 504.52 456.93 495.01 485.89 493.14 526.07 536.02 518.02 509.09 570.27 466.51 493.06 516.01 602.06 528.76 483.69 553.55 566.77 499.81 506.84 563.89 639.32 555.68 562.77 604.93 570.89 513.34 554.27 615.01 542.04 531.05 590.88 554.57 627.95 585.11 586.02 614.87 645.40 612.50 649.97 603.53 651.34 642.90 729.57 674.44 658.62 746.51 652.14 818.73 807.35 686.86 743.07 740.94 756.79 722.56 750.23 620.68 1000.00 834.62 897.97 851.57 866.08 780.01 796.02 744.61 597.88 695.80 690.30 686.87

FWHM Matched 0.1600 C 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 C 0.1600 0.1600 A 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 B 0.1600 C 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 C 0.1600 0.1600 C 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 C 0.1600 0.1600 0.1600 0.1600 A 0.1600 C 0.1600 0.1600 0.1600 0.1600 0.1600 A,C 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 A 0.1600 0.1600 C 0.1600 C 0.1600 B 0.1600 0.1600 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 0.1600 0.1600 A 0.1600 A 0.1600 A,B 0.1600 C 0.1600


82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172

36.25 36.44 36.65 36.92 37.03 37.25 37.54 37.73 37.86 37.99 38.16 38.28 38.54 38.80 38.97 39.15 39.30 39.53 39.69 39.85 40.07 40.32 40.45 40.64 40.85 40.98 41.24 41.37 41.55 41.73 41.89 42.09 42.26 42.44 42.71 43.02 43.20 43.41 43.59 43.81 43.99 44.20 44.41 44.60 44.79 44.98 45.12 45.28 45.44 45.72 45.91 46.19 46.42 46.62 46.83 47.03 47.24 47.51 47.78 47.98 48.22 48.53 48.66 48.81 48.93 49.11 49.38 49.55 49.78 49.96 50.16 50.29 50.47 50.73 50.99 51.23 51.43 51.55 51.78 52.04 52.21 52.47 52.77 52.94 53.05 53.23 53.51 53.78 53.98 54.27 54.50

2.4760 2.4635 2.4502 2.4330 2.4259 2.4118 2.3939 2.3824 2.3745 2.3667 2.3567 2.3493 2.3340 2.3191 2.3094 2.2990 2.2906 2.2781 2.2691 2.2603 2.2485 2.2351 2.2282 2.2184 2.2074 2.2006 2.1871 2.1806 2.1716 2.1626 2.1547 2.1449 2.1369 2.1280 2.1153 2.1009 2.0926 2.0827 2.0747 2.0646 2.0567 2.0473 2.0384 2.0300 2.0220 2.0137 2.0080 2.0010 1.9946 1.9828 1.9752 1.9639 1.9547 1.9466 1.9384 1.9307 1.9226 1.9124 1.9021 1.8945 1.8856 1.8744 1.8698 1.8644 1.8601 1.8535 1.8442 1.8380 1.8302 1.8240 1.8172 1.8129 1.8066 1.7981 1.7897 1.7819 1.7752 1.7713 1.7641 1.7560 1.7506 1.7427 1.7334 1.7282 1.7250 1.7194 1.7111 1.7030 1.6974 1.6888 1.6824

735.23 713.03 735.41 705.65 713.28 715.78 693.04 737.61 662.81 682.94 748.33 668.47 836.69 802.59 908.97 741.07 884.68 822.62 892.88 936.81 807.02 761.81 871.46 929.68 726.23 726.54 861.11 701.80 859.93 837.28 903.74 946.26 907.18 934.39 910.15 868.86 929.16 894.66 765.93 881.56 798.11 897.03 960.69 910.45 840.00 891.96 818.68 711.85 880.41 770.71 719.40 806.46 860.90 740.57 876.71 833.30 921.19 801.13 749.95 944.56 875.39 760.68 854.81 736.02 852.86 781.70 801.31 577.81 734.83 671.60 730.69 473.57 765.55 725.97 624.34 760.82 651.68 660.03 846.87 848.25 688.93 727.80 768.87 710.76 682.35 642.71 607.14 704.80 607.36 694.01 549.51

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A C A

C A A,C A A,B

A B C C

A,C A C B C A,C

A C

C A,C C A A A A C A,C

B A,C A,C A A C C A,C C C C A,C A A,B


173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213

54.67 54.79 54.98 55.36 55.60 55.72 55.91 56.01 56.29 56.40 56.61 56.77 56.89 57.05 57.34 57.46 57.67 57.94 58.22 58.51 58.77 59.12 59.64 59.84 60.06 60.32 60.83 61.09 61.36 61.82 62.33 62.69 62.97 63.31 66.27 67.16 67.60 68.63 69.00 73.65 77.20

1.6776 1.6741 1.6687 1.6583 1.6516 1.6483 1.6433 1.6405 1.6330 1.6302 1.6244 1.6204 1.6173 1.6131 1.6056 1.6025 1.5972 1.5903 1.5833 1.5762 1.5699 1.5614 1.5490 1.5444 1.5392 1.5333 1.5215 1.5158 1.5096 1.4994 1.4886 1.4808 1.4748 1.4678 1.4092 1.3927 1.3847 1.3665 1.3600 1.2852 1.2346

500.69 604.11 596.15 622.81 534.52 527.61 489.54 609.25 519.69 565.90 511.15 532.15 500.71 550.50 528.97 437.38 591.13 540.43 574.77 511.70 493.26 459.81 633.92 462.85 530.84 533.80 450.39 556.34 681.02 575.34 650.52 585.33 642.36 573.83 476.53 441.11 464.96 486.39 548.34 447.58 481.51

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A A A,C A A C B A A A,C C A,B C A,C C A,C C A,C A C A,C C B A,C A,C A,B A,C A,C A,C A,C A



Counts 871373 665715 205659 -28275 179924

Amount 100.00% 76.40% 23.60% -3.25% 20.65%


Counts 3886 367 3519

Amount 100.00% 9.45% 90.55%

Diffraction Pattern Graphics


Match! Copyright © 2003-2014 CRYSTAL IMPACT, Bonn, Germany


Match! Phase Analysis Report Sample: BaFe12O19 KOMERSIL (PELET) Sample Data File name File path Data collected Data range Number of points Step size Rietveld refinement converged Alpha2 subtracted Background subtr. Data smoothed 2theta correction Specimen displacement correction Radiation Wavelength

BaFe12O19 KOMERSIL (PELET).ras G:/tesis/PENGUJIAN DAN KARAKTERISASI/DATA XRD DELOVITA/delovita Jun 16, 2014 09:10:01 10.064º - 80.034º 3501 0.020 No Yes No Yes 0.07º T = 0.00005 X-rays 1.540598 Å

Matched Phases Index Amount (%) A 100.0 16.3

Name Barium dodecairon(III) oxide Unidentified peak area




Ba Fe12 O19 96-100-8329 0.781238 186 101 75 0.97 P 63/m m c hexagonal a= 5.8650 Å c= 23.0990 Å 2.88 5.363 g/cm³ Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~W", Journal of Magnetism and Magnetic Materials 62, 57-67 (1986)




Peak List No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24

2theta [º] 23.57 23.63 23.75 31.21 31.44 32.42 32.62 32.89 34.37 34.61 35.83 36.23 37.43 37.81 40.88 43.13 43.74 45.10 45.53 46.57 46.90 47.13 47.47 47.79

d [Å] 3.7718 3.7619 3.7426 2.8636 2.8433 2.7595 2.7431 2.7207 2.6069 2.5894 2.5040 2.4772 2.4006 2.3775 2.2056 2.0957 2.0681 2.0087 1.9906 1.9485 1.9358 1.9268 1.9136 1.9017

I/I0 538.62 505.89 441.46 489.06 820.46 582.08 907.58 731.61 506.11 772.39 452.70 455.24 451.44 436.69 549.38 533.56 482.24 510.68 527.33 516.30 451.28 518.68 521.42 600.76

FWHM Matched 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 A 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 0.1600 A 0.1600 A 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 A 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 A 0.1600 A 0.1600 A


25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115

48.86 49.45 49.94 50.19 50.50 50.74 51.06 51.37 51.63 51.83 52.23 52.51 52.96 53.20 53.41 53.63 53.91 54.28 54.59 54.87 55.13 55.45 55.72 56.01 56.19 56.30 56.40 56.53 56.67 56.81 56.97 57.20 57.55 57.88 57.99 58.41 58.75 59.05 59.37 59.55 59.87 60.16 60.42 60.72 61.30 61.68 61.95 62.22 62.34 62.62 62.88 63.17 63.60 63.91 64.11 64.36 64.56 64.79 65.09 65.48 65.72 66.06 66.23 66.62 66.99 67.41 67.68 67.93 68.21 68.36 68.66 69.02 69.20 69.53 69.77 70.13 70.68 71.01 71.52 71.85 72.27 72.45 72.80 73.13 73.27 73.60 73.76 74.19 74.35 74.54 74.66

1.8626 1.8415 1.8248 1.8161 1.8059 1.7978 1.7873 1.7772 1.7688 1.7626 1.7500 1.7412 1.7275 1.7203 1.7142 1.7075 1.6993 1.6886 1.6796 1.6720 1.6646 1.6558 1.6483 1.6405 1.6357 1.6328 1.6302 1.6266 1.6231 1.6194 1.6150 1.6091 1.6002 1.5919 1.5891 1.5786 1.5704 1.5630 1.5554 1.5511 1.5436 1.5370 1.5310 1.5241 1.5110 1.5025 1.4968 1.4908 1.4884 1.4824 1.4768 1.4708 1.4617 1.4555 1.4515 1.4463 1.4423 1.4379 1.4318 1.4242 1.4197 1.4132 1.4100 1.4027 1.3958 1.3882 1.3833 1.3789 1.3738 1.3711 1.3658 1.3596 1.3565 1.3510 1.3468 1.3409 1.3317 1.3263 1.3182 1.3129 1.3062 1.3034 1.2980 1.2931 1.2909 1.2859 1.2836 1.2772 1.2748 1.2720 1.2703

497.23 441.12 836.35 450.34 593.97 619.30 630.73 455.91 447.12 524.51 756.99 476.84 600.36 476.05 691.82 731.12 471.28 631.54 676.91 918.92 585.22 777.05 812.18 820.39 568.15 572.65 565.88 548.89 693.25 831.16 1000.00 996.73 563.81 559.67 498.64 464.59 778.57 525.65 556.37 572.55 608.91 597.64 513.97 624.11 616.27 575.99 484.00 473.13 455.89 659.64 597.08 710.16 801.50 453.18 465.21 679.25 565.29 517.31 555.06 534.17 552.67 556.18 612.74 474.14 674.35 705.36 585.79 772.07 557.20 632.88 517.99 436.62 679.05 479.84 531.35 748.13 558.83 536.30 568.72 547.38 497.21 569.50 771.78 731.73 471.48 617.18 487.51 549.11 610.64 505.00 736.87

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A A A A A A

A A A A A A A

A A A A

A A A

A

A A A A A A A A A A A A A A A A A A A A A A

A A


116 117 118 119 120 121 122 123

75.09 75.28 75.41 75.52 75.71 75.84 76.01 76.21

1.2641 1.2613 1.2594 1.2579 1.2552 1.2534 1.2510 1.2483

850.27 563.26 617.84 624.51 611.93 502.98 613.32 449.00

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A A A A A



Counts 445822 368911 76910 4136 72774

Amount 100.00% 82.75% 17.25% 0.93% 16.32%


Counts 1070 63 1007

Amount 100.00% 5.93% 94.07%




Match! Phase Analysis Report Sample: BaFe12O19 PELET+B2030 Sample Data File name File path Data collected Data range Number of points Step size Rietveld refinement converged Alpha2 subtracted Background subtr. Data smoothed 2theta correction Radiation Wavelength

BaFe12O19 PELET+B2030.5%.ras G:/tesis/PENGUJIAN DAN KARAKTERISASI/DATA XRD DELOVITA/delovita Jun 16, 2014 09:09:59 10.020º - 79.985º 3501 0.020 No Yes No Yes 0.02º X-rays 1.540598 Å

Matched Phases Index Amount (%) A 100.0 16.6

Name Barium dodecairon(III) oxide Unidentified peak area




Ba Fe12 O19 96-100-8329 0.798248 186 109 73 0.98 P 63/m m c hexagonal a= 5.8650 Å c= 23.0990 Å 2.88 5.363 g/cm³ Collomb A, Wolfers P, Obradors X, "Neutron diffraction studies of some hexagonal ferrites: BaFe~12~O~19~, BaMg~2~-W and BaCo~2~W", Journal of Magnetism and Magnetic Materials 62, 57-67 (1986)

Candidates Name Barioferrite

Formula Ba Fe12 O19

Entry No. 96-900-8138

FoM 0.7860




Peak List No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

2theta [º] 21.68 31.02 32.28 32.43 32.55 34.22 34.37 34.49 37.31 37.51 40.45 42.47 42.96 46.06 46.47 47.15 47.41 47.97 48.45 48.69

d [Å] 4.0958 2.8806 2.7713 2.7582 2.7489 2.6185 2.6069 2.5984 2.4084 2.3960 2.2283 2.1268 2.1035 1.9690 1.9527 1.9260 1.9161 1.8948 1.8773 1.8687

I/I0 377.78 385.79 413.87 545.00 448.71 538.15 553.52 441.41 489.48 422.30 406.88 461.14 389.10 421.49 403.41 361.91 398.26 405.22 414.53 422.52

FWHM Matched 0.1600 0.1600 A 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 0.1600 0.1600 A 0.1600 0.1600 A 0.1600 A 0.1600 A 0.1600 0.1600 A 0.1600 A 0.1600 A 0.1600 A 0.1600 0.1600


21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99

48.95 49.95 50.24 51.05 51.35 51.78 53.05 53.51 53.85 54.08 54.25 54.51 54.96 55.24 55.52 55.64 55.96 56.46 56.69 56.93 57.37 58.14 58.66 58.86 59.18 60.21 60.63 60.96 61.31 61.68 62.17 62.52 62.87 63.23 63.60 63.76 63.96 64.39 64.73 65.51 65.88 66.20 66.51 67.14 67.42 67.54 67.71 68.02 68.31 68.75 69.09 69.38 69.87 70.24 70.50 70.97 71.32 71.67 72.00 72.14 72.46 72.60 72.74 73.06 73.24 73.86 74.03 74.28 74.58 74.88 75.19 75.43 75.58 75.76 76.04 76.65 77.15 77.61 78.03

1.8593 1.8244 1.8145 1.7876 1.7778 1.7642 1.7250 1.7111 1.7010 1.6943 1.6894 1.6821 1.6694 1.6615 1.6539 1.6505 1.6419 1.6284 1.6224 1.6161 1.6047 1.5854 1.5726 1.5677 1.5599 1.5358 1.5261 1.5186 1.5107 1.5026 1.4920 1.4843 1.4769 1.4695 1.4618 1.4585 1.4545 1.4458 1.4390 1.4236 1.4167 1.4105 1.4047 1.3931 1.3880 1.3857 1.3827 1.3772 1.3720 1.3643 1.3584 1.3534 1.3452 1.3389 1.3347 1.3269 1.3214 1.3157 1.3104 1.3083 1.3034 1.3011 1.2990 1.2942 1.2913 1.2820 1.2795 1.2759 1.2714 1.2670 1.2626 1.2592 1.2571 1.2545 1.2507 1.2421 1.2354 1.2291 1.2237

379.00 446.46 367.18 484.80 388.80 501.29 445.10 380.51 433.57 430.48 407.87 391.13 388.26 771.92 502.91 495.10 385.56 538.80 996.70 655.75 451.12 400.54 426.16 450.23 429.48 444.82 418.13 364.15 526.31 523.98 386.05 521.39 541.11 1000.00 381.97 481.40 422.05 399.47 417.86 400.22 407.12 523.44 529.95 497.97 469.08 524.67 391.73 437.48 520.62 525.70 419.56 441.80 491.53 427.84 393.55 397.39 462.57 557.98 507.33 557.26 389.89 550.33 717.45 489.75 399.13 418.38 457.09 416.48 401.19 532.80 500.55 428.99 532.47 440.09 423.14 472.48 424.47 470.53 385.50

0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600 0.1600

A A A A A A A A A A A A A A A A A A

A A A A A A A A A A A A A A A A A A

A A A A A

A A A A A A A A


Integrated Profile Areas Based on calculated profile Profile area Overall diffraction profile Background radiation

Counts 331244 271983

Amount 100.00% 82.11%


Diffraction peaks Peak area belonging to selected phases Unidentified peak area

59260 4283 54977

17.89% 1.29% 16.60%


Counts 683 65 618

Amount 100.00% 9.56% 90.44%




LAMPIRAN A TABEL DATA PENGUJIAN TRUE DENSITY, POROSITAS, BULK DENSITY, FLUX DENSITY, DAN PERMEABILITAS

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