Filenaam Word: Analysedatum: Golden Gate Single Reflection Diamond ATR. cm-1

Bijlage I

Probleemstelling Bij het vullen van lacunes in porselein wordt veel gebruik gemaakt van een mengsel van epoxy en een fumed silica om de juiste translucentie te bereiken. In de praktijk is gebleken dat fumed silica effect heeft op de vergeling van deze vullingen. Deze vergeling treed in sommige gevallen direct op bij vermenging van fumed silica en epoxy. Het vermoeden bestaat dat dit te maken heeft met vervuiling van de fumed silica en eventuele toevoegingen aan het materiaal tijdens het productieproces.

6

Vraagstelling(en) x

Hoe kunnen wij het probleem van vergeling van epoxy met fumed silica binnen de (keramiek) restauratie praktijk verklaren? o Verkleurt een epoxy met fumed silica meer dan een epoxy zonder deze toevoeging? Wat is de ervaring in de praktijk? o Wat zijn de eigenschappen van epoxy? Wat is een epoxy? (korte uiteenzetting over de eigenschappen van epoxies inclusief de basiscomponenten van de hars en harder) Welke epoxies worden veel gebruikt voor het aanvullen van porselein in de restauratiepraktijk? Wat zijn de verouderingseigenschappen van deze epoxies? Hebben verschillende manieren van uitharden invloed op de vergeling van de epoxies? o Wat zijn de eigenschappen van fumed silica? Welke soorten fumed silica zijn er op de markt en welke zijn gebruikt in de keramiekrestauratie? Wat is het maakproces van fumed silica? Wat is het verschil tussen hydrofobe en hydrofiele fumed silica? Wat is de samenstelling van deze hydrofobe en hydrofiele fumed silica's? o Hoe kunnen de eigenschappen van fumed silica de vergeling van epoxy beïnvloeden? Zijn er aspecten van de chemische eigenschappen van fumed silica die verklaren waarom deze snel vergelen of de vergeling van epoxy verergeren? Zijn er toevoegingen van de fumed silica die de vergeling zouden kunnen versnellen? o Wat zijn de andere factoren die de vergeling van epoxy beïnvloeden?

8

Bijlage II

FTIR onderzoek naar Aerosil 200 en Aerosil R805

Object:

Aerosil 200, hydrofiele fumed silica

Monsternummer:

Aerosil R805, hydrofobe fumed silica

Werknummer:

Monsterplaats:

Objectnummer:

Reden monstername:samenstelling

Doc. map:

Datum monstername:

Filenaam FTIR:

Uitgevoerd door:

Suzan de Groot

Apparatuur:

Perkin Elmer Spectrum 100

Filenaam Word:

Aantal scans:

16

Analysedatum:

Methode:

Golden Gate Single Reflection Diamond

A en B

29-05-2013

ATR

Spectrum 101.5

95

2958 2927

2852

90

85

80

75

806

70

%T

65

60

55

50

45

40 454 35

1064

31.2 4000.0

3600

3200

2800

2400

2000

1800

1600

1400

1200

1000

800

600

400.0

cm-1

Fumed silica - A.sp - 29-5-2013 - Aerosil 200 Fumed silica - B.sp - 29-5-2013 - Aerosil R805

Resultaat: De spectra van Aerosil 200 en Aerosil R805 vertonen beide de absorptiebanden bij 1064 (SiO rek vibratie), 806 en 454 cm-1 Het spectrum van Aerosil R805 vertoont tevens de absorptiebanden bij: 2958 cm-1  asymetrische C-H rek vibratie van -CH3 2927 cm-1  asymetrische C-H rek vibratie van -CH2 2852 cm-1  symetrische C-H rek vibratie van -CH2 Deze absorptiebanden zijn afkomstig van -C8H17 in Aerosil R805. Conclusie: Het is mogelijk met behulp van FTIR het verschil tussen Aerosil 200 en Aerosil R805 aan te tonen.

FTIR onderzoek naar Aerosil 200

Object:

Aerosil 200, hydrofiele fumed silica

Monsternummer:

Aerosil 200, ‘vergeeld’ in epoxy

Werknummer:

Monsterplaats:

Objectnummer:

Reden monstername:samenstelling

Doc. map:

Datum monstername:

Filenaam FTIR:

Uitgevoerd door:

Suzan de Groot

Apparatuur:

Perkin Elmer Spectrum 100

Filenaam Word:

Aantal scans:

16

Analysedatum:

Methode:

Golden Gate Single Reflection Diamond

A en C

29-05-2013

ATR

Spectrum 101.5

95

90

85

80 808

75

70 %T

65

60

55

50

45

40

455 1063

35 32.9 4000.0

3600

3200

2800

2400

2000

1800

1600

1400

1200

1000

cm-1

Fumed silica - A.s p - 29-5-2013 - Aerosil 200 Fumed silica - C.sp - 29-5-2013 - Aerosil 200 'vergeeld' in epoxy

Conclusie: De spectra van Aerosil 200 en Aerosil 200 ‘vergeeld’ vertonen geen verschil.

800

600

400.0

Bijlage III

Gewichten Araldite 2020 monsters Code A 0.1 A 0.2 A 0.3 A 1.1B A 1.2B A 1.3B A 2.1B A 2.2B A 2.3B A 3.1B A 3.2B A 3.3B A 4.1B A 4.2B A 4.3B A 5.1B A 5.2B A 5.3B

fumed silica geen geen geen Aerosil 200 Aerosil 200 Aerosil 200 Aerosil 300 Aerosil 300 Aerosil 300 Aerosil R805 Aerosil R805 Aerosil R805 Aerosil R972 Aerosil R972 Aerosil R972 Aerosil TT600 Aerosil TT600 Aerosil TT600

Resin in gram 1,50 1,50 1,64 1,50 1,54 1,65 1,53 1,52 1,61 1,55 1,53 1,64 1,51 1,53 1,64 1,50 1,53 1,61

0,5ml schepjes hardener in gram FS in gram 0,46 0,46 0,51 0,46 0,31 12 0,46 0,30 12 0,50 0,32 13 0,46 0,33 12 0,47 0,33 12 0,48 35,00 13 0,48 0,41 13 0,48 0,40 13 0,49 0,42 13 0,46 44,00 10 0,46 0,43 10 0,54 0,48 11 0,45 0,63 15 0,46 0,63 15 0,48 0,67 16

gewicht bakje 1,69 1,69 1,69 1,68 1,65 1,68 1,70 1,71 1,73 1,66 1,73 1,80 1,67 1,69 1,70 1,71 1,69 1,61

Gewichten Epo‐Tek 301‐2 monsters Code E 0.1 E 0.2 E 0.3 E 1.1B E 1.2B E 1.3B E 2.1B E 2.2B E 2.3B E 3.1B E 3.2B E 3.3B E 4.1B E 4.2B E 4.3B E 5.1B E 5.2B E 5.3B


Resin in gram 1,50 1,51 1,60 1,54 1,53 1,64 1,52 1,51 1,60 1,53 1,50 1,64 1,51 1,54 1,64 1,52 1,52 1,64

0,5ml schepjes hardener in gram FS in gram gewicht bakje 0,52 1,51 0,53 1,53 0,56 1,57 0,55 0,28 11 1,48 0,53 0,28 11 1,52 0,57 0,28 11 1,50 0,53 0,27 11 1,51 0,53 0,27 11 1,50 0,57 0,28 11 1,50 0,53 0,40 10 1,51 0,52 0,40 10 1,49 0,57 0,43 12 1,48 0,53 0,43 10 1,47 0,54 0,43 10 1,49 0,57 0,43 10 1,49 53,00 0,52 14 1,50 0,53 0,57 14 1,48 0,57 0,57 14 1,53

Gewichten Fynebond monsters Code F 0.1 F 0.2 F 0.3 F 1.1A F 1.2A F 1.3A F 2.1A F 2.2A F 2.3A F 3.1A F 3.2A F 3.3A F 4.1A F 4.2A F 4.3A F 5.1A F 5.2A F 5.3A


Resin in gram 1,56 1,57 1,75 1,55 1,56 1,59 1,57 1,53 1,65 1,56 1,55 1,58 1,55 1,54 1,60 1,54 1,55 1,61

F 1.1B F 1.2B F 1.3B F 2.1B F 2.2B F 2.3B F 3.1B F 3.2B F 3.3B F 4.1B F 4.2B F 4.3B F 5.1B F 5.2B F 5.3B

Aerosil 200 Aerosil 200 Aerosil 200 Aerosil 300 Aerosil 300 Aerosil 300 Aerosil R805 Aerosil R805 Aerosil R805 Aerosil R972 Aerosil R972 Aerosil R972 Aerosil TT600 Aerosil TT600 Aerosil TT600

1,55 1,55 1,60 1,55 1,55 1,58 1,55 1,56 1,60 1,57 1,54 1,62 1,56 1,55 1,61

0,5ml hardener in gram FS in gram schepjes gewicht bakje 0,50 1,67 0,50 1,66 0,56 1,69 0,50 0,12 4 1,60 0,50 0,11 4 1,60 0,51 0,11 4 1,60 0,50 0,11 4 1,64 0,49 0,11 4 1,70 0,53 0,12 4 1,68 0,50 0,10 4 1,61 0,50 0,11 4 1,53 0,50 0,10 4 1,66 0,49 0,17 4 1,59 0,49 0,17 4 1,64 0,51 0,17 4 1,57 0,49 0,19 4 1,43 0,50 0,19 4 1,45 0,52 0,19 4 1,61 0,49 0,50 0,51 0,50 0,49 0,50 0,49 0,49 0,51 0,50 0,49 0,52 0,51 0,50 0,51

0,21 0,23 0,24 0,26 0,26 0,26 0,30 0,30 0,30 0,44 0,44 0,45 0,47 0,48 0,50

8 8 9 9 9 9 9 9 9 10 10 10 11 11 11

1,61 1,61 1,63 1,48 1,47 1,50 1,60 1,72 1,65 1,70 1,66 1,66 1,64 1,53 1,58

Gewichten Hxtal NYL‐1 monsters 0,5ml schepjes hardener in gram FS in gram

Code H 0.1 H 0.2 H 0.3 H 1.1B H 1.2B H 1.3B H 2.1B H 2.2B H 2.3B H 3.1B H 3.2B H 3.3B H 4.1B H 4.2B H 4.3B H 5.1B H 5.2B H 5.3B


Resin in gram

gewicht bakje

1,55 1,52 1,65 1,56 1,55 1,60 1,58 1,54 1,61 1,54 1,54 1,63 1,55 1,55 1,70

0,50 0,50 0,54 0,51 0,52 0,54 0,53 0,52 0,56 0,50 0,50 0,58 0,50 0,50 0,56

0,25 0,25 0,28 0,26 0,26 0,26 0,44 0,45 0,47 0,40 0,40 0,40 0,63 0,63 0,65

10 10 10 10 10 10 12 12 13 10 10 10 15 15 16

1,67 1,71 1,64 1,70 1,78 1,74 1,72 1,72 1,81 1,68 1,71 1,70 1,65 1,59 1,64

H 1.1A H 1.2A H 1.3A H 2.1A H 2.2A H 2.3A H 3.1A H 3.2A H 3.3A H 4.1A H 4.2A H 4.3A H 5.1A H 5.2A H 5.3A

Aerosil 200 Aerosil 200 Aerosil 200 Aerosil 300 Aerosil 300 Aerosil 300 Aerosil R805 Aerosil R805 Aerosil R805 Aerosil R972 Aerosil R972 Aerosil R972 Aerosil TT600 Aerosil TT600 Aerosil TT600

1,51 1,52 1,69 1,52 1,53 1,70 1,53 1,57 1,70 1,51 1,55 1,68 1,53 1,54 1,66

0,48 0,49 0,55 0,49 0,49 0,54 0,49 0,50 0,55 0,48 0,50 0,53 0,49 0,49 0,53

0,11 0,12 0,12 0,13 0,12 0,12 0,16 0,16 0,16 0,20 0,19 0,19 0,24 0,20 0,20

4 4 4 4 4 4 4 4 4 4 4 4 4 4 4

1,48 1,67 1,67 1,65 1,79 1,72 1,72 1,69 1,66 1,67 1,64 1,69 1,67 1,64 1,49

Bijlage IV

Araldite 2020 monsters VOOR veroudering

Metingen Araldite 2020 monsters VOOR veroudering Code A 0.1

fumed silica geen

L*A*B* SCI

AVERAGE A 0.2

geen

A 0.3

geen

AVERAGE

AVERAGE A 1.1B Aerosil 200

AVERAGE A 1.2B 1 2B Aerosil A il 200





AVERAGE A 3.1B 3 1B Aerosil A il R805

AVERAGE A 3.2B Aerosil R805

AVERAGE

L*

a*

SCE L*

b*

91,11 91,36 91,28 91,25 90,93 90,70 91,30 90,98 91,12 91,33 91,38 91,28 78,72 78,21 78,98 78,64 76 76,50 50 76,44 77,78 76,91 78,14 79,79 80,30 , 79,41 78,42 76,38 77,57 77,46 75,73 75 57 75,57 76,35 75,88 79,55 79,11 79,22 79,29 79 79,13 13 79,33 80,22 79,56 80,34 78,67 80,11 80, 79,71

-2,01 -2,05 -2,06 -2,04 -2,04 -2,11 -2,07 -2,07 -2,03 -2,03 -2,07 -2,04 -2,48 -2,60 -2,52 -2,53 -2,11 2 11 -2,42 -2,35 -2,29 -2,37 -2,44 -2,36 , -2,39 -2,24 -2,39 -2,31 -2,31 -2,39 -2 46 -2,46 -2,39 -2,41 -2,28 -2,32 -2,32 -2,31 -3,23 3 23 -3,16 -3,13 -3,17 -3,17 -3,27 -3,24 3, -3,23

1

-1,01 -1,14 -1,05 -1,07 -1,00 -0,86 -1,08 -0,98 -1,08 -1,10 -1,11 -1,10 -0,80 -1,23 -0,33 -0,79 -0,03 0 03 -1,09 -0,45 -0,52 -0,95 -1,06 -0,45 , -0,82 0,18 -0,16 0,43 0,15 -0,51 -0 43 -0,43 -0,48 -0,47 0,20 -0,09 0,53 0,21 -1,35 1 35 -1,35 -0,89 -1,20 -1,04 -1,03 -0,58 0,58 -0,88

a* 87,36 87,29 87,16 87,27 87,21 87,01 87,20 87,14 87,24 87,12 87,23 87,20 75,96 75,61 76,15 75,91 73 73,55 55 73,93 74,85 74,11 75,20 79,80 77,42 , 77,47 75,14 73,27 74,24 74,22 72,68 72 44 72,44 73,21 72,78 76,35 75,85 75,95 76,05 77 77,98 98 77,93 77,90 77,94 78,25 76,20 77,46 77, 6 77,30

b* -2,13 -2,18 -2,20 -2,17 -2,17 -2,23 -2,21 -2,20 -2,17 -2,18 -2,20 -2,18 -2,62 -2,70 -2,66 -2,66 -2,60 2 60 -2,54 -2,49 -2,54 -2,52 -2,59 -2,50 , -2,54 -2,39 -2,54 -2,48 -2,47 -2,52 -2 61 -2,61 -2,52 -2,55 -2,43 -2,45 -2,48 -2,45 -3,22 3 22 -3,17 -3,22 -3,20 -3,24 -3,39 -3,37 3,37 -3,33

-0,81 -0,94 -0,82 -0,86 -0,92 -0,76 -0,88 -0,85 -0,88 -0,87 -0,91 -0,89 -0,76 -1,13 -0,32 -0,74 -0,04 0 04 -1,12 -0,46 -0,54 -0,96 -1,15 -0,54 , -0,88 0,11 -0,13 0,42 0,13 -0,42 -0 30 -0,30 -0,38 -0,37 0,22 -0,13 0,52 0,20 -1,19 1 19 -1,22 -0,63 -1,01 -0,81 -0,75 -0,31 0,3 -0,62

Araldite 2020 monsters VOOR veroudering A 3.3B Aerosil R805




AVERAGE A 5.1B Aerosil TT600



AVERAGE

80,13 79,69 80,48 80,10 80,05 80,22 80 77 80,77 80,35 79,82 79,23 80,46 79,84 81,35 80 44 80,44 81,03 80,94 92,08 91,70 92,14 91,97 , 91,97 91,84 91,95 91,92 92,43 92,24 92 38 92,38 92,35

-3,30 -3,28 -3,08 -3,22 -2,86 -2,93 -2 96 -2,96 -2,92 -2,83 -2,92 -2,84 -2,86 -3,11 -3,16 3 16 -2,95 -3,07 -2,26 -2,28 -2,25 -2,26 , -2,31 -2,35 -2,33 -2,33 -2,24 -2,30 -2 30 -2,30 -2,28

2

-1,13 -1,04 -0,67 -0,95 -2,16 -2,72 -2 63 -2,63 -2,50 -2,84 -3,47 -3,02 -3,11 -1,78 -2,65 2 65 -2,23 -2,22 0,14 -0,03 0,29 0,13 , 0,25 0,25 0,32 0,27 0,20 0,26 0 28 0,28 0,25

77,57 77,02 77,83 77,47 77,48 77,51 78 29 78,29 77,76 77,01 76,38 77,65 77,01 78,58 77,70 77 70 78,28 78,19 90,11 90,40 90,04 90,18 , 90,01 90,35 89,97 90,11 90,33 90,20 90 26 90,26 90,26

-3,42 -3,41 -3,21 -3,35 -3,02 -3,09 -3 11 -3,11 -3,07 -3,02 -3,10 -3,03 -3,05 -3,30 -3,31 3 31 -3,10 -3,24 -2,25 -2,23 -2,26 -2,25 , -2,30 -2,31 -2,32 -2,31 -2,24 -2,30 -2 30 -2,30 -2,28

-0,88 -0,80 -0,42 -0,70 -2,13 -2,69 -2 66 -2,66 -2,49 -2,83 -3,44 -3,02 -3,10 -1,69 -2,56 2 56 -2,11 -2,12 0,45 0,18 0,60 0,41 , 0,57 0,51 0,63 0,57 0,51 0,53 0 58 0,58 0,54

Araldite 2020 monsters NA veroudering

Metingen Araldite 2020 monsters NA veroudering Code A 0.1

fumed silica geen

L*A*B* SCI

AVERAGE A 0.2

AVERAGE A 0.3


AVERAGE A 1.2B 1 2B Aerosil A il 200





AVERAGE A 3.1B 3 1B Aerosil A il R805


AVERAGE

L*

a*

SCE L*

b*

88,20 88,84 88,76 88,60 88,44 88,40 87,07 87,97 89,35 89,55 89,26 89,39 74,62 74,91 76,55 75,36 72 72,50 50 72,43 73,22 72,72 74,67 75,11 74,92 , 74,90 73,92 73,98 75,73 74,54 72,23 73 42 73,42 74,23 73,29 76,46 75,73 76,72 76,30 75 75,63 63 74,75 77,19 75,86 76,71 76,03 78,66 77,13

-3,27 -3,30 -3,31 -3,29 -3,20 -3,21 -3,33 -3,25 -3,15 -2,95 -3,18 -3,09 -2,46 -2,44 -2,48 -2,46 -2,02 2 02 -2,00 -2,09 -2,04 -2,44 -2,47 -2,45 , -2,45 -2,09 -2,14 -2,31 -2,18 -1,91 -2 10 -2,10 -2,03 -2,01 -2,53 -2,58 -2,42 -2,51 -2,84 2 84 -2,85 -2,88 -2,86 -3,12 -2,99 -3,41 3, -3,17

1

11,23 10,94 12,04 11,40 10,12 10,49 10,46 10,36 8,30 7,11 9,52 8,31 16,47 17,61 16,99 17,02 17 17,04 04 17,81 17,06 17,30 16,11 16,80 15,89 , 16,27 17,16 17,39 17,18 17,24 16,88 17 49 17,49 17,61 17,33 16,28 15,08 16,23 15,86 16 16,12 12 15,79 16,75 16,22 14,94 15,80 15,05 5,05 15,26

a* 84,16 84,96 84,64 84,59 84,65 84,77 83,05 84,16 85,10 85,41 85,16 85,22 72,01 72,43 74,04 72,83 69 69,45 45 69,87 70,68 70,00 71,63 72,13 71,87 , 71,88 70,54 70,59 72,30 71,14 69,06 70 60 70,60 71,08 70,25 73,33 72,51 73,56 73,13 73 73,15 15 73,00 74,80 73,65 73,92 73,66 76,91 76,9 74,83

b* -3,40 -3,43 -3,44 -3,42 -3,33 -3,33 -3,45 -3,37 -3,30 -3,10 -3,33 -3,24 -2,63 -2,60 -2,66 -2,63 -2,22 2 22 -2,14 -2,23 -2,20 -2,60 -2,67 -2,67 , -2,65 -2,28 -2,33 -2,52 -2,38 -2,05 -2 23 -2,23 -2,18 -2,15 -2,71 -2,75 -2,59 -2,68 -2,98 2 98 -2,93 -2,99 -2,97 -3,30 -3,12 -3,50 3,50 -3,31

11,63 11,35 12,57 11,85 10,45 10,87 10,88 10,73 8,77 7,54 10,00 8,77 17,56 18,67 17,82 18,02 18 18,48 48 19,09 18,08 18,55 17,30 18,10 17,06 , 17,49 18,45 18,84 18,41 18,57 18,54 18 97 18,97 19,12 18,88 17,59 16,34 17,50 17,14 17 17,36 36 16,66 17,95 17,32 16,21 16,99 15,74 5,7 16,31

Araldite 2020 monsters NA veroudering A 3.3B Aerosil R805







AVERAGE

76,18 76,93 77,35 76,82 75,65 76,02 76 84 76,84 76,17 75,35 75,70 76,14 75,73 78,28 77 90 77,90 79,44 78,54 87,43 86,91 87,56 87,30 , 87,77 87,26 87,93 87,65 88,11 87,80 88 29 88,29 88,07

-3,01 -3,07 -3,08 -3,05 -2,99 -2,91 -2 95 -2,95 -2,95 -2,74 -2,67 -2,64 -2,68 -3,79 -3,71 3 71 -3,51 -3,67 -2,05 -2,07 -2,20 -2,11 , -2,18 -2,15 -2,27 -2,20 -2,21 -2,14 -2 26 -2,26 -2,20

2

15,05 16,63 14,99 15,56 15,84 16,04 16 15 16,15 16,01 17,29 18,46 17,60 17,78 11,67 11,38 11 38 12,15 11,73 20,19 20,42 19,69 20,10 , 19,40 19,78 19,11 19,43 19,01 19,73 18 69 18,69 19,14

73,35 75,66 74,55 74,52 72,88 73,18 74 14 74,14 73,40 72,43 72,82 73,29 72,85 75,42 75,05 75 05 76,62 75,70 85,51 85,78 85,57 85,62 , 85,72 85,43 85,86 85,67 85,96 85,89 86 12 86,12 85,99

-3,17 -3,12 -3,24 -3,18 -3,19 -3,10 -3 19 -3,19 -3,16 -2,98 -2,89 -2,88 -2,92 -4,05 -3,96 3 96 -3,79 -3,93 -2,08 -2,05 -2,24 -2,12 , -2,22 -2,18 -2,31 -2,24 -2,25 -2,15 -2 31 -2,31 -2,24

16,37 17,15 16,28 16,60 17,12 17,37 14 23 14,23 16,24 18,67 19,99 18,94 19,20 12,64 12,32 12 32 13,03 12,66 21,15 20,90 20,66 20,90 , 20,36 20,62 20,06 20,35 20,08 20,68 19 75 19,75 20,17

Bijlage V

Epo‐Tek 301‐2 monsters VOOR veroudering

Metingen Epo-Tek 301-2 monsters VOOR veroudering Code E 0.1

fumed silica geen

L*A*B* SCI

AVERAGE E 0.2

geen

E 0.3

geen

AVERAGE

AVERAGE E 1.1B Aerosil 200

AVERAGE E 1.2B 1 2B A Aerosil il 200





AVERAGE E 3.1B 3 1B A Aerosil il R805

AVERAGE E 3.2B Aerosil R805

AVERAGE

L*

a*

SCE L*

b*

89,73 89,67 90,18 89,86 89,64 88,53 89,72 89,30 88,92 88,11 89,35 88,79 82,42 82,39 81,95 82,25 82 82,19 19 82,21 82,45 82,28 80,53 80,65 81,62 , 80,93 80,79 80,13 81,71 80,88 79,95 79 76 79,76 81,15 80,29 82,08 81,25 81,77 81,70 82 82,52 52 82,48 82,98 82,66 81,11 81,91 83,05 82,02

-1,79 -1,80 -1,81 -1,80 -1,80 -1,77 -1,81 -1,79 -1,76 -1,76 -1,77 -1,76 -1,39 -1,52 -1,41 -1,44 -1,42 1 42 -1,56 -1,45 -1,48 -1,49 -1,58 -1,65 , -1,57 -1,46 -1,67 -1,48 -1,54 -1,39 -1 56 -1,56 -1,43 -1,46 -1,63 -1,68 -1,50 -1,60 -2,17 2 17 -2,35 -2,10 -2,21 -2,24 -2,35 -2,34 ,3 -2,31

1

-1,55 -1,48 -1,60 -1,54 -1,65 -1,41 -1,60 -1,55 -1,53 -1,45 -1,68 -1,55 -5,35 -5,77 -5,53 -5,55 -5,68 5 68 -5,94 -5,57 -5,73 -6,19 -6,51 -6,12 , -6,27 -5,62 -6,41 -5,49 -5,84 -6,10 -6 46 -6,46 -5,74 -6,10 -5,52 -6,05 -5,49 -5,69 -6,19 6 19 -6,40 -5,92 -6,17 -6,64 -6,64 -5,96 5,96 -6,41

a* 87,17 86,79 87,33 87,10 86,24 85,18 86,47 85,96 85,60 84,65 86,08 85,44 80,21 79,76 79,45 79,81 79 79,50 50 79,36 79,84 79,57 78,19 77,96 78,97 , 78,37 78,63 78,30 79,52 78,82 77,88 77 40 77,40 78,50 77,93 79,46 79,08 79,45 79,33 80 80,43 43 80,63 80,51 80,52 80,16 79,59 881,75 ,75 80,50

b* -1,83 -1,87 -1,88 -1,86 -1,91 -1,87 -1,90 -1,89 -1,86 -1,86 -1,85 -1,86 -1,57 -1,70 -1,58 -1,62 -1,59 1 59 -1,72 -1,64 -1,65 -1,62 -1,74 -1,79 , -1,72 -1,54 -1,72 -1,56 -1,61 -1,45 -1 62 -1,62 -1,52 -1,53 -1,75 -1,77 -1,58 -1,70 -2,24 2 24 -2,42 -2,20 -2,29 -2,22 -2,44 -2,36 ,36 -2,34

-1,47 -1,39 -1,49 -1,45 -1,42 -1,18 -1,41 -1,34 -1,31 -1,21 -1,48 -1,33 -5,81 -6,14 -5,90 -5,95 -5,91 5 91 -6,14 -5,81 -5,95 -6,50 -6,80 -6,26 , -6,52 -5,67 -6,47 -5,59 -5,91 -6,15 -6 56 -6,56 -5,81 -6,17 -5,66 -6,16 -5,56 -5,79 -6,19 6 19 -6,42 -5,94 -6,18 -6,68 -6,66 -5,99 5,99 -6,44

Epo‐Tek 301‐2 monsters VOOR veroudering E 3.3B Aerosil R805




AVERAGE E 5.1B Aerosil TT600



AVERAGE

82,18 82,22 83,80 82,73 84,58 84,69 85 15 85,15 84,81 83,62 84,30 84,74 84,22 84,98 85 28 85,28 86,08 85,45 93,98 94,16 94,07 94,07 , 94,63 94,47 94,55 94,55 94,24 94,37 94 28 94,28 94,30

-2,22 -2,36 -2,27 -2,28 -2,39 -2,52 -2 44 -2,44 -2,45 -2,46 -2,42 -2,46 -2,45 -2,50 -2,51 2 51 -2,45 -2,49 -1,37 -1,34 -1,39 -1,37 , -1,33 -1,35 -1,39 -1,36 -1,39 -1,47 -1 38 -1,38 -1,41

2

-6,49 -6,40 -5,74 -6,21 -5,28 -5,47 -5 08 -5,08 -5,28 -5,64 -5,37 -5,18 -5,40 -5,34 -5,24 5 24 -4,79 -5,12 -2,09 -2,01 -1,98 -2,03 , -2,04 -2,05 -1,95 -2,01 -2,02 -2,01 -1 98 -1,98 -2,00

80,39 80,09 81,86 80,78 82,27 82,25 82 63 82,63 82,38 81,72 82,66 82,58 82,32 82,84 82,80 82 80 83,63 83,09 91,89 92,02 92,26 92,06 , 92,68 92,37 92,14 92,40 92,20 92,36 92 18 92,18 92,25

-2,26 -2,44 -2,31 -2,34 -2,46 -2,60 -2 54 -2,54 -2,53 -2,50 -2,45 -2,53 -2,49 -2,57 -2,59 2 59 -2,53 -2,56 -1,39 -1,36 -1,39 -1,38 , -1,34 -1,36 -1,40 -1,37 -1,41 -1,49 -1 39 -1,39 -1,43

-6,47 -6,42 -5,76 -6,22 -5,25 -5,49 -5 06 -5,06 -5,27 -5,61 -5,32 -5,14 -5,36 -5,29 -5,25 5 25 -4,77 -5,10 -1,95 -1,85 -1,83 -1,88 , -1,88 -1,89 -1,80 -1,86 -1,85 -1,85 -1 82 -1,82 -1,84

Epo‐Tek 301‐2 monsters NA veroudering

Metingen Epo-Tek 301-2 monsters NA veroudering Code E 0.1

fumed silica geen

L*A*B* SCI

AVERAGE E 0.2

geen

E 0.3

geen

AVERAGE


AVERAGE E 1.2B 1 2B A Aerosil il 200





AVERAGE E 3.1B 3 1B A Aerosil il R805


AVERAGE

L*

a*

SCE L*

b*

89,43 89,91 89,42 89,59 89,47 89,42 89,92 89,60 89,06 89,15 88,98 89,06 81,55 81,60 82,15 81,77 81 81,30 30 80,88 81,84 81,34 79,37 79,58 80,60 , 79,85 79,66 79,88 81,51 80,35 78,92 78 99 78,99 80,24 79,38 82,06 81,97 82,66 82,23 81 81,91 91 82,29 82,93 82,38 80,18 80,20 881,54 ,5 80,64

-2,44 -2,46 -2,41 -2,44 -2,62 -2,48 -2,48 -2,53 -2,46 -2,38 -2,37 -2,40 -3,25 -3,20 -3,18 -3,21 -3,31 3 31 -2,70 -3,12 -3,04 -3,20 -3,03 -3,10 , -3,11 -3,54 -3,54 -3,46 -3,51 -3,37 -3 90 -3,90 -3,47 -3,58 -3,43 -3,46 -3,70 -3,53 -4,08 4 08 -3,77 -3,40 -3,75 -4,02 -3,45 -3,88 3,88 -3,78

1

1,51 1,44 1,55 1,50 2,01 1,81 1,39 1,74 1,41 1,25 1,16 1,27 3,06 0,40 3,76 2,41 22,60 60 3,69 3,27 3,19 1,91 1,37 3,01 , 2,10 3,03 3,76 3,93 3,57 3,45 3 77 3,77 3,66 3,63 3,52 3,85 3,54 3,64 33,09 09 3,25 3,64 3,33 1,66 1,69 2,43 , 3 1,93

a* 85,93 86,54 86,13 86,20 86,03 86,01 86,38 86,14 85,48 85,52 85,50 85,50 79,16 79,15 79,87 79,39 78 78,95 95 78,30 79,54 78,93 76,70 76,79 78,05 , 77,18 77,29 78,03 79,18 78,17 77,14 78 36 78,36 78,22 77,91 79,47 79,56 80,24 79,76 80 80,24 24 80,80 81,25 80,76 78,19 79,36 79,48 79, 8 79,01

b* -2,56 -2,59 -2,52 -2,56 -2,74 -2,60 -2,61 -2,65 -2,58 -2,50 -2,48 -2,52 -3,53 -3,53 -3,44 -3,50 -3,56 3 56 -2,89 -3,38 -3,28 -3,43 -3,28 -3,34 , -3,35 -3,73 -3,68 -3,64 -3,68 -3,49 -3 50 -3,50 -3,62 -3,54 -3,65 -3,65 -3,89 -3,73 -4,21 4 21 -3,85 -4,06 -4,04 -4,18 -3,47 -4,04 ,0 -3,90

1,87 1,77 1,91 1,85 2,37 2,19 1,76 2,11 1,78 1,63 1,53 1,65 2,96 3,42 3,71 3,36 22,58 58 3,98 3,20 3,25 2,01 1,52 3,12 , 2,22 3,25 3,96 4,14 3,78 3,68 3 79 3,79 3,83 3,77 3,80 4,13 3,81 3,91 33,11 11 3,39 3,67 3,39 1,71 1,74 2,55 ,55 2,00

Epo‐Tek 301‐2 monsters NA veroudering E 3.3B Aerosil R805







AVERAGE

81,44 81,60 82,25 81,76 84,19 84,38 84 72 84,72 84,43 83,91 83,52 84,22 83,88 84,04 84 40 84,40 84,80 84,41 92,74 92,73 92,89 92,79 , 93,02 92,54 93,07 92,88 92,81 92,71 92 96 92,96 92,83

-4,00 -4,05 -3,92 -3,99 -4,05 -3,96 -3 90 -3,90 -3,97 -3,88 -3,84 -3,85 -3,86 -4,01 -3,97 3 97 -3,95 -3,98 -3,16 -3,21 -3,20 -3,19 , -3,14 -3,15 -3,14 -3,14 -3,25 -3,19 -3 21 -3,21 -3,22

2

1,54 2,46 1,77 1,92 3,03 3,35 3 40 3,40 3,26 2,94 2,98 3,10 3,01 2,68 2,41 2 41 3,19 2,76 8,06 8,17 7,99 8,07 , 8,08 8,25 7,98 8,10 7,77 7,95 7 64 7,64 7,79

79,27 81,09 79,77 80,04 82,69 82,82 83 34 83,34 82,95 82,50 82,22 82,87 82,53 82,13 82,41 82 41 83,36 82,63 91,46 91,51 91,68 91,55 , 91,78 91,71 91,61 91,70 91,11 91,20 91 19 91,19 91,17

-4,17 -4,05 -4,11 -4,11 -4,17 -4,08 -4 01 -4,01 -4,09 -3,98 -3,91 -3,96 -3,95 -4,15 -4,10 4 10 -4,04 -4,10 -3,22 -3,27 -3,26 -3,25 , -3,20 -3,14 -3,20 -3,18 -3,32 -3,27 -3 28 -3,28 -3,29

1,77 2,52 2,06 2,12 2,90 3,25 3 27 3,27 3,14 2,76 2,94 2,91 2,87 2,77 2,56 2 56 3,13 2,82 8,13 8,22 8,09 8,15 , 8,20 8,34 8,13 8,22 8,03 8,18 7 98 7,98 8,06

Bijlage VI

Kleurmetingen Fynebond monsters VOOR veroudering.

Metingen Fynebond monsters VOOR veroudering Code F 0.1

fumed silica geen

L*A*B* SCI

AVERAGE F 0.2

geen

F 0.3

geen

AVERAGE

AVERAGE F 1.1A Aerosil 200

AVERAGE F 1.2A 1 2A Aerosil A il 200





AVERAGE F 3.1A Aerosil R805


AVERAGE

L*

a*

SCE L*

b*

90,69 90,67 90,96 90,77 89,54 90,93 90,91 90,46 89,55 89,90 90,65 90,03 79,19 81,41 78,58 79,73 80 80,97 97 83,46 82,40 82,28 81,95 82,94 81,31 82,07 79,03 80,74 80,28 80,02 79,05 80 10 80,10 80,30 79,82 79,70 79,98 80,00 79,89 83,23 83,15 84,73 83,70 83,15 83,91 83 08 83,08 83,38

-1,86 -1,87 -1,89 -1,87 -1,81 -1,87 -1,88 -1,85 -1,85 -1,83 -1,89 -1,86 -1,23 -1,28 -1,20 -1,24 -1,35 1 35 -1,50 -1,39 -1,41 -1,52 -1,60 -1,52 1,52 -1,55 -1,36 -1,42 -1,44 -1,41 -1,32 -1,32 1 32 -1,34 -1,33 -1,32 -1,36 -1,32 -1,33 -1,83 -1,78 -1,83 -1,81 -1,66 -1,79 -1 71 -1,71 -1,72

1

-1,38 -1,38 -1,36 -1,37 -1,31 -1,37 -1,36 -1,35 -1,31 -1,34 -1,42 -1,36 -3,06 -2,61 -3,22 -2,96 -2,85 2 85 -2,86 -2,76 -2,82 -3,64 -3,70 -3,58 3,58 -3,64 -2,82 -2,75 -2,97 -2,85 -3,02 -2,95 2 95 -2,93 -2,97 -2,63 -2,81 -2,84 -2,76 -3,71 -3,73 -3,35 -3,60 -3,53 -3,77 -3 86 -3,86 -3,72

a* 86,95 87,36 87,28 87,20 86,07 87,27 87,34 86,89 85,85 86,02 86,85 86,24 78,05 79,04 76,03 77,71 78,40 78 40 80,90 79,69 79,66 79,58 80,33 78,78 79,56 76,93 78,05 77,66 77,55 76,13 77 21 77,21 77,40 76,91 76,90 77,05 77,09 77,01 80,71 80,89 82,43 81,34 80,82 81,72 81 06 81,06 81,20

b* -1,97 -1,99 -2,02 -1,99 -1,92 -2,00 -2,01 -1,98 -1,97 -1,96 -2,01 -1,98 -1,34 -1,49 -1,31 -1,38 -1,45 1 45 -1,63 -1,51 -1,53 -1,64 -1,72 -1,61 1,61 -1,66 -1,42 -1,53 -1,54 -1,50 -1,41 -1,41 1 41 -1,44 -1,42 -1,41 -1,46 -1,42 -1,43 -1,90 -1,84 -1,88 -1,87 -1,74 -1,87 -1 82 -1,82 -1,81

-1,20 -1,27 -1,16 -1,21 -1,17 -1,22 -1,21 -1,20 -1,16 -1,15 -1,22 -1,18 -3,14 -2,98 -3,14 -3,09 -2,86 2 86 -3,04 -2,86 -2,92 -3,67 -3,78 -3,53 3,53 -3,66 -2,88 -2,76 -2,96 -2,87 -2,99 -2,92 2 92 -2,86 -2,92 -2,64 -2,80 -2,80 -2,75 -3,66 -3,64 -3,29 -3,53 -3,42 -3,73 -3 76 -3,76 -3,64

Kleurmetingen Fynebond monsters VOOR veroudering. F 3.3A Aerosil R805




AVERAGE F 5.1A Aerosil TT600



AVERAGE

82,92 84,60 83,86 83,79 82,87 84,30 84 18 84,18 83,78 85,29 84,90 85,63 85,27 83,40 85 34 85,34 84,90 84,55 90,82 89,47 90,72 90,34 , 91,04 90,70 90,33 90,69 90,92 89,74 90 76 90,76 90,47

-1,75 -1,79 -1,76 -1,77 -2,13 -2,00 -2 08 -2,08 -2,07 -1,89 -1,90 -1,91 -1,90 -2,10 -2,10 2 10 -2,07 -2,09 -1,83 -1,87 -1,86 -1,85 , -1,83 -1,85 -1,82 -1,83 -1,83 -1,82 -1 77 -1,77 -1,81

2

-3,83 -3,58 -3,44 -3,62 -4,87 -4,25 -4 42 -4,42 -4,51 -3,28 -3,34 -3,27 -3,30 -4,26 -4,01 4 01 -4,10 -4,12 -2,68 -3,30 -2,60 -2,86 , -2,64 -2,64 -2,98 -2,75 -2,49 -3,12 -2 61 -2,61 -2,74

81,26 82,17 81,48 81,64 80,28 81,76 81 70 81,70 81,25 82,92 82,51 83,22 82,88 81,32 82,90 82 90 82,40 82,21 88,81 87,28 88,46 88,18 , 88,86 88,42 88,02 88,43 88,93 87,51 88 49 88,49 88,31

-1,83 -1,87 -1,84 -1,85 -2,22 -2,08 -2 17 -2,17 -2,16 -1,94 -1,96 -1,97 -1,96 -2,18 -2,17 2 17 -2,15 -2,17 -1,86 -1,92 -1,91 -1,90 , -1,86 -1,90 -1,87 -1,88 -1,89 -1,87 -1 82 -1,82 -1,86

-3,71 -3,47 -3,35 -3,51 -4,81 -4,16 -4 31 -4,31 -4,43 -3,14 -3,18 -3,11 -3,14 -4,17 -3,90 3 90 -4,00 -4,02 -2,47 -3,21 -2,43 -2,70 , -2,47 -2,46 -2,81 -2,58 -2,26 -2,95 -2 43 -2,43 -2,55

Kleurmetingen Fynebond monsters VOOR veroudering.

Code fumed silica F 1.1B Aerosil 200

L*A*B* SCI

AVERAGE F 11.2B 2B Aerosil 200

AVERAGE F 1.3B Aerosil 200




AVERAGE F 33.1B 1B Aerosil R805

AVERAGE F 3.2B Aerosil R805




AVERAGE F 44.3B 3B Aerosil A il R972

AVERAGE

L*

a*

SCE L*

b*

79,58 79,59 81,12 80,10 79 12 79,12 78,52 79,45 79,03 80,96 82,21 82,72 81,96 80,44 78,84 79,71 79,66 80,48 80,22 79,95 80,22 81,69 81,11 82,51 81,77 83 20 83,20 82,14 82,12 82,49 83,24 83,79 82,75 83,26 84,26 83,78 83,88 83,97 83,51 84,00 84,38 83,96 83,84 84,32 84,89 84,35 84 70 84,70 85,05 85,34 85,03

-1,50 -1,63 -1,59 -1,57 -1 62 -1,62 -1,73 -1,66 -1,67 -1,74 -1,83 -1,75 -1,77 -1,64 -1,70 -1,71 -1,68 -1,57 -1,68 1,68 -1,53 -1,59 -1,70 -0,80 -1,72 -1,41 -2,16 2 16 -2,35 -2,24 -2,25 -2,19 -2,23 -2,27 -2,23 -2,07 -2,23 -2,20 -2,17 -2,64 -2,64 2,64 -2,57 -2,62 -2,49 -2,61 -2,60 -2,57 -2,53 2 53 -2,53 -2,49 -2,52

3

-5,24 -5,32 -4,74 -5,10 -5 56 -5,56 -5,70 -5,37 -5,54 -5,29 -5,10 -4,86 -5,08 -5,17 -5,59 -5,28 -5,35 -5,05 -5,36 5,36 -5,15 -5,19 -4,71 -5,03 -4,65 -4,80 -5,16 5 16 -5,83 -5,65 -5,55 -5,26 -5,15 -5,40 -5,27 -4,49 -4,89 -4,81 -4,73 -5,15 -5,00 5,00 -4,93 -5,03 -5,14 -4,87 -4,71 -4,91 -4,70 4 70 -4,45 -4,29 -4,48

a* 77,34 77,29 78,78 77,80 76 84 76,84 75,97 77,27 76,69 78,72 79,95 80,21 79,63 78,04 76,26 77,40 77,23 77,94 77,68 77,48 77,70 79,24 79,03 80,16 79,48 80 75 80,75 79,98 79,64 80,12 81,56 81,61 80,48 81,22 81,88 81,43 81,54 81,62 81,51 81,64 81,84 81,66 82,41 81,71 82,33 82,15 82 26 82,26 82,55 82,81 82,54

b* -1,67 -1,79 -1,73 -1,73 -1 76 -1,76 -1,86 -1,78 -1,80 -1,89 -1,98 -1,94 -1,94 -1,73 -1,78 -1,78 -1,76 -1,67 -1,77 1,77 -1,62 -1,69 -1,78 -1,87 -1,81 -1,82 -2,28 2 28 -2,45 -2,34 -2,36 -2,27 -2,37 -2,38 -2,34 -2,19 -2,35 -2,32 -2,29 -2,69 -2,72 2,72 -2,67 -2,69 -2,48 -2,72 -2,70 -2,63 -2,60 2 60 -2,63 -2,59 -2,61

-5,64 -5,64 -4,90 -5,39 -5 84 -5,84 -5,83 -5,64 -5,77 -5,59 -5,31 -5,06 -5,32 -5,19 -5,66 -5,34 -5,40 -5,11 -5,44 5,44 -5,24 -5,26 -4,73 -5,13 -4,70 -4,85 -5,27 5 27 -5,97 -5,72 -5,65 -5,44 -5,30 -5,55 -5,43 -4,56 -4,97 -4,90 -4,81 -5,12 -4,94 4,94 -4,89 -4,98 -5,16 -4,83 -4,67 -4,89 -4,66 4 66 -4,40 -4,22 -4,43

Kleurmetingen Fynebond monsters VOOR veroudering. F 5.1B Aerosil TT600

AVERAGE F 5.2B Aerosil TT600


AVERAGE

93,58 93,67 93,61 93,62 93,17 93,27 93 10 93,10 93,18 93,47 93,71 93,35 93,51

-1,48 -1,51 -1,50 -1,50 -1,55 -1,45 -1 54 -1,54 -1,51 -1,47 -1,47 -1,47 -1,47

4

-1,59 -1,48 -1,42 -1,50 -1,73 -1,64 -1 59 -1,59 -1,65 -1,72 -1,62 -1,65 -1,66

91,71 91,81 91,70 91,74 91,50 91,61 91 39 91,39 91,50 91,47 91,77 91,44 91,56

-1,49 -1,51 -1,51 -1,50 -1,57 -1,46 -1 56 -1,56 -1,53 -1,49 -1,49 -1,49 -1,49

-1,47 -1,37 -1,28 -1,37 -1,72 -1,63 -1 59 -1,59 -1,65 -1,65 -1,58 -1,49 -1,57

Kleurmetingen Fynebond monsters NA veroudering

Metingen Fynebond monsters NA veroudering Code F 0.1

fumed silica geen

L*A*B* SCI

AVERAGE F 0.2

geen

AVERAGE F 0.3

geen


AVERAGE F 11.2A 2A Aerosil 200





AVERAGE F 3.1A 3 1A Aerosil A il R805


AVERAGE

L*

a*

SCE L*

b*

89,47 89,29 89,58 89,45 89,51 89,95 88,70 89,39 89,73 90,17 89,63 89,84 80,13 80,80 80,23 80,39 79 22 79,22 80,59 80,01 79,94 80,54 81,26 79,85 , 80,55 77,75 78,80 78,13 78,23 77,84 78 58 78,58 79,13 78,52 79,35 79,71 79,79 79,62 80,89 80 89 80,62 81,44 80,98 80,98 81,42 881,19 , 9 81,20

-2,74 -2,79 -2,57 -2,70 -2,55 -2,59 -2,46 -2,53 -2,47 -2,48 2,48 -2,18 -2,38 -2,93 -3,02 -2,87 -2,94 -2,87 2 87 -3,07 -2,93 -2,96 -3,12 -3,11 -2,97 , -3,07 -2,77 -2,85 -2,72 -2,78 -2,75 -2 84 -2,84 -2,88 -2,82 -2,82 -2,81 -2,87 -2,83 -3,06 3 06 -2,93 -2,94 -2,98 -3,08 -2,99 -2,89 ,89 -2,99

1

3,83 3,83 2,52 3,39 2,51 2,71 2,26 2,49 2,08 2,02 0,86 1,65 7,38 7,56 7,36 7,43 7 03 7,03 7,27 7,76 7,35 6,16 6,77 6,21 , 6,38 7,64 8,09 8,53 8,09 7,53 7 89 7,89 8,21 7,88 6,72 6,85 7,23 6,93 6,31 6 31 6,82 6,38 6,50 6,94 7,19 6,36 6,83

a* 85,61 85,69 85,68 85,66 85,70 86,01 84,78 85,50 85,65 86,07 85,00 85,57 77,42 78,06 77,43 77,64 76 54 76,54 77,98 77,47 77,33 77,89 78,54 77,25 , 77,89 75,02 76,10 75,42 75,51 74,97 75 78 75,78 76,52 75,76 76,45 76,81 76,85 76,70 79,02 79 02 78,68 79,49 79,06 79,17 79,60 79,02 79,0 79,26

b* -2,90 -2,95 -2,72 -2,86 -2,69 -2,76 -2,63 -2,69 -2,63 -2,64 2,64 -2,33 -2,53 -0,18 -3,29 -3,12 -2,20 -3,09 3 09 -3,31 -3,16 -3,19 -3,35 -3,34 -3,16 , -3,28 -2,96 -3,04 -2,91 -2,97 -2,94 -3 04 -3,04 -3,08 -3,02 -3,03 -3,04 -3,07 -3,05 -3,17 3 17 -3,05 -3,07 -3,10 -3,18 -3,08 -3,03 3,03 -3,10

4,24 4,19 2,91 3,78 2,86 3,09 2,67 2,87 2,48 2,40 1,17 2,02 7,76 7,90 7,80 7,82 7 52 7,52 7,63 8,14 7,76 6,62 7,26 6,70 , 6,86 8,31 8,75 9,29 8,78 8,26 8 61 8,61 8,95 8,61 7,28 7,43 7,88 7,53 6,58 6 58 7,19 6,70 6,82 7,28 7,46 6,79 7,18

Kleurmetingen Fynebond monsters NA veroudering F 3.3A Aerosil R805





AVERAGE V G F 5.2A Aerosil TT600


AVERAGE

81,16 81,88 81,34 81,46 80,94 79,40 81 63 81,63 80,66 80,91 80,67 81,03 80,87 82,84 82 60 82,60 82,57 82,67 88,12 86,81 88,44 87,79 87,40 88,10 88,32 87,94 88,72 88,49 88 93 88,93 88,71

-3,01 -3,10 -2,99 -3,03 -3,40 -2,95 -3 21 -3,21 -3,19 -3,61 -3,52 -3,50 -3,54 -3,50 -3,45 3 45 -3,28 -3,41 -3,26 -3,08 -3,20 -3,18 3, 8 -3,10 -3,04 -3,14 -3,09 -3,19 -3,09 -3,18 3 18 -3,15

2

6,17 7,13 6,59 6,63 5,55 4,42 6 35 6,35 5,44 8,05 8,76 9,20 8,67 6,05 5,81 5 81 6,16 6,01 10,16 9,05 9,98 9,73 9,63 10,52 9,83 9,99 9,81 9,60 9 42 9,42 9,61

79,09 79,83 79,30 79,41 79,05 77,19 79 61 79,61 78,62 79,06 79,08 79,57 79,24 80,65 80,36 80 36 80,40 80,47 86,13 84,99 86,57 85,90 85,52 86,22 86,36 86,03 86,70 86,54 86 88 86,88 86,71

-3,15 -3,22 -3,09 -3,15 -3,52 -3,07 -3 33 -3,33 -3,31 -3,71 -3,61 -3,58 -3,63 -3,62 -3,58 3 58 -3,37 -3,52 -3,33 -3,15 -3,28 -3,25 3, 5 -3,19 -3,10 -3,23 -3,17 -3,27 -3,17 -3,26 3 26 -3,23

6,56 7,55 7,01 7,04 5,81 4,79 6 71 6,71 5,77 8,50 9,20 9,51 9,07 6,55 6,27 6 27 6,61 6,48 10,63 9,50 10,49 10,21 0, 10,14 11,05 10,38 10,52 10,37 10,18 10 06 10,06 10,20

Kleurmetingen Fynebond monsters NA veroudering

Code fumed silica F 1.1B Aerosil 200

L*A*B* SCI

AVERAGE F 11.2B 2B Aerosil 200





AVERAGE F 33.1B 1B Aerosil A il R805





AVERAGE F 4.3B 4 3B Aerosil A il R972

AVERAGE

L*

a*

SCE L*

b*

77,96 78,11 78,74 78,27 77 81 77,81 77,69 79,93 78,48 79,53 79,97 79,22 79,57 78,51 77,79 80,16 78,82 78,24 78,62 79,42 78,76 79,63 79,33 80,12 79,69 81 35 81,35 80,78 82,08 81,40 81,70 82,33 82,20 82,08 82,60 82,92 82,63 82,72 82,90 83 00 83,00 83,29 83,06 82,51 82,28 82,88 82,56 84 84,02 02 83,91 84,11 84,01

-3,31 -3,26 -3,25 -3,27 -3 27 -3,27 -3,31 -3,25 -3,28 -3,41 -3,49 -3,37 -3,42 -3,49 -3,43 -3,54 -3,49 -3,41 -3,46 3,46 -3,37 -3,41 -3,45 -3,51 -3,50 -3,49 -3,09 3 09 -3,87 -3,88 -3,61 -3,90 -3,98 -3,70 -3,86 -3,83 -3,78 -3,83 -3,81 -3,95 -3 83 -3,83 -3,79 -3,86 -3,74 -3,83 -3,70 -3,76 -3,89 3 89 -3,99 -3,78 -3,89

3

5,81 6,23 6,39 6,14 5 52 5,52 5,76 6,43 5,90 5,49 5,84 5,33 5,55 6,63 7,04 7,29 6,99 6,28 6,63 6,96 6,62 6,27 6,31 6,86 6,48 6 01 6,01 6,16 6,59 6,25 6,24 7,01 6,64 6,63 6,05 6,59 5,92 6,19 4,85 5 21 5,21 5,25 5,10 4,53 4,67 4,76 4,65 4,80 4 80 4,56 4,86 4,74

a* 75,42 75,65 76,15 75,74 75 16 75,16 75,28 77,35 75,93 77,09 77,38 76,77 77,08 79,26 75,43 78,47 77,72 76,28 77,05 76,97 76,77 77,03 76,68 77,59 77,10 79 08 79,08 79,10 79,88 79,35 79,66 80,04 80,02 79,91 80,06 80,59 80,06 80,24 80,93 81 66 81,66 81,52 81,37 80,59 80,73 80,93 80,75 82,21 82 21 81,92 82,23 82,12

b* -3,56 -3,51 -3,53 -3,53 -3 51 -3,51 -3,52 -3,50 -3,51 -3,63 -3,72 -3,58 -3,64 -3,65 -3,61 -3,67 -3,64 -3,59 -3,59 3,59 -3,59 -3,59 -3,66 -3,70 -3,71 -3,69 -4,13 4 13 -4,00 -4,10 -4,08 -4,06 -4,19 -3,86 -4,04 -4,03 -3,95 -4,03 -4,00 -4,10 -3 90 -3,90 -3,92 -3,97 -3,87 -3,93 -3,84 -3,88 -4,00 4 00 -4,13 -3,89 -4,01

6,23 6,66 6,84 6,58 6 00 6,00 6,23 6,89 6,37 5,90 6,35 5,78 6,01 7,02 7,53 7,41 7,32 6,65 6,90 7,44 7,00 6,84 6,95 7,42 7,07 6 35 6,35 6,40 6,85 6,53 6,58 7,38 7,08 7,01 6,56 7,09 6,45 6,70 5,08 5 39 5,39 5,41 5,29 4,76 4,88 4,97 4,87 5,01 5 01 4,80 5,08 4,96

Kleurmetingen Fynebond monsters NA veroudering F 5.1B Aerosil TT600



AVERAGE

91,61 91,43 91,65 91,56 91,46 91,36 91 64 91,64 91,49 91,61 91,57 91,70 91,63

-3,06 -3,06 -3,08 -3,07 -3,06 -3,02 -3 11 -3,11 -3,06 -3,08 -3,06 -3,07 -3,07

4

10,53 10,66 10,09 10,43 10,28 10,25 10 34 10,34 10,29 9,93 9,90 9,93 9,92

89,96 89,81 90,19 89,99 89,80 89,77 89 84 89,84 89,80 89,80 89,71 89,95 89,82

-3,12 -3,12 -3,14 -3,13 -3,13 -3,08 -3 17 -3,17 -3,13 -3,15 -3,13 -3,13 -3,14

10,96 11,05 10,37 10,79 10,68 10,61 10 77 10,77 10,69 10,37 10,36 10,33 10,35

Bijlage VII

Hxtal NYL‐1 monsters VOOR veroudering

Metingen Hxtal NYL-1 monsters VOOR veroudering Code H 0.1

fumed silica geen

L*A*B* SCI

AVERAGE H 0.2

geen

H 0.3

geen

AVERAGE

AVERAGE H 1.1B Aerosil 200

AVERAGE H 1.2B 1 2B Aerosil A il 200





AVERAGE H 3.1B Aerosil R805


AVERAGE

L*

a*

SCE L*

b*

92,37 92,34 92,26 92,32 91,86 92,29 92,37 92,17 92,20 92,01 92,11 92,11 77,01 76,86 78,36 77,41 75 75,93 93 74,13 77,47 75,84 75,43 74,86 77,62 75,97 74,99 73,80 75,47 74,75 76,27 73 41 73,41 73,87 74,52 76,91 76,20 78,37 77,16 76,03 74,22 75,85 75,37 78,83 77,16 75,80 77,26

-2,07 -2,05 -2,04 -2,05 -2,00 -2,04 -2,07 -2,04 -2,08 -2,07 -2,03 -2,06 -1,49 -1,54 -1,59 -1,54 -1,51 1 51 -1,45 -1,56 -1,51 -1,53 -1,50 -1,59 1,59 -1,54 -1,52 -1,49 -1,50 -1,50 -1,56 -1,44 1 44 -1,40 -1,47 -1,59 -1,56 -1,57 -1,57 -1,58 -1,60 -1,64 -1,61 -1,62 -1,66 -1,58 1,58 -1,62

1

-1,19 -1,37 -1,43 -1,33 -1,34 -1,34 -1,34 -1,34 -1,13 -1,18 -1,46 -1,26 0,38 0,19 0,30 0,29 -0,17 0 17 -0,21 0,40 0,01 -0,38 -0,50 -0,17 0,17 -0,35 0,06 -0,03 0,18 0,07 -0,09 -0,25 0 25 -0,25 -0,20 -0,21 -0,32 -0,14 -0,22 -0,51 -0,53 -0,03 -0,36 -0,17 -0,71 -0,28 0,28 -0,39

a* 88,32 88,44 88,35 88,37 87,98 88,28 88,36 88,21 88,19 88,23 88,15 88,19 74,69 74,14 75,47 74,77 74 74,02 02 71,25 74,52 73,26 73,03 72,71 74,77 73,50 72,81 71,38 73,33 72,51 73,85 71 01 71,01 72,14 72,33 74,48 73,65 75,67 74,60 73,76 71,81 73,86 73,14 76,27 75,52 73,22 75,00

b* -2,22 -2,20 -2,18 -2,20 -2,14 -2,19 -2,23 -2,19 -2,20 -2,21 -2,17 -2,19 -1,54 -1,62 -1,68 -1,61 -1,54 1 54 -1,53 -1,66 -1,58 -1,58 -1,53 -1,68 1,68 -1,60 -1,56 -1,54 -1,55 -1,55 -1,61 -1,48 1 48 -1,41 -1,50 -1,64 -1,63 -1,64 -1,64 -1,62 -1,66 -1,68 -1,65 -1,69 -1,68 -1,64 1,64 -1,67

0,98 -1,23 -1,24 -0,50 -1,18 -1,17 -1,17 -1,17 -0,95 -1,03 -1,28 -1,09 0,28 0,20 0,26 0,25 -0,21 0 21 -0,15 0,40 0,01 -0,34 -0,48 -0,16 0,16 -0,33 0,14 0,14 0,32 0,20 0,02 -0,06 0 06 -0,16 -0,07 -0,13 -0,21 -0,04 -0,13 -0,40 -0,37 -0,20 -0,32 -0,03 -0,61 -0,10 0,10 -0,25

Hxtal NYL‐1 monsters VOOR veroudering H 3.3B Aerosil R805




AVERAGE H 5.1B Aerosil TT600



AVERAGE

75,63 76,24 77,12 76,33 80,05 77,21 77 91 77,91 78,39 79,74 78,81 79,25 79,27 78,05 78 00 78,00 78,60 78,22 87,62 87,77 88,09 87,83 , 87,79 88,18 88,15 88,04 88,05 88,51 88 79 88,79 88,45

-1,68 -1,68 -1,66 -1,67 -1,77 -1,77 -1 75 -1,75 -1,76 -1,77 -1,79 -1,76 -1,77 -1,75 -1,81 1 81 -1,70 -1,75 -2,38 -2,42 -2,29 -2,36 , -2,37 -2,38 -2,42 -2,39 -2,31 -2,32 -2 37 -2,37 -2,33

2

-0,79 -1,00 -0,88 -0,89 -1,53 -1,95 -1 47 -1,47 -1,65 -1,61 -1,66 -1,51 -1,59 -1,80 -1,96 1 96 -1,79 -1,85 -3,47 -3,36 -3,14 -3,32 , -3,34 -3,34 -3,47 -3,38 -3,23 -3,16 -3 15 -3,15 -3,18

73,04 73,57 74,60 73,74 77,42 74,55 75 30 75,30 75,76 77,22 76,31 76,74 76,76 75,54 75,40 75 40 76,02 75,65 85,93 85,76 86,08 85,92 , 85,85 86,35 86,37 86,19 85,95 86,46 86 73 86,73 86,38

-1,75 -1,76 -1,73 -1,75 -1,90 -1,88 -1 84 -1,84 -1,87 -1,87 -1,88 -1,83 -1,86 -1,84 -1,90 1 90 -1,78 -1,84 -2,39 -2,46 -2,33 -2,39 , -2,41 -2,41 -2,44 -2,42 -2,36 -2,35 -2 42 -2,42 -2,38

-0,70 -0,87 -0,74 -0,77 -1,64 -1,97 -1 47 -1,47 -1,69 -1,59 -1,64 -1,45 -1,56 -1,81 -1,96 1 96 -1,87 -1,88 -3,42 -3,33 -3,11 -3,29 , -3,32 -3,32 -3,44 -3,36 -3,20 -3,13 -3 12 -3,12 -3,15

Hxtal NYL‐1 monsters VOOR veroudering

Code fumed silica H 1.1A Aerosil 200

L*A*B* SCI

AVERAGE H 11.2A 2A Aerosil 200

AVERAGE H 1.3A Aerosil 200




AVERAGE H 33.1A 1A Aerosil R805

AVERAGE H 3.2A Aerosil R805




AVERAGE H 44.3A 3A Aerosil A il R972

AVERAGE

L*

a*

SCE L*

b*

80,41 81,90 83,06 81,79 80 52 80,52 80,47 81,09 80,69 80,10 79,89 80,31 80,10 79,74 79,50 81,14 80,13 79,79 80,31 80,15 80,08 80,96 80,99 81,21 81,05 80 62 80,62 80,75 80,88 80,75 81,91 79,83 79,77 80,50 82,33 81,28 81,64 81,75 80,38 79,93 80,50 80,27 81,28 81,51 82,51 81,77 80 97 80,97 80,53 80,24 80,58

-1,58 -1,56 -1,66 -1,60 -1 55 -1,55 -1,57 -1,61 -1,58 -1,51 -1,49 -1,54 -1,51 -1,61 -1,59 -1,64 -1,61 -1,56 -1,52 1,52 -1,55 -1,54 -1,57 -1,61 -1,63 -1,60 -1,55 1 55 -1,52 -1,60 -1,56 -1,54 -1,46 -1,47 -1,49 -1,58 -1,56 -1,58 -1,57 -1,61 -1,63 1,63 -1,66 -1,63 -1,62 -1,67 -1,71 -1,67 -1,67 1 67 -1,66 -1,65 -1,66

3

0,11 -0,10 0,08 0,03 -0 10 -0,10 -0,18 -0,13 -0,14 0,03 -0,06 -0,04 -0,02 -0,16 -0,14 -0,05 -0,12 -0,06 0,07 0,22 0,08 -0,02 -0,22 -0,04 -0,09 -0,49 0 49 -0,55 -0,30 -0,45 -0,49 -0,28 0,05 -0,24 -0,36 -0,44 -0,36 -0,39 -1,30 -1,24 1,24 -0,89 -1,14 -1,06 -1,19 -1,06 -1,10 -1,16 1 16 -1,34 -1,01 -1,17

a* 78,00 79,48 80,87 79,45 77 99 77,99 78,03 78,60 78,21 77,62 77,47 77,84 77,64 77,14 76,86 78,67 77,56 77,46 78,04 77,75 77,75 78,41 78,37 78,76 78,51 78 09 78,09 78,16 79,14 78,46 79,41 77,26 77,49 78,05 79,85 78,85 79,23 79,31 78,09 77,53 78,08 77,90 78,88 79,06 80,10 79,35 78 45 78,45 78,21 77,83 78,16

b* -1,62 -1,60 -1,69 -1,64 -1 61 -1,61 -1,62 -1,67 -1,63 -1,56 -1,54 -1,58 -1,56 -1,67 -1,66 -1,68 -1,67 -1,60 -1,56 1,56 -1,59 -1,58 -1,62 -1,67 -1,68 -1,66 -1,61 1 61 -1,59 -1,61 -1,60 -1,59 -1,51 -1,51 -1,54 -1,62 -1,61 -1,62 -1,62 -1,67 -1,69 1,69 -1,72 -1,69 -1,67 -1,74 -1,77 -1,73 -1,73 1 73 -1,72 -1,71 -1,72

0,28 0,08 0,24 0,20 0 05 0,05 -0,03 0,03 0,02 0,20 0,11 0,12 0,14 -0,06 0,01 0,09 0,01 0,11 0,23 0,39 0,24 0,12 -0,09 0,11 0,05 -0,39 0 39 -0,48 -0,16 -0,34 -0,36 -0,17 0,20 -0,11 -0,25 -0,35 -0,26 -0,29 -1,26 -1,18 1,18 -0,84 -1,09 -1,02 -1,17 -1,02 -1,07 -1,12 1 12 -1,31 -0,95 -1,13

Hxtal NYL‐1 monsters VOOR veroudering H 5.1A Aerosil TT600

AVERAGE H 5.2A Aerosil TT600


AVERAGE

85,59 85,41 85,95 85,65 84,54 84,73 85 13 85,13 84,80 84,81 85,15 85,15 85,04

-2,08 -2,08 -2,10 -2,09 -2,12 -2,13 -2 17 -2,17 -2,14 -2,19 -2,21 -2,19 -2,20

4

-2,71 -2,62 -2,54 -2,62 -2,90 -2,99 -3 01 -3,01 -2,97 -2,52 -2,74 -2,60 -2,62

83,47 83,27 83,79 83,51 82,40 82,51 82 98 82,98 82,63 82,58 82,95 83,07 82,87

-2,12 -2,12 -2,14 -2,13 -2,18 -2,19 -2 22 -2,22 -2,20 -2,25 -2,28 -2,25 -2,26

-2,65 -2,56 -2,48 -2,56 -2,87 -2,95 -2 97 -2,97 -2,93 -2,45 -2,69 -2,53 -2,56

Hxtal NYL‐1 monsters NA veroudering

Metingen Hxtal NYL-1 monsters NA veroudering Code H 0.1

fumed silica geen

L*A*B* SCI

AVERAGE H 0.2

geen

H 0.3

geen

AVERAGE


AVERAGE H 1.2B 1 2B Aerosil A il 200







AVERAGE

L*

a*

SCE L*

b*

92,05 91,83 92,24 92,04 91,40 91,73 91,59 91,57 91,73 91,67 91,95 91,78 76,45 75,61 76,52 76,19 74 74,76 76 75,07 78,91 76,25 76,76 77,01 76,63 76,80 74,15 73,12 77,15 74,81 73,15 73 85 73,85 76,71 74,57 75,01 75,18 76,47 75,55 74,00 74,25 76,27 74,84 77,15 76,43 77,13 76,90

-2,50 -2,47 -2,52 -2,50 -2,31 -2,38 -2,30 -2,33 -2,45 -2,43 -2,49 -2,46 -2,17 -2,04 -2,28 -2,16 -2,24 2 24 -2,23 -2,37 -2,28 -2,45 -2,48 -2,36 2,36 -2,43 -2,08 -2,17 -2,27 -2,17 -2,12 -2,25 2 25 -2,28 -2,22 -2,22 -2,13 -2,34 -2,23 -2,33 -2,47 -2,39 -2,40 -2,46 -2,54 -2,51 2,51 -2,50

1

1,33 1,24 1,36 1,31 0,27 0,81 0,12 0,40 1,25 1,25 1,37 1,29 5,81 6,00 5,47 5,76 55,42 42 5,67 4,92 5,34 4,77 4,57 5,32 4,89 5,71 5,83 5,30 5,61 5,76 5 61 5,61 5,48 5,62 4,95 4,73 5,04 4,91 5,78 6,09 5,88 5,92 5,13 5,32 5,48 5,31

a* 87,91 87,70 87,98 87,86 87,91 87,67 87,90 87,83 87,67 87,49 87,77 87,64 73,68 72,83 74,70 73,74 72 72,17 17 72,32 76,89 73,79 76,08 75,43 74,54 75,35 71,41 71,17 74,45 72,34 70,83 73 02 73,02 74,24 72,70 72,37 72,96 73,96 73,10 71,78 73,50 73,85 73,04 74,74 73,97 75,04 74,58

b* -2,62 -2,58 -2,65 -2,62 -2,41 -2,50 -2,39 -2,43 -2,57 -2,58 -2,62 -2,59 -2,29 -2,17 -2,33 -2,26 -2,37 2 37 -2,33 -2,43 -2,38 -2,44 -2,52 -2,43 2,43 -2,46 -2,19 -2,22 -2,40 -2,27 -2,21 -2,24 2 24 -2,37 -2,27 -2,32 -2,20 -2,45 -2,32 -2,42 -2,46 -2,50 -2,46 -2,55 -2,66 -2,57 2,57 -2,59

1,62 1,45 1,65 1,57 0,53 1,05 0,37 0,65 1,51 1,51 1,62 1,55 6,15 6,44 5,53 6,04 5,83 5 83 6,11 4,98 5,64 4,71 4,69 5,59 5,00 6,20 6,19 5,73 6,04 6,22 5 66 5,66 5,87 5,92 5,39 5,09 5,44 5,31 6,22 6,24 6,40 6,29 5,55 5,77 5,89 5,74

Hxtal NYL‐1 monsters NA veroudering H 3.3B Aerosil R805







AVERAGE

75,96 77,73 75,61 76,43 77,55 77,71 78 72 78,72 77,99 77,60 77,83 78,99 78,14 76,63 75 98 75,98 77,50 76,70 87,93 87,80 88,21 87,98 , 89,23 89,08 89,18 89,16 89,01 88,80 80 88 80,88 86,23

-2,43 -2,55 -2,43 -2,47 -2,69 -2,70 -2 73 -2,73 -2,71 -2,66 -2,72 -2,69 -2,69 -2,64 -2,60 2 60 -2,62 -2,62 -3,24 -3,13 -3,26 -3,21 , -3,31 -3,30 -3,31 -3,31 -3,32 -3,27 -3 27 -3,27 -3,29

2

4,95 4,97 4,78 4,90 5,20 5,73 5 46 5,46 5,46 5,70 5,78 5,64 5,71 4,71 4,40 4 40 4,85 4,65 4,31 4,44 4,15 4,30 , 4,24 0,33 4,22 2,93 3,90 3,79 3 89 3,89 3,86

74,14 75,45 73,34 74,31 74,95 75,38 76 20 76,20 75,51 75,13 75,82 76,56 75,84 74,10 73,43 73 43 74,70 74,08 85,95 86,19 86,15 86,10 , 87,24 87,31 87,14 87,23 86,99 86,79 86 90 86,90 86,89

-2,49 -2,66 -2,52 -2,56 -2,85 -2,83 -2 88 -2,88 -2,85 -2,79 -2,81 -2,83 -2,81 -2,79 -2,74 2 74 -2,77 -2,77 -3,31 -3,16 -3,34 -3,27 , -3,36 -3,35 -3,38 -3,36 -3,30 -3,36 -3 33 -3,33 -3,33

5,28 5,35 5,19 5,27 5,56 6,06 5 73 5,73 5,78 6,18 6,18 6,03 6,13 5,08 4,76 4 76 5,24 5,03 4,65 4,71 4,48 4,61 , 4,55 4,65 4,54 4,58 4,20 4,11 4 18 4,18 4,16

Hxtal NYL‐1 monsters NA veroudering

Code fumed silica H 1.1A Aerosil 200

L*A*B* SCI

AVERAGE H 11.2A 2A Aerosil 200





AVERAGE H 33.1A 1A Aerosil R805





AVERAGE H 44.3A 3A Aerosil A il R972

AVERAGE

L*

a*

SCE L*

b*

79,30 79,19 79,76 79,42 79 15 79,15 79,76 80,01 79,64 79,37 80,10 80,03 79,83 78,06 78,48 79,67 78,74 78,50 79,35 79,51 79,12 79,75 80,57 80,21 80,18 79 42 79,42 78,84 79,87 79,38 81,64 82,19 81,43 81,75 82,22 81,95 82,31 82,16 78,42 79,88 79,26 79,19 79,71 80,08 80,62 80,14 80 54 80,54 80,63 81,16 80,78

-2,21 -2,19 -2,30 -2,23 -2 26 -2,26 -2,35 -2,32 -2,31 -2,23 -2,27 -2,28 -2,26 -2,19 -2,18 -2,30 -2,22 -2,14 -2,24 2,24 -2,26 -2,21 -2,23 -2,22 -2,34 -2,26 -2,27 2 27 -2,30 -2,32 -2,30 -2,34 -2,42 -2,35 -2,37 -2,35 -2,35 -2,37 -2,36 -2,46 -2,63 2,63 -2,47 -2,52 -2,49 -2,54 -2,53 -2,52 -2,54 2 54 -2,52 -2,55 -2,54

3

6,93 7,60 7,03 7,19 6 32 6,32 6,55 6,16 6,34 6,25 6,58 6,42 6,42 5,40 6,20 5,29 5,63 6,50 6,67 6,34 6,50 5,46 5,10 6,16 5,57 5 99 5,99 6,26 6,07 6,11 5,82 6,03 6,04 5,96 5,44 5,75 5,41 5,53 6,00 5,82 5,84 5,89 5,92 5,87 5,95 5,91 5 25 5,25 5,02 5,73 5,33

a* 76,75 76,72 77,21 76,89 76 52 76,52 77,20 77,39 77,04 76,78 77,54 77,46 77,26 75,33 75,80 76,93 76,02 76,05 76,85 76,94 76,61 77,20 77,90 77,73 77,61 76 99 76,99 77,57 77,47 77,34 79,08 79,64 78,93 79,22 79,67 79,53 79,77 79,66 75,97 77,68 76,78 76,81 77,17 77,56 78,13 77,62 78 02 78,02 78,09 78,72 78,28

b* -2,31 -2,26 -2,39 -2,32 -2 33 -2,33 -2,43 -2,41 -2,39 -2,31 -2,36 -2,38 -2,35 -2,31 -2,27 -2,40 -2,33 -2,22 -2,34 2,34 -2,35 -2,30 -2,31 -2,32 -2,42 -2,35 -2,38 2 38 -2,32 -2,41 -2,37 -2,42 -2,50 -2,44 -2,45 -2,44 -2,45 -2,46 -2,45 -2,56 -2,73 2,73 -2,58 -2,62 -2,60 -2,65 -2,66 -2,64 -2,65 2 65 -0,65 -2,65 -1,98

7,47 8,18 7,59 7,75 6 84 6,84 7,05 6,66 6,85 6,77 7,13 6,96 6,95 5,81 6,68 5,66 6,05 6,97 7,18 6,86 7,00 5,92 5,55 6,64 6,04 6 46 6,46 6,52 6,49 6,49 6,27 6,51 6,51 6,43 5,82 6,13 5,80 5,92 6,46 6,21 6,30 6,32 6,36 6,29 6,37 6,34 5 62 5,62 5,38 6,11 5,70

Hxtal NYL‐1 monsters NA veroudering H 5.1A Aerosil TT600



AVERAGE

84,71 84,88 85,18 84,92 83,59 83,65 84 17 84,17 83,80 84,34 84,46 84,46 84,42

-3,15 -3,14 -3,14 -3,14 -3,21 -3,16 -3 23 -3,23 -3,20 -3,24 -3,22 -3,22 -3,23

4

5,58 6,14 5,79 5,84 5,09 5,43 5 03 5,03 5,18 5,02 4,72 5,09 4,94

82,48 82,67 82,96 82,70 81,31 81,40 81 91 81,91 81,54 82,06 82,18 82,21 82,15

-3,25 -3,23 -3,24 -3,24 -3,32 -3,26 -3 33 -3,33 -3,30 -3,34 -3,33 -3,34 -3,34

6,02 6,60 6,25 6,29 5,51 5,85 5 45 5,45 5,60 5,45 5,12 5,50 5,36

Bijlage VIII

Fumed silica - en zijn invloed op de veroudering en verkleuring van epoxy lijmen.

Araldite 2020, verzadigt. Foto’s na verouderen

Puur

Aerosil 200

Aerosil 300

Aerosil R805

Aerosil R972

Aerosil TT600

Manshanden, UvA, 2013

Araldite 2020 Na veroudering

A 0.1—A 0.3Araldite 2020 puur

A 5.1B—A 5.3BAraldite 2020 met Aerosil TT600, verzadigt


A 1.1B—A 1.3BAraldite 2020 met Aerosil 200, verzadigt

A 2.1B—A 2.3BAraldite 2020 met Aerosil 300, verzadigt


A 3.1B—A 3.3BAraldite 2020 met Aerosil R805, verzadigt

A 4.1B—A 4.3BAraldite 2020 met Aerosil R972, verzadigt

Bijlage IX


Epo-Tek 301-2, verzadigt. Foto’s na verouderen

Puur

Aerosil 200

Aerosil 300

Aerosil R805

Aerosil R972

Aerosil TT600


Epo-Tek 301-2 Na veroudering

E 0.1—E0.3 Epo-Tek 301-2 puur

E 5.1B-E 5.3B Epo-Tek 301-2 met Aerosil TT600, verzadigt


E 1.1B—E1.3B Epo-Tek 301-2 met Aerosil 200, verzadigt

E 2.1B-E 2.3B Epo-Tek 301-2 met Aerosil 300, verzadigt


E 3.1B—E 3.3B Epo-Tek 301-2 met Aerosil R805, verzadigt

E 4.1B-E 4.3B Epo-Tek 301-2 met Aerosil R972, verzadigt

Bijlage X


Fynebond, verzadigt. Foto’s na verouderen

Puur

Aerosil 200

Aerosil 300

Aerosil R805

Aerosil R972

Aerosil TT600



Fynebond A-monsters. Foto’s na verouderen

Puur

Aerosil 200

Aerosil 300

Aerosil R805

Aerosil R972

Aerosil TT600


Fynebond. Na veroudering

F 0.1– F 0.3 Fynebond puur

F 5.1B-F 5.3B Fynebond met Aerosil TT600, verzadigt


F 1.1B– F 1.3B Fynebond met Aerosil 200, verzadigt

F 2.1B-F 2.3B Fynebond met Aerosil 300, verzadigt


F 3.1B– F 3.3B Fynebond met Aerosil R805, verzadigt

F 4.1B-F 4.3B Fynebond met Aerosil R972, verzadigt


F 1.1A– F 1.3A Fynebond met Aerosil 200

F 2.1A-F 2.3A Fynebond met Aerosil 300


F 3.1A– F 3.3A Fynebond met Aerosil R805

F 4.1A-F 4.3A Fynebond met Aerosil R972


F 5.1A– F 5.3A Fynebond met Aerosil TT600

Bijlage XI


Hxtal NYL-1, verzadigt. Foto’s na verouderen

Puur

Aerosil 200

Aerosil 300

Aerosil R805

Aerosil R972

Aerosil TT600



Hxtal NYL-1, A-monsters. Foto’s na verouderen

Puur

Aerosil 200

Aerosil 300

Aerosil R805

Aerosil R972

Aerosil TT600


Hxtal NYL-1. Na veroudering

H 0.1-H 0.3 Hxtal NYL-1 puur

H 5.1B– H5.3B Hxtal NYL-1 met Aerosil TT600, verzadigt


H 1.1B-H 1.3B Hxtal NYL-1 met Aerosil 200, verzadigt

H 2.1B– H2.3B Hxtal NYL-1 met Aerosil 300, verzadigt


H 3.1B-H 3.3B Hxtal NYL-1 met Aerosil R805 verzadigt

H 4.1B– H4.3B Hxtal NYL-1 met Aerosil R972, verzadigt


H 1.1A-H 1.AB Hxtal NYL-1 met Aerosil 200

H 2.1A– H2.3A Hxtal NYL-1 met Aerosil 300


H 3.1A-H 3.3A Hxtal NYL-1 met Aerosil R805

H 4.1A– H4.3A Hxtal NYL-1 met Aerosil R972


H 5.1A– H 5.3A Hctal NYL-1 met Aerosil TT600

Bijlage XII

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET ARALDITE 2020

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Product name Product code Product description

: ARALDITE 2020 : 00050782 : Not available.

1.2 Relevant identified uses of the substance or mixture and uses advised against Product use : 2-Component adhesive system 1.3 Details of the supplier of the safety data sheet Supplier : Huntsman Advanced Materials (Europe)BVBA Everslaan 45 3078 Everberg / Belgium Tel.: +41 61 299 20 41 Fax: +41 61 299 20 40 e-mail address of person responsible for this SDS

: [email protected]

1.4 Emergency telephone number Supplier Telephone number : EUROPE: +32 35 75 1234 France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : Working pack (preparation) Classification according to Directive 1999/45/EC [DPD] The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification : Xn; R20/21/22 C; R34 R43 N; R51/53 Human health hazards

: Harmful by inhalation, in contact with skin and if swallowed. Causes burns. May cause sensitisation by skin contact.

: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms. Environmental hazards

2.2 Label elements

Date of issue / Date of revision : 1/24/2011.

1/16

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - United Kingdom (UK) ARALDITE 2020 Date of printing : 24 January 2011 MSDS no. Date of issue : 24 January 2011 Version

2/16 : 00050782 : 1

SECTION 2: Hazards identification Hazard symbol or symbols

:

Indication of danger Risk phrases

: Corrosive, Dangerous for the environment : R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R34- Causes burns. R43- May cause sensitisation by skin contact. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Safety phrases

: S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S61- Avoid release to the environment. Refer to special instructions/safety data sheet.

Hazardous ingredients

: reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) butanedioldiglycidyl ether isophorone diamine trimethylhexamethylenediamine : Not applicable.

Supplemental label elements

: Contains epoxy constituents. See information supplied by the manufacturer.

Supplemental label elements

Special packaging requirements Containers to be fitted : Not applicable. with child-resistant fastenings Tactile warning of danger 2.3 Other hazards Other hazards which do not result in classification

: Not applicable.

: Not available.

SECTION 3: Composition/information on ingredients Substance/mixture

: Working pack (preparation) Classification

Product/ingredient name

Identifiers

%

reaction product: bisphenol A(epichlorhydrin); epoxy resin (number average molecular weight < 700) butanedioldiglycidyl ether

REACH #: 012119456619-26 CAS: 25068-38-6

35-50

CAS: 2425-79-8

25-35

Xn; R20/21 Xi; R36/38 R43 R52/53

isophorone diamine

CAS: 2855-13-2

7-10

Xn; R21/22 C; R34


67/548/EEC

Regulation (EC) No. 1272/2008 [CLP]

Xi; R36/38

Skin Irrit. 2, H315

R43 N; R51/53

Eye Irrit. 2, H319 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 Acute Tox. 4, H302 Acute Tox. 4, H312

Type [1]

[1]

[1]

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SECTION 3: Composition/information on ingredients

trimethylhexamethylenediamine

CAS: 25620-58-0

5-7

R43 R52/53

Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Chronic 3, H412

Xn; R22 C; R34 R43 R52/53

Acute Tox. 4, H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Chronic 3, H412

See section 16 for the full text of the Rphrases declared above

[1]

See Section 16 for the full text of the H statements declared above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Type [1] Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII [4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures 4.1 Description of first aid measures Eye contact : Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Inhalation

: Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.

Skin contact

: Get medical attention immediately. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse.

Ingestion

: Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway.


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SECTION 4: First aid measures Protection of first-aiders

Loosen tight clothing such as a collar, tie, belt or waistband. : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact : Corrosive to eyes. Causes burns. Inhalation : Harmful by inhalation. May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact : Corrosive to the skin. Causes burns. Harmful in contact with skin. May cause sensitisation by skin contact. Ingestion : Harmful if swallowed. May cause burns to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion

: Adverse symptoms may include the following: stomach pains

4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : Symptomatic treatment and supportive therapy as indicated. Following severe exposure the patient should be kept under medical review for at least 48 hours.

SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media

: Use an extinguishing agent suitable for the surrounding fire. : None known.

5.2 Special hazards arising from the substance or mixture Hazards from the : In a fire or if heated, a pressure increase will occur and the container may burst. substance or mixture Hazardous thermal decomposition products

: Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides

5.3 Advice for firefighters Date of issue / Date of revision : 1/24/2011.

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SECTION 5: Firefighting measures Special precautions for fire-fighters

: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.

Special protective equipment for fire-fighters

: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from personnel entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also Section 8 for additional information on hygiene measures. 6.2 Environmental precautions

: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities.

6.3 Methods and materials for containment and cleaning up Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill

6.4 Reference to other sections

: Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. : See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling


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SECTION 7: Handling and storage Protective measures

: Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. Avoid release to the environment. Refer to special instructions/safety data sheet. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general occupational hygiene

: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s) Recommendations Industrial sector specific solutions

: Store between the following temperatures: 2 to 40°C (35.6 to 104°F). Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.

: Not available. : Not available.

SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters Occupational exposure limits No exposure limit value known.

Recommended monitoring procedures

: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Derived effect levels No DELs available. Predicted effect concentrations No PECs available.

8.2 Exposure controls


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SECTION 8: Exposure controls/personal protection Appropriate engineering controls

: Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Individual protection measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Eye/face protection

Skin protection Hand protection

: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Material of gloves for long term application (BTT>480min):

: butyl rubber, Ethyl Vinyl Alcohol Laminate (EVAL)

Material of gloves for short term/splash application (10min
: nitrile rubber

(BTT = Break Through Time)

Use gloves approved to relevant standards e.g. EN 374 (Europe), F739 (US). Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Additional information can be found for instance at www.gisbau.de. Body protection

Other skin protection

: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection

: In case of inadequate ventilation wear respiratory protection. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Environmental exposure controls

: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : Liquid. Colour : Not available. Odour : Not available. Odour threshold : Not available. pH Melting point/freezing point



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SECTION 9: Physical and chemical properties Initial boiling point and boiling : Not available. range Closed cup: >120°C [DIN 51758 EN 22719 (Pensky-Martens Closed Cup)] Not available. Not available. Not applicable. Not applicable. Not available.

Flash point Evaporation rate Flammability (solid, gas) Burning time Burning rate Upper/lower flammability or explosive limits

: : : : : :

Vapour pressure Vapour density Relative density Solubility(ies) Water solubility

: Not available. : Not available. : Not available.

Partition coefficient: noctanol/water

: Not available.

Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties

: : : : :

9.2 Other information Density

:

Not available. Not available. Not available. Not available. Not available.

: 1.1 g/cm3 [20°C (68°F)]

SECTION 10: Stability and reactivity 10.1 Reactivity

: No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

: The product is stable.

10.3 Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

: No specific data.

10.5 Incompatible materials

: No specific data.

10.6 Hazardous decomposition products

: Under normal conditions of storage and use, hazardous decomposition products should not be produced.


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SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product/ingredient name

Endpoint

reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700)

Species Rat - Male

0.00001 ppm

5 hours

LD50 Dermal

Rat - Male, Female Rat - Female Rat - Male, Female Rat - Male, Female

>2000 mg/kg

-

>2000 mg/kg >2150 mg/kg

-

1163 mg/kg

-

LD50 Oral Irritation/Corrosion Conclusion/Summary Sensitiser

: Not available.

Product/ingredient name reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) butanedioldiglycidyl ether isophorone diamine

Conclusion/Summary Mutagenicity

Test

butanedioldiglycidyl ether

Conclusion/Summary Carcinogenicity Product/ingredient name

Route of exposure

OECD 429 Skin Sensitisation: Local Lymph Node Assay OECD 406 Skin Sensitization Data based on tests on similar product

Species

Result

skin

Mouse

Sensitising

skin

Guinea pig

Sensitising

skin

Guinea pig

Sensitising

: Not available.

Product/ingredient name reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700)

Exposure

LC0 Inhalation Vapour

LD50 Oral LD50 Dermal


Result

Test

Result

-

Positive

OECD 471 Bacterial Reverse Mutation Test OECD 473 In vitro Mammalian Chromosomal Aberration Test OECD 474 Mammalian Erythrocyte Micronucleus Test

Positive Negative Negative Positive Positive Negative

: Not available. Test


Species

Exposure

Result

Route of exposure

Target organs

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SECTION 11: Toxicological information reaction product: OECD 453 Combined Chronic Rat bisphenol AToxicity/Carcinogenicity (epichlorhydrin); epoxy Studies resin (number average molecular weight < 700) OECD 453 Combined Chronic Rat Toxicity/Carcinogenicity Studies OECD 453 Combined Chronic Mouse Toxicity/Carcinogenicity Studies

2 years; 7 Negative days per week

Oral

-

2 years; 5 Negative days per week 2 years; 3 Negative days per week

Dermal

-

Dermal

-

Reproductive toxicity Product/ingredient name reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700)

Test OECD 416 Two-Generation Reproduction Toxicity Study

Species Rat

Result/Result type Oral: 540 mg/kg NOEL :

Target organs -

Teratogenicity Product/ingredient name reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700)

Test

Species

OECD 414 Prenatal Developmental Rat - Female Toxicity Study

>540 mg/kg NOEL :

-

>300 mg/kg NOEL :

Rabbit Female OECD 414 Prenatal Developmental Rabbit Toxicity Study Female Information on the likely routes of exposure

Result/Result type

180 mg/kg NOAEL

: Not available.

Potential acute health effects Inhalation : Harmful by inhalation. May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Ingestion : Harmful if swallowed. May cause burns to mouth, throat and stomach. Skin contact : Corrosive to the skin. Causes burns. Harmful in contact with skin. May cause sensitisation by skin contact. Eye contact : Corrosive to eyes. Causes burns. Symptoms related to the physical, chemical and toxicological characteristics Inhalation : No specific data. Ingestion : Adverse symptoms may include the following: stomach pains Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur Eye contact

: Adverse symptoms may include the following: pain watering redness

Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure


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SECTION 11: Toxicological information Potential immediate effects

: Not available.

Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Potential chronic health effects Product/ingredient name

Test

Result type


OECD 408 Repeated Dose 90-Day Oral Toxicity Study in Rodents

NOAEL

Subchronic NOAEL Oral Subchronic NOEL : Dermal Subchronic NOAEL Dermal Subchronic NOAEL Oral

OECD 411 Subchronic NOEL : Dermal Toxicity: 90-day Study

OECD 411 Subchronic NOAEL Dermal Toxicity: 90-day Study

Target organs

50 mg/kg

-

10 mg/kg

-

100 mg/kg

-

200 mg/kg

-


OECD 407 Repeated Dose 28-day Oral Toxicity Study in Rodents

Conclusion/Summary General

: Not available. : Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : Not available.

Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects Other information

NOAEL

Result

SECTION 12: Ecological information 12.1 Toxicity Product/ingredient name

Test

Endpoint


-

Acute

OECD 202 Daphnia sp. Acute Acute Immobilisation Test Acute


Exposure Species

EC50 72 hours Algae Static

EC50 48 hours Static IC50 3 hours Static OECD 203 Fish, Acute Acute LC50 96 hours Toxicity Test Static Chronic NOEC 21 days OECD 211 Daphnia Magna Reproduction Test Semistatic OECD 202 Daphnia sp. Acute Acute EC50 24 hours Static Immobilisation Test OECD 201 Alga, Growth Acute EL50 72 hours


Result 9.4

mg/L

Daphnia

1.7

mg/L

Bacteria

>100

mg/L

Fish

1.5

mg/L

Daphnia

0.3

mg/L

Daphnia

75

mg/L

Algae

>160

mg/L 11/16


12/16 : 00050782 : 1

SECTION 12: Ecological information Inhibition Test OECD 209 Activated Sludge, Respiration Inhibition Test OECD 203 Fish, Acute Toxicity Test

Acute Acute

Static IC50 3 hours Bacteria Static LC50 96 hours Fish Static

>100

mg/L

24

mg/L

12.2 Persistence and degradability Product/ingredient name reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) butanedioldiglycidyl ether

Test OECD Derived from OECD 301F (Biodegradation Test)

Period 28 days

Result 5%

OECD 301F Ready Biodegradability Manometric Respirometry Test

28 days

43 %

Conclusion/Summary

: reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700): Not readily biodegradable.

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) butanedioldiglycidyl ether

Fresh water 4.83 days Fresh water 3.58 days Fresh water 7.1 days

-

Not readily

-

-

Not readily

12.3 Bioaccumulative potential Product/ingredient name

LogPow

BCF

Potential

reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700) butanedioldiglycidyl ether

3.242

31

low

-0.269

-

low

12.4 Mobility in soil Soil/water partition coefficient (KOC) Mobility


12.5 Results of PBT and vPvB assessment Not applicable. 12.6 Other adverse effects

: No known significant effects or critical hazards.

12.7 Other ecological information


12/16


13/16 : 00050782 : 1

SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Hazardous waste : Yes. European waste catalogue (EWC) Waste code

Waste designation

07 02 08*

other still bottoms and reaction residues

Packaging Methods of disposal

Special precautions

: The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. : This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information 14.1 UN number ADR/RID UN2289 ADN/ADNRnot available IMDG UN2289

IATA

UN2289

14.2 UN proper shipping name ISOPHORONEDIAMINE SOLUTION not available ISOPHORONEDIAMINE SOLUTION (BISPHENOL A EPOXY RESIN). Marine pollutant (reaction product: bisphenol A-(epichlorhydrin); epoxy resin (number average molecular weight < 700)) ISOPHORONEDIAMINE SOLUTION ADR/RID

ADN/ADNR

IMDG

IATA

14.3 Transport hazard class(es)

8

8

8

14.4 Packing group

III

III

III

14.5 Environmental hazards

Yes.

Yes.

Yes.

14.6 Special precautions for user

Not available.

Not available.

Not available.


13/16


14/16 : 00050782 : 1

SECTION 14: Transport information Additional information

Hazard identification number 80

Emergency schedules (EmS) F-A, S-B

Tunnel code E

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Passenger and Cargo Aircraft Quantity limitation: 5 L Packaging instructions: 818 Cargo Aircraft Only Quantity limitation: 60 L Packaging instructions: 820

: Not applicable.

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Substances of very high concern None of the components are listed. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other EU regulations Europe inventory Black List Chemicals Priority List Chemicals Integrated pollution prevention and control list (IPPC) - Air Integrated pollution prevention and control list (IPPC) - Water National regulations References

: : : :

All components are listed or exempted. Not listed Not listed Not listed

: Not listed

: The provision of Safety Data Sheets comes under Regulation 6 of CHIP (CHIP is the recognised abbreviation for the Chemicals Hazard Information and Packaging Regulations). This is an addition to the Health and Safety at Work Act 1974.

International regulations Chemical Weapons Convention List Schedule I Chemicals

: Not listed

Chemical Weapons Convention List Schedule II Chemicals

: Not listed


14/16


15/16 : 00050782 : 1

SECTION 15: Regulatory information Chemical Weapons Convention List Schedule III Chemicals

: Not listed

: This product contains substances for which Chemical Safety Assessments are still required.

15.2 Chemical Safety Assessment

SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. acronyms 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification Acute Tox. 4, H302 Acute Tox. 4, H312 Acute Tox. 4, H332 Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Chronic 2, H411 Full text of abbreviated H statements

Full text of classifications [CLP/GHS]

Justification Expert judgment Expert judgment On basis of test data Expert judgment Expert judgment Expert judgment Expert judgment

Harmful if swallowed. : H302 H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. ACUTE TOXICITY: ORAL - Category 4 : Acute Tox. 4, H302 Acute Tox. 4, H312 ACUTE TOXICITY: SKIN - Category 4 Acute Tox. 4, H332 ACUTE TOXICITY: INHALATION - Category 4 Aquatic Chronic 2, H411 AQUATIC TOXICITY (CHRONIC) - Category 2 Aquatic Chronic 3, H412 AQUATIC TOXICITY (CHRONIC) - Category 3 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2 Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1


15/16


16/16 : 00050782 : 1

SECTION 16: Other information Full text of abbreviated R phrases

: R22- Harmful if swallowed. R20/21- Harmful by inhalation and in contact with skin. R20/21/22- Harmful by inhalation, in contact with skin and if swallowed. R21/22- Harmful in contact with skin and if swallowed. R34- Causes burns. R36/38- Irritating to eyes and skin. R43- May cause sensitisation by skin contact. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Full text of classifications [DSD/DPD]

: C - Corrosive Xn - Harmful Xi - Irritant N - Dangerous for the environment

MSDS no. Date of printing Date of issue/ Date of revision

: 00050782 : 1/24/2011. : 1/24/2011.

Date of previous issue : No previous validation. Version : 1 Notice to reader While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE. IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE. THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST. Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users. NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT THE ABOVE ADDRESS.


16/16

Bijlage XIII

Bijlage XIV

aYnev:err:i Fyne Conse rvation Serylces St

Catherine's, Argyll PA2S BBA, Scoiland.

Tel:Fax: 44 (0)141 357 4107

FYNEBOND SAFETY DATA SHEET PART

1.

1:

RESIN

COMPOSTTTON

Liquid epoxy resin of the Bisphenol A, epichlorohydrin type (Mn <= 700), specifically Bis (4-(2,3-epoxpropoxy) phenyl ) propane

2.

HAZARDS IDENTIFICATION

lrritating to eyes and skin. May cause sensitization by skin contact. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

3.

FIRST AID MEASURES

Never give fluids or induce vomiting if patient is unconscious or is having convulsions.

lnhalation. Remove to fresh air if effects occur. Consult a physician.

Skin Contact immediately flush with plenty of water Ícr at least 15 minutes while removing contaminated clothing. Remove residues with soap and water. Call a physician if irritation persists. Eye Contact lrrigate immediately with water for a least 5 minutes. consult medical personnel.

lngestion The decision of whether to induce vomiting or not should be made by an attending physician. Note to Physician No specific antidote' Treatment based on judgement of the physician in response to reactions of the patient.

4.

FIRE.FIGHTING MEASURES

Extinguishing Media Carbon dioxide. Dry chemical. Foam. Hazardous Com bustion products Under conditions oÍ incomplete combustion or pyrolysis, phenolics and carbon oxides may be evolved. The thermal decomposition products therefore should be treated as potentially hazardous substances and appropriate precautions should be taken.

Protection of Firefighters wear positive-pressure, seif-contained breathing apparatus and protective Íire fighting clothing (includes fire Íighting helmet, coat, trousers, boots and glovesf Specific Fire or Explosion Hazards Non-flammable product

Page one of four

5.

ACCIDENTAL RELEASE MEASURES

Personal Precautions Wear adequate personal protective equipment, see Section 7.

Environmental Precautions Prevent from entering into soil, waterways and groundwater. Flushings and wash waters must be confined and prevented from entering into soil, waterways and ground water.

Methods of Cleaning Up Soak up with absorbent material such as sand and collect in suitable containers. Solvents are not recommended for clean-up uniess the recommended exposure guidelines and safe handling practices for the specific solvent are followed. Residual product may be removed using steam or hot soapy water.

6.

IIANDLING AND STORAGE

Practise care and caution to avoid skin and eye contact. Avoid breathing vapours of heated material.

7.

EXPOSURECONTROLS/PERSONALPROTECTION

Exposure Guidelines None established.

Engineering Controls Good general ventilation should be sufficient for most conditions.

Personal Protective Equipment - Respiratory Protection No respiratory protection should be needed. - Skin Protection

For brieÍ contact, no precautions other than clean body-covering clothing should be needed. Use impervious gloves when prolonged or frequently repeated contact couid occur. Remove contaminated clothing no later than at the end of the work period and launder beÍore reuse. - Eye/Face Protection Use safety glasses. Where contact with this material is likely, chemical goggles are recommended because

eye contact with this material may cause discomfort even though it is unlikely to cause injury.

8.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance. Colour. Odour: Specific gravity: Vapour pressure: Boiling poinUrange.

liquid to semi-solid colourless

Íaint epoxy 1.1-1.18

not determined decomposes prior to boiling -15 to 5 oC

Freezing poinUrange: Water solubility: none Flash point. 252oC (PMCC) >300 oC Auto-ignition temp: Flammability. not determined

Page two of four

9.

STABILITY AND REACTIVITY

Chem ical Stabilíty Stable under normal storage conditions.

Conditions to Avoid Excessive heating over long periods of time degrades the product (causing discolouration).

Materials to Avoid Acids, amines, bases and oxidising agents.

Hazardous Polym erisation HazardoLls polymerisation will not occur by itself, but masses of more that 0.5 kg of product, plus an aliphatic amine will cause irreversible polymerisation with considerable heat build up.

ÏOXICOLOGICAL INFORMATION

10.

Acute toxicity - lngestion The oral LD5g for rats Ís expected to be >2000 mglkg. Single dose oral toxicity is believed hazards anticipated from swallowing small amounts incídental to normal handling.

to be 1ow.

No

- Skin Gontact

A single prolonged exposure is not likely to result in the material being absorbed through skin in amounts. The LD5g for skin absorption in rabbits is believed to be >2000 mg/kg.

harmful

- lnhalation Vapours are unlikely due to physical properUes.

lrritation - Skin Repeated exposure may cause skin irritation and, in some workers, sensitisation

- Eyes May cause slight transient (temporary) eye irrltation.

Sensitisation Has caused allergic skin reaction in humans.

Carcinogenicity Several studies have been conducted to assess the potential carcinogenicity of diglycidyl ether of Bisphenol A (DGEBPA)-based epoxy resins. ln one of these, a DGEBPA-based resin-lcontàláing'nigh levels oÍ several impurities, including a known animal skin carcinogen) was reported to produce r wea[ caicinogenic response in the skin of one of two strains of mice tested. Recent studies have suggested slight increases i-n two systemic tumour types Íollowing repeated application of certain DGEBPA-contaiÀing resinslor pure DGEBpA), aittrougn the response was not uniform among practically identical resins. Basedtn these djta, and the other studies which have not shown cancer, the cause-efÍect relationship between DGEBpA-treatment and these tumour increases is questionable. lndeed, a recent review of the available data by the lnternationai Agency for Research on Cancer (IRAC) has concluded that DGEBPA is not classifiable as tb its carcinogenicity.

11.

ECOLOGICAT I ]NFORMATION

Degradation Biodegradation under aerobic conditions is below detectable limits

Page three of four

Aquatic Toxicity Material is expected to be very toxic to aquaiic organisms

12,

DISPOSAL CONSIDERATIONS

Disposal The recommended procedure for disposing of waste products is burning under carefully controlled conditions, carried out by operators experienced in chemical disposal. Burn in an adequate incinerator or bury in an approved landfill in compliance with applicable regulations. Avoid contamination of soil and ground water. Wastes or Residues Check iocal legislation governing the disposal of hazardous chemical waste.

Ïhe information herein is given in good faith and to the best of our knowledge but implied, is made.

Page four of Íour

no warranty, express or

e Con se rvation Seryrces

Fyn St

Catheríne's, ArgytÍ pA25 8BA, Scoiland.

Tel:Fax: 44

e)141 357 4107

FYNEBOND SAFETY DATA SHEEÏ PARï 2: HARDENER

1.

coMPOSlTloN

['":ïff:l:::1,"*ïf ;:J'Jfi'ffi1 5i'il3?,ÊTJ,"i,::ïy;#,[ïï,"",ï:i:il,,l 2.

whose amine groups are

HMARDS IDENTIFICATION

1ïgïlH:ltffii;t:,"I'Jr?:i"L'H',ï"d 3.

causes burns to eves and skin May

".u,"

orinoness May

FIRST AID MEASURES

lnhalatÍon Remove to fresh air if effects

occur. rf not breathing

,

appryartificial respiration.

Skin Contact lf drenched, remove contaminated clothing. Frush exposed areas wíth water. Eye Contact Frush thoroughry with water for a least 15 minutes. Get immediate medicar attention.

lngestion Do NOT induce vomiting. Give large quantities of water. Get medicar attentÍon-

4.

FIRE-FIGHTING MEASURES

Extinguishing Media

Water spray, dry powder, foam or carbon dioxide

Combustion products Ammonia and oxides of carbon may be formed on burning in limited air supply

5.

PERSONAL & ENVIRONMENTAL PROTECTION

Personal precautions Wear adequate personal protective equipment. Environm ental precautions

3':Jot"TtJl:ï"ï{ffi#l::"t 6.

the soil' Dispose or in accordance with rocar raws and regurations governins

HANDLING AND STORAGE

Page one of two

7.

EXPOSURE CONïROLS / PERSONAL PROTECTION

Exposure GuÍdelínes None established.

Personal Protective Equipment l - Respiratory Protection No respiratory protection should be ne'eded - Skin

Protection

:

'

For brief contact, no precautions other than clean body-covering clothing should be needed. Use impervious gloves when prolonged or frequently repeated contacf could oCcur. Remove contaminated clothing no later than at the end of the work period and launder before re-use. - Eye/Face Protection Use safety glasses. Where contact with this material is likely, chemical goggles are recommended

8.

PHYSICAL AND CHEMICAL PROPERTIES

Appearance Odour Specific gravity (20'C) Vapour pressure, mm Hg/oC pH, 5%o aqueous solution Flash point, PMCC 9.

_

colourless liquid faínt amine pungency 0.9480 11101;101133 11.7

i21oc

STABILIry AND REACTIVITY

Chem ical

Stability

Stable under normal storage conditions.

10.

TOXICOLOGICAL INFORMATION

The single oral dose LDrg value in rats is 1 oogl(g and the single dermal LDso value in rabbits is 0.76glkg. The Draize score for skin irritation in rabbits is 8.0/8.0 and the pioduct has beeï determined to be corrosive to the skin by the D'O-T. 4-hour test. The Draize score Íor eye irritation in the rabbit is estimated to be g0110t110.0

lrritation - Skin

corrosive: treat as expecting skin damage with burns and blistering. - Eyes Believed to be extremely irritating with possible permanent eye injury

Sensitizatíon Skin - no. Respiratory - unknown.

Carcinogluicity lnactive in Mouse Lymphoma forward mutaticn neqative

assay. Ames test - negatlve. cell transformation test

-

The information herein is given in good faith and to the best of our knowledge but no warranty, express or implied. is made Page two of two

Bijlage XV

MATERIAL SAFETY DATA SHEET HXTAL NYL-1 PART A. Prepared January 1, 2008

SECTION 1: IDENTIFICATION. PRODUCT NAME: HXTAL NYL—1, PART A. CHEMICAL NAME: 4,4-Isopropylidenedicyclohexanol- epichlorohydrin. CHEMICAL FAMILY: Liquid Epoxy Resin.

SECTION 2: PRODUCT/INGREDIENT, (Pr./ln.) PRODUCT: HXTAL NYL-1, PART A. 100%. INGREDIENT: Epichlorohydrin. 1-30ppm.

SECTION 3: ACUTE TOXICITY DATA. This Information complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) EYE CONTACT: Testing shows product is minimally irritating to eyes. SKIN CONTACT: Testing shows product is slightly irritating to skin. INHALATION: Product is not expected to irritate, nose, throat, or respiratory tract because of its low volatility. Mists may present an inhalation hazard. INGESTION: Testing demonstrates product is slightly toxic and may be harmful if swallowed. SIGNS AND SYMPTOMS; Irritation as noted above. AGGRAVATED MEDICAL CONDITIONS: Pre-existing skin, eye, and inhalation disorders may be aggravated by exposure to product. HAZARD STATUS: HXTAL NYL-1 , PART A is not a hazardous material by OSHA Appendix A criteria, HMIS: HEALTH: 1, FLAMMABILITY: 1, REACTlVllY: 0

SECTION 4: OCCUPATIONAL EXPOSURE LIMITS. Product: Ingredient:

OSHA PEL/TWA PEL/CEILING None Established 5 ppm (Skin)

ACGIH TLV/TWA TLV/STEL None Establishsd 2 ppm (Skin)

SECTION 5: EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT: Flush eyes with plenty of clean water for 15 minutes while holding eyelids open. Get immediate medical attention.

SKIN CONTACT: Remove contaminated clothing and shoes. Wipe material from skin. Flush skin with cool water. Wash thoroughly with soap and water. If irritation occurs, get medical attention. Do not reuse clothing until cleaned. Contaminated leather, including shoes, cannot be decontaminated and should be destroyed. INHALATION: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. INGESTION: Do not induce vomiting. If vomiting occurs, keep head below hips to prevent aspiration of liquid into lungs. Get medical attention. (NOTE TO PHYSICIAN): If more than 2 ml per Kg has been ingested and vomiting has not occurred, emesis should be induced with supervision, keep victim's head below hips to prevent aspiration of liquid. If symptoms such as convulsions, loss of gag reflex, or unconsciousness occur before emesis, gastric lavage using a cuffed endotracheal tube should be considered.

SECTION6: SUPPLEMENTAL HEALTH INFORMATION. Epichlorohydrin has been reported to produce cancer in laboratory animals and to produce mutagenic changes in bacteria and cultured human cells. The International Agency for Research on Cancer (IARC) states that the evidence that Epichlorohydrin causes cancer in humans is inadequate.

SECTION 7: PHYSICAL DATA. Appearance and odor: Colorless viscous liquid with faint mild odor. Melting point: < 0°F Vapor pressure at 20°C: Unknown Specific Gravity: 1.09 Vapor density: Heavier than air Boiling point: Unknown, >200°F Solubility in water: negligible Volatile fraction by weight: negligible Evaporation: low, < l, where rate for butyl acetate =1.

SECTION 8: FIRE AND EXPLOSION HAZARDS. Flash Point: 240°F (PMCC) Flammability: Will not burn unless preheated. Flammable limits: lower end tipper: Unknown Extinguishing media: Water fog, foam, dry chemical, CO2 Special fire fighting procedures: Do not enter confined fire space without wearing a positive pressure NIOSH approved self contained breathing apparatus and full bunker gear (helmet with face shield, bunker coat, gloves, and rubber boots). Cool containers with water. Unusual fire and explosion hazards: None.

SECTION 9: REACTIVlTY.

Stability: Stable. Hazardous polymerization: Will not occur. Conditions to avoid: Can react vigorously with strong oxidizing agents, strong Lewis or mineral acids, and strong mineral and organic bases, especially primary and secondary aliphatic amines. Uncontrolled reaction with strong acids may be violent. Reaction with some curing agents may evolve considerable heat. Hazardous decomposition products: Carbon monoxide, aldehydes, and acids may form during combustion.

SECTION 10: EMPLOYEE PROTECTION. EXPOSURE AVOIDANCE: No person unfamiliar with the danger of chemical hazards and the contents of this MSDS should be permitted to use HXTAL NYL-1 PART A. Splash resistant goggles should be worn to prevent all eye contact. Gloves and other protective clothing should be worn to minimize skin contact. Ventilation should be provided to control vapor concentration. Eye wash equipment and safety showers should be provided.

SECTION 11: ENVIRONMENTAL PROTECTION. SPILLS: Flammability - HXTAL NYL-1, PART A can burn if preheated, but it is not easy to ignite. Nevertheless, use caution when cleaning spills. Large Spills: Wear a respirator and protective clothing as appropriate. Shut off source of spill if safe to do so. Dike and contain. Scoop up to storage/salvage containers. Soak up residue with dry absorbent materials such as clay or sand or other dry absorbents. Dispose of in compliance with all Federal, state, and local laws and regulations. Flush area with water to remove trace residues. Small Spills: Take up with dry absorbent materials and dispose of in compliance with all Federal, state, and local laws and regulations. Environmental Hazards: Keep out of surface waters, sewers and waterways entering or leading to surface waters. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Note: HXTAL NYL-1 PART A cure with HXTAL NYL-1 PART B is a highly inert solid material that can be discarded with other solid waste in ordinary refuse, if such disposal does not conflict with Federal, state, and local laws and regulations.

SECTION 12: SPECIAL PRECAUTIONS. Keep HXTAL NYL -1 PART A in sturdy, well-sealed containers. Store In a cool, dry place having adequate ventilation. Keep away from flames and high temperatures. Handle in accordance with the hazard potentials of HXTAL NYL-1 PART B, other epoxy curing agents, if any, and other auxiliary materials used with HXTAL NYL-1 PART A. After each use, carefully wash with soap and water before eating, drinking, smoking, or using toilet facilities, Inadequately cleaned hands can carry material to eyes hours later. Launder contaminated clothing before reuse. Leather articles, including shoes, cannot be decontaminated and should be destroyed to prevent reuse.

SECTION 13: TRANSPORTATION. HXTAL NYL-1 PART A is not a hazardous substance according to the US Department of Transportation regulations.

SECTION 14: LABEL STATEMENTS. CAUTION - For Professional use only! CAUTION - May cause irritation! Avoid all contact with the eyes! Avoid prolonged or repeated contact with the skin! Avoid prolonged or repeated breathing of the vapors! Wash thoroughly after handling. Inadequately washed hands can carry material to the eyes hours later! Launder contaminated clothing before reuse. Contaminated leather articles cannot be decontaminated and should be destroyed to prevent reuse. Keep HXTAL NYL-1 PART A away from children and everyone else not familiar with chemical hazards and the HXTAL NYL-1 PART A Material Safety Data Sheet.

SECTION 15: NOTICES. NOTICE No. 1 - Information in this Material Safety Data Sheet is believed to be as complete and correct as present knowledge permits, however, the information and data are supplied without warranty of any kind as to accuracy and suitability. Users of HXTAL NYL-1 PART A must consider the contents of this MSDS only as a supplement to data and information they gather for themselves from testing and experience, from ongoing study of chemical safety literature, and from other sources. Users must independently determine the suitability and completeness of information from many sources of which this MSDS is only a small part. By such effort and means, they must assure safe use and disposal of HXAL NYL-1 PART A so as to safeguard the safety, health, and property of themselves, their associates, and employees; their customers and clients and the general public. The manufacturer of HXTAL NYL-1 PART A assumes no responsibility for any injury arising directly or indirectly from use of the material. NOTICE No. 2 - HXTAL NYL-1 PART A is manufactured and sold for professional use only. It is sold with the limitation that it not be used by, sold, given, or distributed to any person unfamiliar with the danger of chemical hazards and with this MSDS. NOTICE No. 3 - HXTAL NYL-1 PART A, alone or in combination with other materials, including HXTAL NYL-1 PART B, is unsuitable for use inside of or on the surfaces of any living human or animal. Such use is specifically prohibited. NOTICE No. 4 - HXTAL NYL-1 PART A must be used and stored in such manner as to prevent children and others unfamiliar with chemical hazards and this MSDS from obtaining access to it. NOTICE No. 5 - Information in this MSDS must not be regarded as recommending use of HXTAL NYL-1 PART A to obtain any result. Users must perform Independent tests that prove HXTAL NYL-1 PART A, alone or in combination with other materials, (Including HXTAL NYL-1 PART B), has sufficient strength, durability, and reliability to perform safety and satisfactorily in any application for which It is used. NOTICE No. 6 - The toxicological properties of HXTAL NYL-1 PART A have not been fully investigated. Therefore to assure safety, users must accept procedures to eliminate opportunities for direct contact with skin and eyes and to prevent ingestion and inhalation.

MATERIAL SAFETY DATA SHEET HXTAL NYL-1 PART B. Prepared 23 February 1989.

SECTION 1: IDENTIFICATION. Product Name: HXTAL NYL-1 PART B Chemical Name: Poly(oxy)(methyl-1,2-ethanediyl), alpha-hydro-omega-(2-aminomethylathoxy)-ether with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol(3:1) + Imidizoles. Chemical Family: Alkyl ether amine + Imidizoles.

SECTION 2-A: PRODUCT / INGREDIENT (Pr/ln) Product: HXTAL NYL-1 PART B 100%

SECTION 2-B: ACUTE TOXICITY DATA. Acute Oral LD 50 – Product: <0.22 g/kg (Rat) Acute Dermal LD 50 - Product: < 0.40 g/kg (Rabbit) Acute Inhalation - Product: 0/6 Deaths (Rat), 8 Hrs. Saturated Atmosphere

SECTION 3: HEALTH INFORMATION. This information is provided to comply with OSHA Hazard Communication Standard (29 CFR 1910.1200) EYE CONTACT: Tests show HXTAL NYL-1 PART B is toxic and extremely irritating. Estimated irritation index: (80 to 110)/ 110 (rabbit), with possible permanent eye injury. Corrosive. SKIN CONTACT: Tests show product is toxic and extremely irritating. Estimated irritation index: 8.0/8.0 (Rabbit). Product may cause severe skin damage with burns and blistering . Corrosive. INHALATION: Product may irritate nose, throat, or respiratory tract. Vapor from heated product and mists may present inhalation hazards. INGESTION: Testing shows product Is toxic and harmful if swallowed. SIGNS AND SYMPTOMS. Irritation as noted above. AGGRAVATED MEDICAL CONDITIONS: Preexisting skin, eye, and inhalation disorders may be aggravated by exposure to this product. HAZARD STATUS: HXTAL NYL-1 PART B is a hazardous material by OSHA Appendix A criteria. HMIS - Health 3, Flammability: 1, Reactivity:0.

SECTION 4: OCCUPATIONAL EXPOSURE LIMITS. OSHA PEL/TWA PEL/CEILING

ACGIH TLV/TWA TLV/STEL

Product:

None Established

None Established

SECTION 5: EMERGENCY AND FIRST AID PROCEDURES. EYE CONTACT; Hold eyelids open & flush eyes with plenty of clean water for 15 min. Get medical attention fast! SKIN CONTACT: If irritation occurs, get medical attention. For small area contact, immediately wipe away with soft cloth or tissue, and wash thoroughly with cool water and soap. Inadequately washed hands can carry material to eyes hours later. If drenched, immediately remove clothing and shoes. Wipe material from skin and wash thoroughly with cool water and soap. Do not reuse clothing until laundered. Leather articles cannot be adequately decontaminated and should be destroyed to prevent reuse. INHALATION: If irritation occurs, remove victim to fresh air. Provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention. INGESTION: Do not induce vomiting. If vomiting occurs, keep head below hips to prevent aspiration of liquid into lungs. Get immediate medical attention.

SECTION 6: SUPPLEMENTAL HEALTH INFORMATION. NOTE: The toxicological properties of HXTAL NYL-1 PART B have not been fully determined. Users must therefore adopt suitable procedures to eliminate all opportunities for direct contact with skin and eyes, and also to prevent any possibility of ingestion or inhalation.

SECTION 7: PHYSICAL DATA. Appearance and odor: Colorless liquid, mild ammonia-like odor. Melting point: Unknown. Vapor pressure: <1 mm Hg at 40°C. Boiling point: > 200°F. Specific gravity: 0.9812. pH: >12.3 VERY BASIC. (Note Think Lye!) Percent volatile: Nil. Viscosity: > 80 CS at 25°C. Solubility in water: Soluble.

SECTION 8: FIRE AND EXPLOSION HAZARDS. Unusual fire and explosion hazards: None. Flash point: > 300°F. Flammable limits, upper and lower: Unknown. Product will not burn unless preheated. Evolved from burning: Ammonia, carbon dioxide, and carbon monoxide may be formed upon burning in limited air supply. Extinguishing media: Water, loam, dry chemical, CO2.

Special fire fighting procedures: Do not enter confined fire space without wearing a positive pressure NIOSH approved self contained breathing apparatus and full bunker gear (helmet with face shield, bunker coat, gloves, and rubber boots). Coo1 containers with water.

SECTION 9: REACTIVITY. Stability: Stable. Hazardous polymerization: Will not occur. Violent reactions: May occur with acids. Avoid uncontrolled reaction with acids. Heat output: Reaction with some epoxides and accelerators may evolve considerable heat.

SECTION 10: EMPLOYEE PROTECTION. EXPOSURE AVOIDANCE: No person unfamiliar with the dangers of chemical hazards and with the contents of this MSDS should be permitted to use HXTAL NYL-1 PART B. Splash resistant goggles plus full face shield should be worn to prevent all eye contact. Gloves and other protective clothing should be worn to minimize skin contact Ventilation should be provided to control vapor concentration. Eye wash equipment and safety showers should be provided.

SECTION 11: ENVIRONMENTAL PROTECTION. SPILLS: Flammability: HXTAL NYL-1 PART B can burn if preheated but is not easily ignited, nevertheless, use caution when cleaning spills. For large spills: Wear a respirator and protective clothing as appropriate. Dike and contain. Scoop up residue with dry absorbent material such as clay, sand, or similar material. Dispose of in compliance with Federal, state, and local laws and regulations. Flush area with water to remove trace residue. Small spills: Take up with dry absorbent material and dispose of in compliance with Federal, state, and local laws and regulations. ENVIRONMENTAL HAZARDS: Keep out of surface waters, sewers and waterways entering or leading to surface waters. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. NOTE: HXTAL NYL-1 PART B when used to cure HXTAL NYL-1 PART A produces an inert material that can usually be discarded with ordinary refuse if such disposal does not conflict with Federal, state, and local laws and regulations.

SECTION 12: SPECIAL PRECAUTIONS. KEEP HXTAL NYL-1 PART B in sturdy well-sealed containers away from high temperatures and flames. If storage above 100°F is unavoidable, a nitrogen atmosphere is suggested. Periods of high temperature exposure should be minimized. Store in a cool dry place with adequate ventilation. Minimum handling temperatures should be maintained and moisture contamination should be avoided. Handle in accordance with the hazard potential of HXTAL NYL-1 PART A and of any auxiliary materials used with HXTAL NYL-1 PART B. After each use, carefully wash with soap and water before eating, drinking, smoking, or using toilet facilities.

Inadequately cleaned hands can carry material to eyes hours later Launder contaminated clothing before reuse. Leather articles including shoes cannot be decontaminated and should be destroyed to prevent reuse.

SECTION 13: TRANSPORTATION. Because it is corrosive, HXTAL NYL-1 PART B is a hazardous material according to U.S. Department of Transportation Regulations. Proper shipping name: Alkaline corrosive liq. N.O.S. DOT Class: Corrosive material UN 2735 Packing Group III

SECTION 14: LABEL STATEMENTS. Warning! Danger! Professional use only! Causes severe skin burns. Causes severe eye burns and may cause blindness. Serious injury may result if swallowed. Serious injury may result if absorbed through skin. Avoid contact with eyes. Avoid contact with skin. Avoid breathing vapor or mist. Keep containers tightly closed. Use only in well ventilated locations Wash thoroughly after handling. Inadequately washed hands can carry material to eyes hours later. Launder contaminated clothing before reuse. Destroy contaminated leather articles including shoes. Keep away from children and everyone else, unfamiliar with chemical hazards and this Material Safety Data Sheet.

SECTION 15: NOTICES. NOTICE NO. 1: Information in this MSDS is believed to be as complete and correct as present knowledge permits. However, the information and data are supplied without warranty of any kind as to accuracy and suitability. Users of HXTAL NYL-1 PART B must consider the contents of this MSDS only as a supplement to data and information they gather for themselves from testing and experience from ongoing study of chemical safety literature and from other sources. Users must independently determine the suitability and completeness of information from many sources of which this MSDS is only a small part. By such effort and means, users must assure safe use and disposal of HXTAL NYL-1 PART B so as to safeguard the safety, health, and property of themselves, their associates and employees, their customers and clients, and the general public. The manufacturer of HXTAL NYL-1 PART B assumes no responsibility for any injuries arising directly or indirectly from use of the material. NOTICE NO. 2: HXTAL NYL-1 PART B is manufactured and sold for professional use only. It is sold with the limitation that it not be used by, sold, given, or distributed to any person unfamiliar with the danger of chemical hazards and with this MSDS. NOTICE NO. 3: HXTAL NYL-1 PART B, alone or in combination with other materials, including HXTAL NYL-1 PART A, has not been manufactured for use inside of or on the surfaces of any living human or animal, and such use is specifically prohibited.

NOTICE NO. 4: HXTAL NYL-1 PART B must be used and stored in such manner as to prevent children and others unfamiliar with chemical hazards and this MSDS from obtaining access to it. NOTICE NO. 5: Information in this MSDS must not be regarded as recommending that HXTAL NYL-1 PART B be used to obtain any particular result. Users must perform independent tests that prove HXTAL NYL-1 PART B, alone or in combination with other materials (including HXTAL NYL-l PART A) has adequate strength, durability, and reliability to perform safely and satisfactorily in any application for which it is used. NOTICE NO. 6: The toxicologica1 properties of HXTAL NYL-1 PART B have not been fully determined. Therefore, to assure safety, users must adopt procedures to eliminate opportunities for direct contact with skin and eyes and to prevent any ingestion or inhalation.

Bijlage XVI

VEILIGHEIDSINFORMATIEBLAD (EC 1907/2006) AEROSIL® 200 materiaalnr. specificatie VA-Nr

238014000099 132138 03223439

Versie Datum van herziening Afdrukdatum Pagina

1.31 / NL 31.07.2012 04.10.2012 1/7

1. IDENTIFICATIE VAN DE STOF OF HET PREPARAAT EN VAN DE ONDERNEMING productinformatie Handelsnaam

AEROSIL® 200

Firma

Evonik Industries AG Inorganic Materials Produktsicherheit IM-PT-PS Postfach 1345 D-63403 Hanau

Telefoon Telefax

+49 (0)6181 59-4787 +49 (0)6181 59-4205 [email protected] +49 (0)7623-919191

Emailadres Telefoonnummer voor noodgevallen Gebruik van de chemische stof / preparaat

Functie

Afdichtkit Bonte drukinkt Verf en lakken lijm Siliconenkit cosmetische toevoegingen cosmetica Middel tegen aankoeken Anti-blokrmiddel coatingmiddel Dispergeerhulpmiddel vloeihulpmiddel Versterkingsmiddelen drager

REACH-registratienr.: indien aanwezig in hfst. 3 vermeld 2. IDENTIFICATIE VAN DE GEVAREN Indeling overeenkomstig verordening (EG) nummer 1272/2008 [CLP]. Opmerkingen

Geen gevaarlijke stof of gevaarlijk mengsel volgens verordnung (EG) nummer 1272/2008.

GHS-markering Opmerkingen

Volgens EU-CLP verordening (1272/2008) niet markeringsverplicht

Indeling volgens richtlijn 67/548/EG of richtlijn 1999/45/EG Het product is niet onderworpen aan de EG-richtlijn 67/548/EEG of 1999/45/EG als gevaarlijke chemische stof of preparaat.

Andere Gevaren Volgens de criteria van de REACH-verordening geen PBT-, vPvB-stof.

3. SAMENSTELLING EN INFORMATIE OVER DE BESTANDDELEN

EU-GHS(P04/001) / 30.07.2012 19:25



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Informatie over de bestanddelen / Gevaarlijke bestanddelen volgens EU-CLP-verordening (EG) nr. 1272/2008 • Siliciumdioxide, chemisch bereid CAS-Nr.

112945-52-5 7631-86-9

EG-Nr.

231-545-4

REACH-nr.

01-2119379499-16-0000 (TPR)

Informatie over de bestanddelen / Gevaarlijke bestanddelen volgens richtlijn 67/548/EG of richtlijn 1999/45/EG • Siliciumdioxide, chemisch bereid 112945-52-5 CAS-Nr. EG-Nr.

231-545-4

REACH-nr.

7631-86-9

01-2119379499-16-0000 (TPR)

Teksten van de H-zinnen, zie onder hoofdstuk 16 Teksten van de R-zinnen; zie hoofdstuk 16 4. EERSTEHULPMAATREGELEN Inademing Bij vrijkomen van product in stofvorm: Mogelijke klachten: hoesten, niezen Slachtoffer naar de frisse lucht brengen. Contact met de huid Met veel water en zeep afwassen. Contact met de ogen Mogelijke klachten veroorzaakt door effect vreemd voorwerp. Bij geopend ooglid zorgvuldig met veel water spoelen. Bij blijvende klachten: Oogarts raadplegen. Inslikken Mond reinigen met water en daarna veel water drinken. Na opname van grotere hoeveelheden van de substantie / Bij klachten: Voor medische behandeling zorgen. Belangrijkste acute en uitgestelde symptomen en effecten Verschijnselen niet bekend Gevaren niet bekend Vermelding van de vereiste onmiddellijke medische verzorging en speciale behandeling Geen risico's die speciale eerstehulpmaatregelen vereisen. 5. BRANDBESTRIJDINGSMAATREGELEN Geschikte blusmiddelen alle blusmiddelen geschikt Speciale gevaren die door de stof of het mengsel worden veroorzaakt niet bekend Advies voor brandweerlieden Bluswater mag niet in de riolering, de ondergrond of in open water lopen. Zorgen voor voldoende mogelijkheden om het bluswater op te vangen. Verbrandingsresten en verontreinigd bluswater moeten overeenkomstig de plaatselijke voorschriften van de autoriteiten verwijderd worden.

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6. MAATREGELEN BIJ ACCIDENTEEL VRIJKOMEN VAN DE STOF OF HET PREPARAAT Persoonlijke voorzorgsmaatregelen, beschermde uitrusting en noodprocedures Persoonlijke beschermingsmiddelen gebruiken. Insluitings- en reinigingsmethoden en -materiaal Gemorst materiaal opvegen of opzuigen en in een geschikt vat afvoeren voor verwijdering. 7. HANTERING EN OPSLAG Hantering Voorzorgsmaatregelen voor het veilig hanteren van de stof of het mengsel Eventueel: Objectafzuiging. Aanwijzingen voor bescherming tegen brand en explosie Maatregelen treffen tegen ontladingen van statische elektriciteit. Opslag Voorwaarden voor een veilige opslag, met inbegrip van incompatibele producten Op een droge plaats bewaren.

8. MAATREGELEN TER BEHEERSING VAN BLOOTSTELLING/PERSOONLIJKE BESCHERMING Controleparameters • Siliciumdioxide, chemisch bereid CAS-Nr. Controleparameters Expositiewijze

112945-52-5 7631-86-9 10 mg/m3 In te ademen rook.

Controleparameters Expositiewijze

5 mg/m3 inadembaar stof

EG-Nr.

231-545-4 Tijdgewogen gemiddelde (TWA):(MAC (NL)) Tijdgewogen gemiddelde (TWA):(MAC (NL))

Persoonlijke beschermingsmiddelen Adembescherming Geen speciale beschermingsmiddelen nodig. Bij het optreden van stof: Stofmasker met deeltjesfilter P2 Bescherming van de handen Veiligheidshandschoenen van de volgende materialen dragen: stof, rubber, leer. De gegevens van de materiaaldikte en de doorbraaktijd zijn niet van toepassing voor niet opgeloste vaste/verstuifbare stoffen. Oogbescherming veiligheidsbril met zijkleppen Bij het optreden van stof: roosterbril Bescherming van de huid en het lichaam Geen speciale beschermingsmiddelen nodig. preventieve huidbescherming

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Hygiënische maatregelen Niet eten, drinken of roken tijdens gebruik. Voor een pauze en bij beëindiging van het werk handen en/of gezicht wassen. Gebruik van zeer vette zeep en een huidcreme ter verzorging van de huid om een optimale huidbescherming te waarborgen. Verontreinigde kleding wassen vooraleer opnieuw te gebruiken. Beschermende maatregelen Hanteer overeenkomstig goede industriële hygiëne en veiligheid. Bij mogelijkheid tot contact met de huid / ogen moet(en) de aangegeven handschoenen / bril / lichaamsbescherming worden gebruikt. Bij overschrijding van de voor de werkplek geldende waarden en/of bij vrijkomen van grotere hoeveelheden (lek, morsen, stof) moet het aangegeven ademmasker worden gebruikt. 9. FYSISCHE EN CHEMISCHE EIGENSCHAPPEN Voorkomen Vorm Kleur Geur Aggregaattoestand

poeder wit reukloos vast

Informatie over fysische en chemische basiseigenschappen pH

3,7 - 4,7 (40 g / l) (suspensie)

Smeltpunt/traject

ca. 1700 °C

Kookpunt/traject

niet van toepassing

Vlampunt

niet van toepassing

Ontvlambaarheid (vast,gas)

niet van toepassing

Ontstekingstemperatuur

niet van toepassing

Zelfontvlambaarheid

niet van toepassing

Thermische ontleding

> 2000 °C

Onderste explosiegrens

niet van toepassing

Bovenste explosiegrens

niet van toepassing

Minimum ontstekingsenergie

niet van toepassing

Dampspanning

niet van toepassing

Dichtheid

ca. 2,2 g/cm3

Opstampdichtheid

ca. 50 g / l Methode:

(20 °C)

DIN / ISO 787/11

Oplosbaarheid in water

> 1 mg/l

Verdelingscoëfficiënt (noctanol/water) Viscositeit, dynamisch

niet van toepassing

EU-GHS(P04/001) / 30.07.2012 19:25

(20 °C)

niet van toepassing



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10. STABILITEIT EN REACTIVITEIT Gevaarlijke ontledingsproducten

niet bekend

11. TOXICOLOGISCHE INFORMATIE Acute orale toxiciteit

LD50 rat: > 10000 mg/kg Methode: literatuur

Acute inhalatoire toxiciteit

LC0 rat: 0,139 mg/l / 4 u Methode: literatuur (experimenteel maximaal bereikbare concentratie) Mortaliteit is niet opgetreden.

Acute dermale toxiciteit

LD50 konijn: > 5000 mg/kg Methode: literatuur

Huidirritatie

konijn / literatuur niet irriterend

Oogirritatie


Toxiciteit bij herhaalde toediening Oraal geen negatieve effecten inhalatief geen irreversibele veranderingen en geen tekenen van silicose vastgesteld gentoxiciteit in vitro

geen aanwijzing voor mutageen werking literatuur

gentoxiciteit in vivo


Carcinogeniteit

geen negatieve effecten

Toxiciteit ten aanzien van de voortplanting Ervaring bij mensen

geen negatieve effecten Silicose of andere productspecifieke ziekten van de ademhalingswegen zijn in de omgang met het product niet geobserveerd.

12. ECOLOGISCHE INFORMATIE Ecotoxiciteitseffecten Toxiciteit voor vissen

LC50 (Brachydanio rerio): > 10000 mg/l / 96 u Methode: OECD 203

Giftigheid voor daphnia

EC50 Daphnia magna: > 10000 mg/l / 24 u Methode: OECD 202

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Resultaten van PBT-beoordeling Volgens de criteria van de REACH-verordening geen PBT-, vPvB-stof. 13. INSTRUCTIES VOOR VERWIJDERING product Kan onder het inachtnemen van de vereiste technische voorschriften na overleg met de verwerker en de betreffende overheidsinstantie samen met huisvuil worden opgeslagen. Ongereinigde verpakkingen Het gewassen verpakkingsmateriaal overbrengen naar plaatselijke recycling. Andere landen: nationale voorschriften in acht nemen. Afvalstofnummer Voor dit product kan geen afvalcodenummer conform het Europese afvalregister worden vastgelegd, omdat pas het beoogde gebruik door de verbruiker een toewijzing mogelijk maakt. Het afvalcodenummer dient conform het Europese afvalregister (EU-beslissing inzake afvalregister 2000/532/EG) in overleg met de verwerker/fabrikant/de overheid te worden vastgelegd.

14. INFORMATIE MET BETREKKING TOT HET VERVOER

Transport/nadere gegevens Het product is geclassificeerd als ongevaarlijk overeenkomstig de vervoersvoorschriften.

15. WETTELIJK VERPLICHTE INFORMATIE Nationale wetgeving

16. OVERIGE INFORMATIE teksten van de R-zinnen Teksten van de H-zinnen Verdere informatie Wijzigingen die zijn aangebracht na het verschijnen van de vorige uitgave worden gemarkeerd in de kantlijn. Deze uitgave vervangt alle vroegere versies. De in dit veiligheidsinformatieblad verstrekte gegevens zijn zover ons bekend juist op de aangegeven uitgiftedatum. Deze informatie is uitsluitend bedoeld als handleiding voor veilig hanteren, gebruik, verwerken, opslag, vervoer, verwijderen en vrijkomen en mag niet beschouwd worden als een garantie of aanduiding van kwaliteit. De informatie heeft alleen betrekking op het hierin vermelde product en is niet zonder meer geldig wanneer het samen met andere producten of in enig ander procede wordt gebruikt, tenzij dit in de tekst vermeld wordt.

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Legenda ADR ADN ASTM ATP BCF BetrSichV c. c. CAS CESIO ChemG CMR DIN DNEL EINECS GefStoffV GGVSEB GGVSee GLP GMO IATA DGR ICAO-TI IMDG Code ISO LOAEL LOEL NOAEL NOEC NOEL o. c. OECD OEL PBT PEC PNEC RID TA TPR TRGS VCI vPvB VOC VwVwS WGK WHO

EU-GHS(P04/001) / 30.07.2012 19:25

European Agreement concerning the International Carriage of Dangerous Goods by Road European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways American Society for Testing and Materials Adaptation to Technical Progress Bioconcentration Factor German Ordinance on Industrial Safety and Health closed cup (geschlossenes Gefäß) Chemical Abstract Services European Committee of Organic Surfactants and their Intermediates German Chemicals Act Carcinogenic-Mutagenic-toxic for Reproduction German Institute for Standardization Derived No Effect Level European Inventory of Existing Commercial Chemical Substances German Ordinance on Hazardous Substances German ordinance for road, rail and inland waterway transportation of dangerous goods German ordinance for sea transportation of dangerous goods Good Laboratory Practice. Genetic Modified Organism International Air Transport Association – Dangerous Goods Regulations International Civil Aviation Organisation - Technical Instructions International Maritime Dangerous Goods Code International Organization For Standardization Lowest Observed Adverse Effect Level Lowest Observed Effect Level No Observed Adverse Effect Level No Observed Effect Concentration No Observed Effect Level open cup (offenes Gefäß) Organisation for Economic Cooperation and Development Occupational Exposure Limit Persistent, Bioaccumulative, Toxic Predicted Effect Concentration Predicted No Effect Concentration Regulations concerning the International Carriage of Dangerous Goods by Rail Technical Instructions (German Ordinance) Third Party Representative (Art. 4) Technical Rules for Hazardous Substances (German Regulations) German "Verband der Chemischen Industrie e. V." Very Persistent, Very Bioaccumulative Volatile Organic Compounds German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water Hazard Classes German Water Hazard Class World Health Organization

Bijlage XVII

___ ___

Specification ____________________________________________________________________ AEROSIL® 300 Evonik Degussa GmbH

Spec. no.: 1230/1 Material number, Bulk: 23.8016.0000.00 Valid for all forms of packaging Standard

Inorganic Materials Dr. Martin Reisinger Tel. 49-(0)6181/59- 2839 [email protected] www.evonik.com/aerosil page date of print:

1 of 1 16.06.2009

valid from:

10.10.1998

Product specification ____________________________________________________________________ Properties and Test Methods

Units Target Values (Spec. Limits) ____________________________________________________________________ 663/0100

Specific surface area (BET)

663/0200 663/0200

pH

663/0300 663/0300

Moisture

663/0501 663/

SiO2-content (1)

m²/g

300 (270 - 330) 3,7 - 4,7

in 4% dispersion

%

<= 1,5

%

>= 99,8

2 hours at 105°C

(1) based on ignited material

Characteristic physico-chemical data ____________________________________________________________________ Properties and Test Methods

Units Typical Values ____________________________________________________________________ 663/0701 663/0701

Tamped density (approximate value)

g/l

50

(+)

663/0400 663/0400

Ignition loss

%

<= 2,0

(+)

663/0801

HCl-content (1)

%

<= 0,025

(+)

663/0563

Al2O3-content (1)

%

<= 0,050

(+)

663/0571

Fe2O3-content (1)

%

<= 0,003

(+)

663/0581

TiO2-content (1)

%

<= 0,030

(+)

663/0900 663/0900

Sieve residue by Mocker, 45 µm

%

<= 0,050

(+)

663/0990

Average primary particle size

nm

7

(+)

acc. to DIN ISO 787/XI, Aug. 1983

2 hours at 1000°C based on material dried for 2 hours at 105°C

acc. to DIN ISO 787/XVIII, Apr. 1984

____________________________________________________________________ (+) No measured value given in quality documents

All warranty claims in respect of the conformance of our product are subject to our terms of contract and General terms and Conditions of Sale and Delivery. The data listed above reflects the criteria for our internal quality tests. We do not hereby make any express or implied warranty, whether for specific properties or for fitness for any particular application or purpose. All values are valid for the product when despatched from the plants.

ZJQ_SPEZ/DEG/16.06.2009/14:30/dss0402p/001

E/K:0000610185/0000000000/0101/11

JQP0002


238016000009 132142 03184634


1.29 / NL 05.07.2012 30.07.2012 1/7


AEROSIL® 300

Firma


Telefoon Telefax

+49 (0)6181 59-4787 +49 (0)6181 59-4205 [email protected] +49 (0)7623-919191


Functie

Afdichtkit Bonte drukinkt Verf en lakken lijm Siliconenkit cosmetica Middel tegen aankoeken Anti-blokrmiddel coatingmiddel Dispergeerhulpmiddel vloeihulpmiddel Versterkingsmiddelen drager

REACH-registratienr.: indien aanwezig in hfst. 3 vermeld 2. IDENTIFICATIE VAN DE GEVAREN Indeling overeenkomstig verordening (EG) nummer 1272/2008 [CLP]. Opmerkingen

Geen gevaarlijke stof of gevaarlijk mengsel volgens verordnung (EG) nummer 1272/2008.

GHS-markering Opmerkingen

Volgens EU-CLP verordening (1272/2008) niet markeringsverplicht

Indeling volgens richtlijn 67/548/EG of richtlijn 1999/45/EG Het product is niet onderworpen aan de EG-richtlijn 67/548/EEG of 1999/45/EG als gevaarlijke chemische stof of preparaat.

Andere Gevaren Volgens de criteria van de REACH-verordening geen PBT-, vPvB-stof.


Informatie over de bestanddelen / Gevaarlijke bestanddelen volgens EU-CLP-verordening (EG) nr.

EU-GHS(P04/001) / 05.07.2012 01:17



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1272/2008 • Siliciumdioxide, chemisch bereid CAS-Nr.

112945-52-5 7631-86-9

EG-Nr.

231-545-4

REACH-nr.

01-2119379499-16-0000 (TPR)


231-545-4

REACH-nr.

7631-86-9

01-2119379499-16-0000 (TPR)

Teksten van de H-zinnen, zie onder hoofdstuk 16 Teksten van de R-zinnen; zie hoofdstuk 16 4. EERSTEHULPMAATREGELEN Inademing Bij vrijkomen van product in stofvorm: Mogelijke klachten: hoesten, niezen Slachtoffer naar de frisse lucht brengen. Contact met de huid Met veel water en zeep afwassen. Contact met de ogen Mogelijke klachten veroorzaakt door effect vreemd voorwerp. Bij geopend ooglid zorgvuldig met veel water spoelen. Bij blijvende klachten: Oogarts raadplegen. Inslikken Mond reinigen met water en daarna veel water drinken. Na opname van grotere hoeveelheden van de substantie / Bij klachten: Voor medische behandeling zorgen. Belangrijkste acute en uitgestelde symptomen en effecten Verschijnselen niet bekend Gevaren niet bekend Vermelding van de vereiste onmiddellijke medische verzorging en speciale behandeling Geen risico's die speciale eerstehulpmaatregelen vereisen. 5. BRANDBESTRIJDINGSMAATREGELEN Geschikte blusmiddelen alle blusmiddelen geschikt Speciale gevaren die door de stof of het mengsel worden veroorzaakt niet bekend Advies voor brandweerlieden Bluswater mag niet in de riolering, de ondergrond of in open water lopen. Zorgen voor voldoende mogelijkheden om het bluswater op te vangen. Verbrandingsresten en verontreinigd bluswater moeten overeenkomstig de plaatselijke voorschriften van de autoriteiten verwijderd worden.

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6. MAATREGELEN BIJ ACCIDENTEEL VRIJKOMEN VAN DE STOF OF HET PREPARAAT Persoonlijke voorzorgsmaatregelen, beschermde uitrusting en noodprocedures Persoonlijke beschermingsmiddelen gebruiken. Insluitings- en reinigingsmethoden en -materiaal Gemorst materiaal opvegen of opzuigen en in een geschikt vat afvoeren voor verwijdering. 7. HANTERING EN OPSLAG Hantering Voorzorgsmaatregelen voor het veilig hanteren van de stof of het mengsel Eventueel: Objectafzuiging. Aanwijzingen voor bescherming tegen brand en explosie Maatregelen treffen tegen ontladingen van statische elektriciteit. Opslag Voorwaarden voor een veilige opslag, met inbegrip van incompatibele producten Op een droge plaats bewaren. Duitse opslagclassificatie brandbare / niet brandbare vloeistoffen en vaste stoffen voor zover ze niet aan andere bewaarklasse toe te wijzen zijn.

8. MAATREGELEN TER BEHEERSING VAN BLOOTSTELLING/PERSOONLIJKE BESCHERMING Controleparameters • Siliciumdioxide, chemisch bereid CAS-Nr. Controleparameters Expositiewijze




EG-Nr.

231-545-4 Tijdgewogen gemiddelde (TWA):(MAC (NL)) Tijdgewogen gemiddelde (TWA):(MAC (NL))

Persoonlijke beschermingsmiddelen Adembescherming Geen speciale beschermingsmiddelen nodig. Bij het optreden van stof: Stofmasker met deeltjesfilter P2 Bescherming van de handen Veiligheidshandschoenen van de volgende materialen dragen: stof, rubber, leer. De gegevens van de materiaaldikte en de doorbraaktijd zijn niet van toepassing voor niet opgeloste vaste/verstuifbare stoffen. Oogbescherming veiligheidsbril met zijkleppen Bij het optreden van stof: roosterbril Bescherming van de huid en het lichaam Geen speciale beschermingsmiddelen nodig. preventieve huidbescherming

EU-GHS(P04/001) / 05.07.2012 01:17


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Hygiënische maatregelen Niet eten, drinken of roken tijdens gebruik. Voor een pauze en bij beëindiging van het werk handen en/of gezicht wassen. Gebruik van zeer vette zeep en een huidcreme ter verzorging van de huid om een optimale huidbescherming te waarborgen. Verontreinigde kleding wassen vooraleer opnieuw te gebruiken. Beschermende maatregelen Hanteer overeenkomstig goede industriële hygiëne en veiligheid. Bij mogelijkheid tot contact met de huid / ogen moet(en) de aangegeven handschoenen / bril / lichaamsbescherming worden gebruikt. Bij overschrijding van de voor de werkplek geldende waarden en/of bij vrijkomen van grotere hoeveelheden (lek, morsen, stof) moet het aangegeven ademmasker worden gebruikt. 9. FYSISCHE EN CHEMISCHE EIGENSCHAPPEN Voorkomen Vorm Kleur Geur Aggregaattoestand

poeder wit reukloos vast


3,7 - 4,7 (40 g / l) (suspensie)

Smeltpunt/traject

ca. 1700 °C

Kookpunt/traject

niet van toepassing

Vlampunt

niet van toepassing


niet van toepassing


niet van toepassing

Zelfontvlambaarheid

niet van toepassing


> 2000 °C


niet van toepassing


niet van toepassing


niet van toepassing

Dampspanning

niet van toepassing

Dichtheid

ca. 2,2 g/cm3

Opstampdichtheid


(20 °C)

DIN / ISO 787/11


> 1 mg/l


niet van toepassing

EU-GHS(P04/001) / 05.07.2012 01:17

(20 °C)

niet van toepassing



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niet bekend

11. TOXICOLOGISCHE INFORMATIE Acute orale toxiciteit


Acute inhalatoire toxiciteit

LC0 rat: 0,139 mg/l / 4 u Methode: literatuur (experimenteel maximaal bereikbare concentratie) Mortaliteit is niet opgetreden.

Acute dermale toxiciteit


Huidirritatie


Oogirritatie






Carcinogeniteit








EU-GHS(P04/001) / 05.07.2012 01:17


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Resultaten van PBT-beoordeling Volgens de criteria van de REACH-verordening geen PBT-, vPvB-stof. 13. INSTRUCTIES VOOR VERWIJDERING product Kan onder het inachtnemen van de vereiste technische voorschriften na overleg met de verwerker en de betreffende overheidsinstantie samen met huisvuil worden opgeslagen. Ongereinigde verpakkingen Het gewassen verpakkingsmateriaal overbrengen naar plaatselijke recycling. Andere landen: nationale voorschriften in acht nemen. Afvalstofnummer Voor dit product kan geen afvalcodenummer conform het Europese afvalregister worden vastgelegd, omdat pas het beoogde gebruik door de verbruiker een toewijzing mogelijk maakt. Het afvalcodenummer dient conform het Europese afvalregister (EU-beslissing inzake afvalregister 2000/532/EG) in overleg met de verwerker/fabrikant/de overheid te worden vastgelegd.



15. WETTELIJK VERPLICHTE INFORMATIE Nationale wetgeving

16. OVERIGE INFORMATIE teksten van de R-zinnen Teksten van de H-zinnen Verdere informatie Wijzigingen die zijn aangebracht na het verschijnen van de vorige uitgave worden gemarkeerd in de kantlijn. Deze uitgave vervangt alle vroegere versies. De in dit veiligheidsinformatieblad verstrekte gegevens zijn zover ons bekend juist op de aangegeven uitgiftedatum. Deze informatie is uitsluitend bedoeld als handleiding voor veilig hanteren, gebruik, verwerken, opslag, vervoer, verwijderen en vrijkomen en mag niet beschouwd worden als een garantie of aanduiding van kwaliteit. De informatie heeft alleen betrekking op het hierin vermelde product en is niet zonder meer geldig wanneer het samen met andere producten of in enig ander procede wordt gebruikt, tenzij dit in de tekst vermeld wordt.

EU-GHS(P04/001) / 05.07.2012 01:17


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Legenda ADR ADN ASTM ATP BCF BetrSichV c. c. CAS CESIO ChemG CMR DIN DNEL EINECS GefStoffV GGVSEB GGVSee GLP GMO IATA DGR ICAO-TI IMDG Code ISO LOAEL LOEL NOAEL NOEC NOEL o. c. OECD OEL PBT PEC PNEC RID TA TPR TRGS VCI vPvB VOC VwVwS WGK WHO

EU-GHS(P04/001) / 05.07.2012 01:17

European Agreement concerning the International Carriage of Dangerous Goods by Road European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways American Society for Testing and Materials Adaptation to Technical Progress Bioconcentration Factor German Ordinance on Industrial Safety and Health closed cup (geschlossenes Gefäß) Chemical Abstract Services European Committee of Organic Surfactants and their Intermediates German Chemicals Act Carcinogenic-Mutagenic-toxic for Reproduction German Institute for Standardization Derived No Effect Level European Inventory of Existing Commercial Chemical Substances German Ordinance on Hazardous Substances German ordinance for road, rail and inland waterway transportation of dangerous goods German ordinance for sea transportation of dangerous goods Good Laboratory Practice. Genetic Modified Organism International Air Transport Association – Dangerous Goods Regulations International Civil Aviation Organisation - Technical Instructions International Maritime Dangerous Goods Code International Organization For Standardization Lowest Observed Adverse Effect Level Lowest Observed Effect Level No Observed Adverse Effect Level No Observed Effect Concentration No Observed Effect Level open cup (offenes Gefäß) Organisation for Economic Cooperation and Development Occupational Exposure Limit Persistent, Bioaccumulative, Toxic Predicted Effect Concentration Predicted No Effect Concentration Regulations concerning the International Carriage of Dangerous Goods by Rail Technical Instructions (German Ordinance) Third Party Representative (Art. 4) Technical Rules for Hazardous Substances (German Regulations) German "Verband der Chemischen Industrie e. V." Very Persistent, Very Bioaccumulative Volatile Organic Compounds German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water Hazard Classes German Water Hazard Class World Health Organization

Bijlage XVIII

___ ___

Specification ____________________________________________________________________ AEROSIL® R 805 Evonik Degussa GmbH

Spec. no.: 4170/1 Material number, Bulk: 23.8222.0013.00 Valid for all forms of packaging AeR805


1 of 1 16.06.2009

valid from:

17.03.2004




663/0210 663/0210

pH

663/0600

Carbon content

m²/g

150 (125 - 175) 3,5 - 5,5

in 4% dispersion

%

4,5 - 6,5


Units Typical Values ____________________________________________________________________ 663/0701 663/0701


g/l

60

(+)

663/0300 663/0300

Moisture

%

<= 0,5

(+)

663/0400 663/0400

Ignition loss

%

5,0 - 7,0

(+)

663/0501 663/

SiO2-content (1)

%

>= 99,8

(+)

663/0563

Al2O3-content (1)

%

<= 0,050

(+)

663/0571

Fe2O3-content (1)

%

<= 0,010

(+)

663/0581

TiO2-content (1)

%

<= 0,030

(+)

663/0801

HCl-content (1)

%

<= 0,025

(+)

663/0990


nm

12

(+)


2 hours at 105°C





ZJQ_SPEZ/DEG/16.06.2009/14:32/dss0402p/001

E/K:0000610185/0000000000/0101/11

JQP0002

VEILIGHEIDSINFORMATIEBLAD (EC 1907/2006) AEROSIL® R 805 materiaalnr. specificatie VA-Nr


238222001312 144161 03163598

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AEROSIL® R 805

Firma


Telefoon Telefax

+49 (0)6181 59-4787 +49 (0)6181 59-4205 [email protected] +49 (0)7623-919191

Emailadres Telefoonnummer voor noodgevallen Gebruik van de chemische stof / preparaat Functie

Verf en lakken Afdichtstoffen lijm vloeihulpmiddel Versterkingsmiddelen

REACH-registratienr.: indien aanwezig in hfst. 3 vermeld 2. IDENTIFICATIE VAN DE GEVAREN Andere Gevaren Het product is volgens de ons ter beschikking staande gegevens geen gevaarlijke stof in de zin van de wet op chemicaliën resp. de verordening op gevaarlijke stoffen in de momenteel actuele versie.


Informatie over de bestanddelen / Gevaarlijke bestanddelen volgens richtlijn 67/548/EG of richtlijn 1999/45/EG • Silaan, trimethoxyoctyl-, hydrolyseprodukten met silica 92797-60-9 296-597-2 CAS-Nr. EG-Nr. Teksten van de R-zinnen; zie hoofdstuk 16 4. EERSTEHULPMAATREGELEN Inademing Bij vrijkomen van product in stofvorm: Mogelijke klachten: hoesten, niezen Slachtoffer naar de frisse lucht brengen. Contact met de huid Met veel water en zeep afwassen. Contact met de ogen Mogelijke klachten veroorzaakt door effect vreemd voorwerp. Bij geopend ooglid zorgvuldig met veel water spoelen.

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3.7 / NL 30.09.2011 25.06.2012 2/7

Bij blijvende klachten: Oogarts raadplegen. Inslikken Mond reinigen met water en daarna veel water drinken. Na opname van grotere hoeveelheden van de substantie / Bij klachten: Voor medische behandeling zorgen. Belangrijkste acute en uitgestelde symptomen en effecten Verschijnselen niet bekend Gevaren niet bekend Vermelding van de vereiste onmiddellijke medische verzorging en speciale behandeling Geen risico's die speciale eerstehulpmaatregelen vereisen. 5. BRANDBESTRIJDINGSMAATREGELEN Geschikte blusmiddelen alle blusmiddelen geschikt Speciale gevaren die door de stof of het mengsel worden veroorzaakt In geval van brand kunnen vrijkomen: koolmonoxyde en kooldioxyde. Advies voor brandweerlieden Bluswater mag niet in de riolering, de ondergrond of in open water lopen. Zorgen voor voldoende mogelijkheden om het bluswater op te vangen. Verbrandingsresten en verontreinigd bluswater moeten overeenkomstig de plaatselijke voorschriften van de autoriteiten verwijderd worden. 6. MAATREGELEN BIJ ACCIDENTEEL VRIJKOMEN VAN DE STOF OF HET PREPARAAT Persoonlijke voorzorgsmaatregelen, beschermde uitrusting en noodprocedures Persoonlijke beschermingsmiddelen dragen. Milieuvoorzorgsmaatregelen Mag niet in afvalwater bodem open water grondwater riolering terechtkomen. Insluitings- en reinigingsmethoden en -materiaal Gemorst materiaal opvegen of opzuigen en in een geschikt vat afvoeren voor verwijdering. Verdere aanwijzingen Vorming van stof vermijden. 7. HANTERING EN OPSLAG Hantering Voorzorgsmaatregelen voor het veilig hanteren van de stof of het mengsel Eventueel: Objectafzuiging. Aanwijzingen voor bescherming tegen brand en explosie Maatregelen nemen om het ontstaan van elektrostatische lading te voorkomen. Als er reparatiewerkzaamheden aan de productie-installatie(b.v. laswerkzaamheden) noodzakelijk zijn, moet de zone, waarin de reparatie wordt uitgevoerd, verregaand vrij zijn van het product. Klasse voor stofexplosie St1 Methode: Gestandaardiseerde max. drukstijgingsnelheid, KSt:

EU-GHS(P04/001) / 29.09.2011 00:35

VDI-richtlijn 2263 blad 1 < 3 bar·m/s



238222001312 144161 03163598

3.7 / NL 30.09.2011 25.06.2012 3/7

genormaliseerde 1 m3 container, ontstekingsenergie 10 kJ Opslag Voorwaarden voor een veilige opslag, met inbegrip van incompatibele producten Tegen hitte en zonstraling beschermen. De verpakkingen goed gesloten op een droge, koele en goed geventileerde plaats bewaren.

8. MAATREGELEN TER BEHEERSING VAN BLOOTSTELLING/PERSOONLIJKE BESCHERMING Controleparameters • Stof CAS-Nr. Controleparameters Expositiewijze


Tijdgewogen gemiddelde (TWA):(MAC (NL))


10 mg/m3 Inhaleerbaar

Tijdgewogen gemiddelde (TWA):(MAC (NL))

Persoonlijke beschermingsmiddelen Adembescherming Geen speciale beschermingsmiddelen nodig. Bij het optreden van stof: Stofmasker met deeltjesfilter P2 Bescherming van de handen Veiligheidshandschoenen van de volgende materialen dragen: stof, rubber, leer. De gegevens van de materiaaldikte en de doorbraaktijd zijn niet van toepassing voor niet opgeloste vaste/verstuifbare stoffen. Oogbescherming veiligheidsbril met zijkleppen Bij het optreden van stof: roosterbril Bescherming van de huid en het lichaam Geen speciale beschermingsmiddelen nodig. Hygiënische maatregelen Niet eten, drinken of roken tijdens gebruik. Voor een pauze en bij beëindiging van het werk handen en/of gezicht wassen. Gebruik van zeer vette zeep en een huidcreme ter verzorging van de huid om een optimale huidbescherming te waarborgen. Verontreinigde kleding wassen vooraleer opnieuw te gebruiken. Beschermende maatregelen Hanteer overeenkomstig goede industriële hygiëne en veiligheid. Bij mogelijkheid tot contact met de huid / ogen moet(en) de aangegeven handschoenen / bril / lichaamsbescherming worden gebruikt. Bij overschrijding van de voor de werkplek geldende waarden en/of bij vrijkomen van grotere hoeveelheden (lek, morsen, stof) moet het aangegeven ademmasker worden gebruikt. 9. FYSISCHE EN CHEMISCHE EIGENSCHAPPEN Voorkomen Vorm Kleur Geur

EU-GHS(P04/001) / 29.09.2011 00:35

poeder wit reukloos



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3,5 - 5,5

(40 g / l) (20 °C) water / methanol 1: 1 in suspensie Milieu:

Smeltpunt/traject

niet van toepassing

Kookpunt/traject

niet van toepassing

Vlampunt

niet van toepassing


niet bepaald


460 °C Methode:

Zelfontvlambaarheid

niet bepaald


stof: Methode:


niet bepaald


> 1 kJ

VDI-richtlijn 2263 blad 1

1500 g/m³ VDI 2263 genormaliseerde 1 m3 container

<= 10 kJ Methode:

VDI-richtlijn 2263 blad 1 genormaliseerde 1 m3 container Maximale absolute explosiedruk

2,8 bar Methode: VDI-richtlijn 2263 blad 1 genormaliseerde 1 m3 container

Dampspanning

niet van toepassing

Dichtheid

ca. 2,1 g/cm3

Opstampdichtheid


(20 °C)

DIN / ISO 787/11


onoplosbaar


niet van toepassing niet van toepassing

10. STABILITEIT EN REACTIVITEIT Te vermijden omstandigheden

Bij temperaturen > 150 °C gaat de hydrofobie verloren.

Gevaarlijke ontledingsproducten

Koolmonoxide, kooldioxide (CO2)

11. TOXICOLOGISCHE INFORMATIE

EU-GHS(P04/001) / 29.09.2011 00:35



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3.7 / NL 30.09.2011 25.06.2012 5/7

Acute orale toxiciteit


Huidirritatie

konijn / OECD Test Richtlijn 404 niet irriterend

Oogirritatie

konijn / OECD Test Richtlijn 405 niet irriterend

gentoxiciteit in vitro

Ames proef S. typhimurium / E. coli negatief Methode: literatuur

Ervaring bij mensen

Silicose of andere productspecifieke ziekten van de ademhalingswegen zijn in de omgang met het product niet geobserveerd.

12. ECOLOGISCHE INFORMATIE Ecotoxiciteitseffecten Ecotoxicologisch onderzoeken betreffende dit product zijn niet beschikbaar.

13. INSTRUCTIES VOOR VERWIJDERING product Kan onder het inachtnemen van de vereiste technische voorschriften na overleg met de verwerker en de betreffende overheidsinstantie samen met huisvuil worden opgeslagen. Ongereinigde verpakkingen Het gewassen verpakkingsmateriaal overbrengen naar plaatselijke recycling. Andere landen: nationale voorschriften in acht nemen. Afvalstofnummer Voor dit product kan geen afvalcodenummer conform het Europese afvalregister worden vastgelegd, omdat pas het beoogde gebruik door de verbruiker een toewijzing mogelijk maakt. Het afvalcodenummer dient conform het Europese afvalregister (EU-beslissing inzake afvalregister 2000/532/EG) in overleg met de verwerker/fabrikant/de overheid te worden vastgelegd.


Beladingsgegevens/Opmerkingen IATA_C Air shipments must not exceed a quantity of three pallets (with bags) and/or three big bags in the same aircraft. IATA_P Air shipments must not exceed a quantity of three pallets (with bags) and/or three big bags in the same aircraft. IMDG To be stowed away from any source of heat (such as heatable fuel tanks, steam piping, etc.) Transport/nadere gegevens Geen gevaarlijke stof volgens klasse 4.2 in verpakkingen kleiner/gelijk 3 m³. Indien in verpakkingen (zakken, big bags of silo) met een volume van meer dan 3 m³, dan gevaarlijke stof conform klasse 4.2 UN 3190 III.

EU-GHS(P04/001) / 29.09.2011 00:35


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15. WETTELIJK VERPLICHTE INFORMATIE Etikettering overeenkomstig de EG-Richtlijnen Andere gegevens

Het product is volgens de ons ter beschikking staande gegevens geen gevaarlijke stof in de zin van de wet op chemicaliën resp. de verordening op gevaarlijke stoffen in de momenteel actuele versie.

Nationale wetgeving

16. OVERIGE INFORMATIE teksten van de R-zinnen Verdere informatie Wijzigingen die zijn aangebracht na het verschijnen van de vorige uitgave worden gemarkeerd in de kantlijn. Deze uitgave vervangt alle vroegere versies. De in dit veiligheidsinformatieblad verstrekte gegevens zijn zover ons bekend juist op de aangegeven uitgiftedatum. Deze informatie is uitsluitend bedoeld als handleiding voor veilig hanteren, gebruik, verwerken, opslag, vervoer, verwijderen en vrijkomen en mag niet beschouwd worden als een garantie of aanduiding van kwaliteit. De informatie heeft alleen betrekking op het hierin vermelde product en is niet zonder meer geldig wanneer het samen met andere producten of in enig ander procede wordt gebruikt, tenzij dit in de tekst vermeld wordt.

EU-GHS(P04/001) / 29.09.2011 00:35


238222001312 144161 03163598


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Legenda ADR

European Agreement concerning the International Carriage of Dangerous Goods by Road

ADN

European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ASTM

American Society for Testing and Materials

ATP

Adaptation to Technical Progress

BCF

Bioconcentration Factor

BetrSichV

German Ordinance on Industrial Safety and Health

c. c.

closed cup (geschlossenes Gefäß)

CAS

Chemical Abstract Services

CESIO

European Committee of Organic Surfactants and their Intermediates

ChemG

German Chemicals Act

CMR

Carcinogenic-Mutagenic-toxic for Reproduction

DIN

German Institute for Standardization

DNEL

Derived No Effect Level

EINECS

European Inventory of Existing Commercial Chemical Substances

GefStoffV

German Ordinance on Hazardous Substances

GGVSEB

German ordinance for road, rail and inland waterway transportation of dangerous goods

GGVSee

German ordinance for sea transportation of dangerous goods

GLP

Good Laboratory Practice.

GMO

Genetic Modified Organism

IATA DGR

International Air Transport Association – Dangerous Goods Regulations

ICAO-TI

International Civil Aviation Organisation - Technical Instructions

IMDG Code

International Maritime Dangerous Goods Code

ISO

International Organization For Standardization

LOAEL

Lowest Observed Adverse Effect Level

LOEL

Lowest Observed Effect Level

NOAEL

No Observed Adverse Effect Level

NOEC

No Observed Effect Concentration

NOEL

No Observed Effect Level

o. c.

open cup (offenes Gefäß)

OECD

Organisation for Economic Cooperation and Development

OEL

Occupational Exposure Limit

PBT

Persistent, Bioaccumulative, Toxic

PEC

Predicted Effect Concentration

PNEC

Predicted No Effect Concentration

RID

Regulations concerning the International Carriage of Dangerous Goods by Rail

TA

Technical Instructions (German Ordinance)

TPR

Third Party Representative (Art. 4)

TRGS

Technical Rules for Hazardous Substances (German Regulations)

VCI

German "Verband der Chemischen Industrie e. V."

vPvB

Very Persistent, Very Bioaccumulative

VOC

Volatile Organic Compounds

VwVwS

German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water Hazard Classes

WGK

German Water Hazard Class

WHO

World Health Organization

EU-GHS(P04/001) / 29.09.2011 00:35

Bijlage XIX

SAFËTY DATA Sl-iEET (Ee 1so7/2006) AEROSIL@ R972

no. speciricarion VA-Nr Meleriêí

t.

Version

13287s ffïlïï"d"" paoe

?.3

/ / REG-EU

@ Evq"*i.qÍ

11;71i1,i

1lz

IDËNïIFICATiOIU OF THË $UBSïANCËJPREPARAïION AFID OF THË COfuIPANY/UNDËRïAKiNG

Product information ïrede

iiane

AËRCS|L@

Company

fi S72

Evonik lndustries AG inorganic Maierials Prod uktsicherheit I tt{-PT-PS Postfach 1345

D-63403 Hanau aA À-â +4vtuj0tó!aà DY-.+íóf +49 {0)618í 59-4205

ieiePí'0írrj

Telefax Êmail address [rliergeney

ieie phsne

[email protected]

iiLimber

Use of the Substance /

"43 i0i7623-91Ê1S1

Preparalion Siiicone rubber JíJaiicí ti5

Paints and lacquers Coloured printing inks

ïon*r Adhesive Cosmetics Coating agent pesiieide REACH Registration No.: if avaiiable lísted in Chapter. 3 2" I.IAZARDS IDENT!FICATION

Classification according to F,egulation (EC) No.1272!2Q08 [CLP]

Renaikr

f.l*l a l'iazeidcus substance

*i mixii;ie ac-*aidi*g t*

Regi:iati*lr {EC} I'Jo. 127212**8"

Classification as per Directive 67l548lEC or Directive 199gl45lEC iiot e hezerejei;s

sr-;beianee +r prepareiir:n aceoriiing

io ËC-direciives 67i5481ËEC or i99$1451ÊC.

GHS-l-abelting

Remarks

Labeiiirrg not requiret! sc..jaÍding ia ËU-CLF tf,njinance í1272í2*fi8).

Other Hazards A PBTivFvE evaluation is nci availeble, since a ehemicai safeiy evaiuaiícn is nci requireci I hae nci been carried out.

3. COMPOSITIOH/INFORMATION ON INGREDIENT$

lníormation an ingredients I FiazarcÍous ccrïponents as per ËU-CLP Regulation (ECi Ho. 1272í2908 o

SiÍane, dichlorodimethyl-, reactích products with silica

CAS-f{c.

aU-óHSíPD4/00i i I 01 1 2.2012

6861 1*+4-9

D5:31

i-i. ivo.

lt

l-ó!j'j.-4

$AFETY DATA SHFET

(EC reo7r2oo6)

AEROS||-@ R 972 ?.371 REG trit

^f,^+^.;-í ^-,

Revision date Print Date ?

132875

Specification VA-Nr

tt,lz.zutz

ê-*' crrnflËrd k Ëí +éE ttt ?

aÈk,

18.',tz.2012 4 ia

inf*r*ratian *n ingredients I HaaardouË ccE"!ïpsnents as per *ireetive 6i154Ê/FC or Sireetive 19Sgt45/ËC

* Silsne, diehloroCimethyl-, r*acÉiot': praducts with silica

{;45-No. Texts

oí

68ë'',i 1-44-g

L(, - t\{J

H nhrases. see in Cha;:ter 16

Qaa rl,rrntor

1Ê, ínr iawt nf rictz nhrococ

'l! iEtElêT *. ltlg a ^!t1 ttÀE^Qt !t!Lngvr\L+tÉËQ -t9

lg'rira!atío* ln case product dusi is released: Poss!ble discorrort: cough, sneezing ir^.,^ lVtUvË

.,;^!l*stt-.r!lllJ

i^r^ {.,-,-!. -i" rlrLV !rÉ!rr! r-r'l

$kin contact \iVash off with plenty of water and soap"

Eye eontact Possible discomfcrt is due to ïoreign substanee effect. Rinse tharauqhl'y'oïiïh clentir cf v:aie:" keeping e'ye1id apen. In case of persistent discomfort: Consuit an ophthalmologist.

lngestion r-i^^É !JrEG!!

n^..t!r.Ír_,urr!

.rriÍJ-r yrurEr !tr,-rr r;t-,tn"

-,,À 4rru

Atiî, u.rrr^

4í+',,t.,ê,À+ crrrrcvuruè

nia^4., rrrntar i-r!E'!r'/'Jt ^{ vlAtEi

After absorbing large amounts of substance I ln case of drscomfod: Supply with medical care iviost imporiant syrnptoms and effeets, both aeute anei deia.veel

Symptoms None known li===rde

None known

indicaticn of

an3r

imr*eeiiaíe rnedicai atten{-ior: and sp*eiai ïreatment needed

No hazards which require special first aid measilres. 5, F!ft,Ë-FIËi.iïiÈiG

flÍ

EÁË

U

FIES

Suitable extinguishi ng medía ll ^.,ri^^.,i^L:^^ nll ^ gÀtllluul>lltl:g

-,,f,^.-^^^^r{.es sr ^,,i+^Lt^ }!rdr lrts èurritér

Special haaards arising from the substance or mixture May be reieased in ease of fire: carl:on monoxide, carbon dioxide, íormaldeh-vde and methane.

Àivice

f+ r

firefighiers

Water used to extingursh fire should nat enter drainage systems, soil or stretches of water. Ensure there are sufíicient retaining facilities fcr vo'ater used tc extinguish fii-e. f ,,--. --.- !,.--^ +l--- ^,.r;Fê,..-.!,-.-.,,^+^--*J.--.n+.a.-;4-+^l riíë íii$!íjijiis.iiiii coniailninaied fir* e:.iinguishing lvat*r .-t,^+ must Lb* dispa;*ri cf in acccrdanee,oviih iacai regulations. Ê. ACCIDENTAL RELEASE hAEASURES

Personal precautions, protective equi pment and emergency proced u res tAlaar narcnnal .'.,"u,P' nrn+nnfirra

anr rinmant ,J!tu,P,r,L',!r-

Ënvironmental precauiions Do not ailow entrance in sewage water, soil stretches of water, grcundwater, drainage systerns.

SAFETY DÁTA SHEET {Ec

1907/2006)

AEROSIL@ R 972 M*ierÍeí nc. Specification VA-Nr

Version Revision date Print Date

i.37 / REG_EU

P

3t7

Methods and material far csntainment and cleaning

17j22912

@ evq#r.#

18.12.2A12

i.rp

Sweep up or vacuum up spillage and collect in suitable container for disposal.

Àdditional advice Avoid dust formation 7. HANDLING ANB $TORAGË

Handling Precautions for safe handling if necessary: Lccal veniiieticn.

Advice on protection against fire and explosion Ï^1.^ ^-^^^,,+i^^^^, r 4hE |/tËuautlvrrgt

Y iltÉdèulEè

^^^;^^+rit ètcttu ^+^+i^ ,{i^^l, ^.^^d\-ldlr utèuttatvEt,

Dust explosion class 1 m3

vessel = not dust explosive

t/Dl Guidelin.. 2263 sheet I Storage

Conciiiions for saÍe storage. including any incompaÉibiiiiies Keep in a dry piace.

8. EXPOSURË CONïROLS/PËRSONAL PROïECTION

Control parameters

Personal proiective equipment Respiratory protection Nc special protective equípment i'equired. lf dusi oceurs: Dust mask with P2 particle fiiier Hand protection \,rear protecti'le gloves made of the fc'liolving materials: materlai, rubber, leather. The material thickness and rupture time data do not apply to non-solute solids / dusts. Eye protection SafeÍy giasses wiih side-shields lf dust occurs: basket-shaped glasses

Skin and body protectíon No speciai protective equipmeni required"

Hygiene measures When using, do not eat, drink or smoke. Wash face andlor hands beÍoi"e break and end of To ensure ideal skin protection: use super Íatted soaps and skin cream for skin care. Wash contaminated clothing before re-usê.

r,voi'k.

Protective measures Handle in accordance with good industrial hygiene and safety practices. lf there is the possibility of skin/eye contact, the indicated hand/eyelbody protection should be used. lf workplace exposure limits are exceeded and/or larger anrounts are released (leakage, spilling, dust) the indicated respiratory protection should be used.

EU"GHS(PM/001)/01 12 2012 air31

SAFETY DATA SHEËT (Ec

íso7r2oo6)

AEROSIL@ R 972 Specification VA-Nr

I.37 / REG*EU

Versicn Revision date Print Date

f.lfaterial no.

13287s

17j22012

@ evq"*À?Í

18.12.2812

4t7

g. PHYSICAL AND CHEMICAL PROFERTIES

Appearance powder white odourless

Farn Colour Odour physical state

soiid

lnformation on basic physical and chemical properties t+u g r r) tlu -L) water / methanol 1: 1 in suspension

pfi

J,b -

5,3

Medium:

llleiiing poinï/rarrge

nci applicabie

Boiling pointlrange

not appiicable

Flash pcirrt

not appiicabie

Flammabiiity (solid, gasi

not applicable

igniiian lemperature

> 800

"c

Methodr

VDl2263

Autoinflammabilit_v

not appiicable

Lower explosion limit

not determined

Lipper explcsian iimii

not determineci

Minimum iqnition enerqy

not applicable

Vapour pressure

nci appiicable

Density

ca.2,2

ïapped density

rc

g/cm3

ÀOall

Method:

DIN

/ ISO 787111

2 t iltgil

yvi'rul 5uluullxy Panition coefficienr

tz1 "C,

(n

-octanol/water)

Viscosiiy, dynanic

not applicable

noi applicable

Í9. STAB|LITY AÍ.ID RËACTIV|ïY

1

Conditions to avoid

With temperatures > 300'C, hydrophobicity is lost.

Hazardcr.rs decomposiiion prodi:cLs

Carbon monexide, ea;-bon dioxicie {COzi

1. TOXICOLOGICAL INFORMATION

=r r"dHqrzná/frn

1

rr

rrl

SAFËïY DATA SHËËï (Ec íeo7l2006) AEROST!-@ R 972' itr4Í^.i^t

latQ-rÉ

Specification VA-Nr

G Evq"flljÍ

Í,37 / REG*EU 17.12.2012 18.12.2012

Version Revision date Print Date

h^

517

Acule oral taxicily

LUDU

r(Ar. >

CUUU

Íilg/Kg

Method: literature Acute inhaiaÍifft toxieiiy

LCO Rat; 0,477 mgll l4 h Method. analogy OECD

(maximum concentration attainable in experiments) Rabbii / literaiure

Skin irritation

not irritating Eye ii"ritatrcn

Rabbit / liieralure not irritating

Repeaied dose taxicrty

L,rÍat

no negative effeets inhalative

l!+ irreyersíble changes and nc indication af siiicosis. Carcinogenicity

no negative effects

Toxicity ta repicduction

no negative effscts

Human experience

Silicosis or other prociuct specific illnesses oÍ the respiratory tract were not observed ir-r association wiih ihe produci.

12. ECOLOGICAL INFORMATION -^^t^--i^2L.. ^g--^^ l=r.t,ru;f,.rUtry rEul9 Èt

Toxicity to fish

LC50 {Brachydanio rerio}: > 10000 mgii 196 h Method: OECD 203

Toxieity in

aq

uatic invei"lebrates

EC50 Daphnia magna: > iCI000 mgll t24

h

Methad: OECD 202 Toxicii,v tc algae

iC 50 scenedesrnus subspicaius; > 10000 mgít

i72h

Methad: OECD 201

Results of PBT assessment A PBTIvPvB evaluation is not available, since a chemical safety evaluation is not required / has not been carried out.

13. DISPOSAL CONSIDERATICINS Drndr ral

Can be ciisposed of with domestie reíuse in aecordance wiih the necess€ry technical regulations following consuiiaiion with waste disposal expert(s) and ihe responsibie authorities.

Uncleaned packaging Cffer rinseci packaging rrtaterialto lacai reeyeiing faeilities. Other couniries: observe the national regulations.

È

-LGlrslÈM Í01),

l,

.

2 2t12 15.3.,

$AFETY DATA SHEET (Ec lsoz/2006) AEROSIL@ R 972 ldaterial no"

Specification

132875

VA-Nr

Version Revisicn date Print Date Paqe

1.37 I REG_EU

17j22012

G evq#r"fl

18.12.2012

6t7

Waste Key Number No waste key number a$ per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined)use to which the product is put bythe eonsumer. The waste key number must be determined as per the European Waste ïy.rpes List {decision an fU Waste Types LisJ 2A00i532lEC) in cooperation with the dísposal íirm I producing firm / ofÍicrai authority.

14. TRAN$PORT INFORMATION

Transporífu rther i nformatic n Not dangerous according to transport regulations.

1

5. REGULATORY INFORM-ATION FJational legislation

I ó I

O. Lr ^?t I

!Fh aÀtF^Fll nEÍt' Itïr\rÍtrYtA a -tAÀt I IL,lï

Risk phrase iR phrase) texts Texts of the H-phrases Further information Changes since ihe iast varsion are highiighied in ihe margin. ïhis version repiaces aii previaiis ';ersions. ïhe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, proeêssing, storage, transportation, disposal and releasc and is nottc be eonsidered a warrantyor quality specification. ïhe informaiion reiaies only to ihe specific material designated and may not be vaiid for such material used in combination with any other materials or in any process, unless specified in the text.

ÉU-GHS(P041001 ) / 01

1

2 2D12 DÉ:31

SAFETY DATA SHEET {Ec ieoT/2006) AERO$IL@ R 972 Meteria{ nc. o^^î&^^+i^^ JpE!ilrudilurr

aa61i tJagt J

4

VA-Nr

Version Revision date

í.37 i REG_EU

Print Date

17.12.2012 18.12.2012

P

7

@ evqnr"S

t7

Legend

ADR ADN ADilR ASTM Aïp BCF BetrSiehV c. c. CAS CËS|O ChêmG CMR DtN DNEL EINECS GefStoffV GGVSEB GGVSee GLP GÈiO IATA DGR ICAO-TI |MDG Code ISO LOAEL LOEL NOAEL NOEC NOEL c. c. OECD OEL PgT PEC PNEC RID TA ïPR TRGS VCI vPvB VOC VwVwS WGK ntHO

ÊU-GHS{Pm1001

)

i

01.1 2.2O12 A5:31

European Agreemênt concerning the lnternátional Caniage of Dangerous Goods by Road European Agreement eoRcerniRg the lnternational Caniage of Dangerous Goods by lnland Wáterways European aEreerr'iefti concerning thê lniernáiioi'iêi carriage cf dangerous goods by inland waterways (ADNJ American Society for Testing árid l,Íaterials Adaptation to ïechnical Prcgress Bioconcentration Factor German Ordinánce on lnduslrial Safety and Healih closed cup Chemical Absiract Services European Committêê of Organic Surfacianis and iheir Intermediates Geiman Chemicais Act Carcinogenic-Mutagenic-toxic íor Reproduction German lnstitutê 'for Standardization Derived No Effect Level Ëuropean lnventory of Existing Cornmercial Chemical Substances German Ordinance on Hazardous Substances German ordinance for road, rail and inland walerway transpoÍtation of dangerous goods German ordinance for sea transportation oÍ dangerous goods Good Laboratory Practice. Geneiic Modiíied Organisnr lnternational Air ïransport Association

-

Dángerous Goods Regulations

lnternational Civil Aviation Organisation - Technical lnstructions ínternationêl Maritimê DêRgercus Goods C+de lnternational Organization For Standardization Lowest Observed Adverse EÍÍect Level Lowest Observed Effect Level No Observed Adverse Effeci Level No Observed Effect Concentration No Obseryed Fffect Level open cup Organisation for Economíc Cooperaticn and Development Occupational Exposure Limit Persistent, Bioaccumulative, Toxic Predicied Environmental Concentration Predicted No Effect Concentration Regulations conceming the lnternational Carriage of Dangerous Gccds by Rail Technicai lnstructions (German Odinance) Third Party Representative (Art. 4) Technical Rules for Hazardous $ubstances (German Regulations) German "Verband der ehemisehen lndustrie e. V." Very Persistent, Very Bioaccumulative Volatile Organic Compounds German Administrative Regulation on the Classification of Subslances Hazardous to Watêrs into Water Hazard Classes German Water Hazard Class World Health O!'ganízation

Bijlage XX

___ ___

Specification ____________________________________________________________________ AEROSIL® TT 600 Evonik Degussa GmbH

Spec. no.: 1370/1 Material number, Bulk: 23.8114.0020.00 Valid for all forms of packaging Standard


1 of 1 03.09.2009

valid from:

10.10.1998




663/0200 663/0200

pH

m²/g

200 (150 - 250) 3,6 - 4,5

in 4% dispersion


Units Typical Values ____________________________________________________________________ 663/0501 663/

SiO2-content (1)

%

>= 99,8

(+)

663/0701 663/0701


g/l

60

(+)

663/0300 663/0300

Moisture

%

<= 2,5

(+)

663/0400 663/0400

Ignition loss

%

<= 2,5

(+)

663/0801

HCl-content (1)

%

<= 0,025

(+)

663/0563

Al2O3-content (1)

%

<= 0,050

(+)

663/0571

Fe2O3-content (1)

%

<= 0,003

(+)

663/0581

TiO2-content (1)

%

<= 0,030

(+)

663/0900 663/0900

Sieve residue by Mocker, 45 µm

%

<= 0,050

(+)

663/0990


nm

40

(+)



2 hours at 105°C


acc. to DIN ISO 787/XVIII, Apr. 1984



ZJQ_SPEZ/DEG/03.09.2009/09:54/dss0401p/001

E/K:0000610185/0000000000/0101/11

JQP0002

VEILIGHEIDSINFORMATIEBLAD (EC 1907/2006) AEROSIL® TT 600 materiaalnr. specificatie VA-Nr


238114002099 100746 03099736

1.25 / NL 08.09.2011 05.03.2012 1/7


AEROSIL® TT 600

Firma


Telefoon Telefax

+49 (0)6181 59-4787 +49 (0)6181 59-4205 [email protected] +49 (0)7623-919191


Anti-blokrmiddel Verf en lakken katalysatordrager

REACH-registratienr.: indien aanwezig in hfst. 3 vermeld 2. IDENTIFICATIE VAN DE GEVAREN Andere Gevaren Het product is volgens de ons ter beschikking staande gegevens geen gevaarlijke stof in de zin van de wet op chemicaliën resp. de verordening op gevaarlijke stoffen in de momenteel actuele versie.



231-545-4

7631-86-9

Teksten van de R-zinnen; zie hoofdstuk 16 4. EERSTEHULPMAATREGELEN Inademing Bij vrijkomen van product in stofvorm: Mogelijke klachten: hoesten, niezen Slachtoffer naar de frisse lucht brengen. Contact met de huid Met veel water en zeep afwassen. Contact met de ogen Mogelijke klachten veroorzaakt door effect vreemd voorwerp. Bij geopend ooglid zorgvuldig met veel water spoelen. Bij blijvende klachten: Oogarts raadplegen.

EU-GHS(P04/001) / 06.09.2011 04:44

REACH-nr.

01-2119379499-16-0000 (TPR)


238114002099 100746 03099736


1.25 / NL 08.09.2011 05.03.2012 2/7

Inslikken Mond reinigen met water en daarna veel water drinken. Na opname van grotere hoeveelheden van de substantie / Bij klachten: Voor medische behandeling zorgen. Belangrijkste acute en uitgestelde symptomen en effecten Verschijnselen niet bekend Gevaren niet bekend Vermelding van de vereiste onmiddellijke medische verzorging en speciale behandeling Geen risico's die speciale eerstehulpmaatregelen vereisen. 5. BRANDBESTRIJDINGSMAATREGELEN Geschikte blusmiddelen alle blusmiddelen geschikt Speciale gevaren die door de stof of het mengsel worden veroorzaakt niet bekend Advies voor brandweerlieden Bluswater mag niet in de riolering, de ondergrond of in open water lopen. Zorgen voor voldoende mogelijkheden om het bluswater op te vangen. Verbrandingsresten en verontreinigd bluswater moeten overeenkomstig de plaatselijke voorschriften van de autoriteiten verwijderd worden. 6. MAATREGELEN BIJ ACCIDENTEEL VRIJKOMEN VAN DE STOF OF HET PREPARAAT Persoonlijke voorzorgsmaatregelen, beschermde uitrusting en noodprocedures Persoonlijke beschermingsmiddelen dragen. Insluitings- en reinigingsmethoden en -materiaal Gemorst materiaal opvegen of opzuigen en in een geschikt vat afvoeren voor verwijdering. 7. HANTERING EN OPSLAG Hantering Voorzorgsmaatregelen voor het veilig hanteren van de stof of het mengsel Eventueel: Objectafzuiging. Aanwijzingen voor bescherming tegen brand en explosie Maatregelen treffen tegen ontladingen van statische elektriciteit. Opslag Voorwaarden voor een veilige opslag, met inbegrip van incompatibele producten Op een droge plaats bewaren.

8. MAATREGELEN TER BEHEERSING VAN BLOOTSTELLING/PERSOONLIJKE BESCHERMING Controleparameters • Siliciumdioxide, chemisch bereid

EU-GHS(P04/001) / 06.09.2011 04:44


238114002099 100746 03099736

CAS-Nr.






EG-Nr.

1.25 / NL 08.09.2011 05.03.2012 3/7 231-545-4 Tijdgewogen gemiddelde (TWA):(MAC (NL)) Tijdgewogen gemiddelde (TWA):(MAC (NL))

Persoonlijke beschermingsmiddelen Adembescherming Geen speciale beschermingsmiddelen nodig. Bij het optreden van stof: Stofmasker met deeltjesfilter P2 Bescherming van de handen Veiligheidshandschoenen van de volgende materialen dragen: stof, rubber, leer. De gegevens van de materiaaldikte en de doorbraaktijd zijn niet van toepassing voor niet opgeloste vaste/verstuifbare stoffen. Oogbescherming veiligheidsbril met zijkleppen Bij het optreden van stof: roosterbril Bescherming van de huid en het lichaam Geen speciale beschermingsmiddelen nodig. Hygiënische maatregelen Niet eten, drinken of roken tijdens gebruik. Voor een pauze en bij beëindiging van het werk handen en/of gezicht wassen. Gebruik van zeer vette zeep en een huidcreme ter verzorging van de huid om een optimale huidbescherming te waarborgen. Verontreinigde kleding wassen vooraleer opnieuw te gebruiken. Beschermende maatregelen Hanteer overeenkomstig goede industriële hygiëne en veiligheid. Bij mogelijkheid tot contact met de huid / ogen moet(en) de aangegeven handschoenen / bril / lichaamsbescherming worden gebruikt. Bij overschrijding van de voor de werkplek geldende waarden en/of bij vrijkomen van grotere hoeveelheden (lek, morsen, stof) moet het aangegeven ademmasker worden gebruikt. 9. FYSISCHE EN CHEMISCHE EIGENSCHAPPEN Voorkomen Vorm Kleur Geur

poeder wit reukloos


3,6 - 4,5 (40 g / l) (suspensie)

Smeltpunt/traject

ca. 1700 °C

Kookpunt/traject

niet van toepassing

Vlampunt

niet van toepassing


niet van toepassing


niet van toepassing

Zelfontvlambaarheid

niet van toepassing

EU-GHS(P04/001) / 06.09.2011 04:44

(20 °C)



238114002099 100746 03099736


> 2000 °C


niet van toepassing


niet van toepassing


niet van toepassing

Dampspanning

niet van toepassing

Dichtheid

ca. 2,2 g/cm3

Opstampdichtheid


1.25 / NL 08.09.2011 05.03.2012 4/7

(20 °C)

DIN / ISO 787/11


Moeilijk oplosbaar


niet van toepassing niet van toepassing


niet bekend

11. TOXICOLOGISCHE INFORMATIE Acute orale toxiciteit Acute inhalatoire toxiciteit

LD50 rat: > 10000 mg/kg Methode: literatuur LC0 rat: 0,139 mg/l / 4 u Methode: literatuur

(experimenteel maximaal bereikbare concentratie) Mortaliteit is niet opgetreden. (limiettest) Acute dermale toxiciteit


Huidirritatie


Oogirritatie



EU-GHS(P04/001) / 06.09.2011 04:44




238114002099 100746 03099736

1.25 / NL 08.09.2011 05.03.2012 5/7



Carcinogeniteit








13. INSTRUCTIES VOOR VERWIJDERING product Kan onder het inachtnemen van de vereiste technische voorschriften na overleg met de verwerker en de betreffende overheidsinstantie samen met huisvuil worden opgeslagen. Ongereinigde verpakkingen Het gewassen verpakkingsmateriaal overbrengen naar plaatselijke recycling. Andere landen: nationale voorschriften in acht nemen. Afvalstofnummer Voor dit product kan geen afvalcodenummer conform het Europese afvalregister worden vastgelegd, omdat pas het beoogde gebruik door de verbruiker een toewijzing mogelijk maakt. Het afvalcodenummer dient conform het Europese afvalregister (EU-beslissing inzake afvalregister 2000/532/EG) in overleg met de verwerker/fabrikant/de overheid te worden vastgelegd.



15. WETTELIJK VERPLICHTE INFORMATIE Etikettering overeenkomstig de EG-Richtlijnen Andere gegevens

EU-GHS(P04/001) / 06.09.2011 04:44

Het product is volgens de ons ter beschikking staande gegevens geen gevaarlijke stof in de zin van de wet op chemicaliën resp. de verordening op gevaarlijke stoffen in de momenteel actuele versie.


238114002099 100746 03099736


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Nationale wetgeving

16. OVERIGE INFORMATIE teksten van de R-zinnen Verdere informatie Wijzigingen die zijn aangebracht na het verschijnen van de vorige uitgave worden gemarkeerd in de kantlijn. Deze uitgave vervangt alle vroegere versies. De in dit veiligheidsinformatieblad verstrekte gegevens zijn zover ons bekend juist op de aangegeven uitgiftedatum. Deze informatie is uitsluitend bedoeld als handleiding voor veilig hanteren, gebruik, verwerken, opslag, vervoer, verwijderen en vrijkomen en mag niet beschouwd worden als een garantie of aanduiding van kwaliteit. De informatie heeft alleen betrekking op het hierin vermelde product en is niet zonder meer geldig wanneer het samen met andere producten of in enig ander procede wordt gebruikt, tenzij dit in de tekst vermeld wordt.

EU-GHS(P04/001) / 06.09.2011 04:44


238114002099 100746 03099736


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Legenda ADR

European Agreement concerning the International Carriage of Dangerous Goods by Road

ADN

European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways

ASTM

American Society for Testing and Materials

ATP

Adaptation to Technical Progress

BCF

Bioconcentration Factor

BetrSichV

German Ordinance on Industrial Safety and Health

c. c.

closed cup (geschlossenes Gefäß)

CAS

Chemical Abstract Services

CESIO

European Committee of Organic Surfactants and their Intermediates

ChemG

German Chemicals Act

CMR

Carcinogenic-Mutagenic-toxic for Reproduction

DIN

German Institute for Standardization

DNEL

Derived No Effect Level

EINECS

European Inventory of Existing Commercial Chemical Substances

GefStoffV

German Ordinance on Hazardous Substances

GGVSEB

German ordinance for road, rail and inland waterway transportation of dangerous goods

GGVSee

German ordinance for sea transportation of dangerous goods

GLP

Good Laboratory Practice.

GMO

Genetic Modified Organism

IATA DGR

International Air Transport Association – Dangerous Goods Regulations

ICAO-TI

International Civil Aviation Organisation - Technical Instructions

IMDG Code

International Maritime Dangerous Goods Code

ISO

International Organization For Standardization

LOAEL

Lowest Observed Adverse Effect Level

LOEL

Lowest Observed Effect Level

NOAEL

No Observed Adverse Effect Level

NOEC

No Observed Effect Concentration

NOEL

No Observed Effect Level

o. c.

open cup (offenes Gefäß)

OECD

Organisation for Economic Cooperation and Development

OEL

Occupational Exposure Limit

PBT

Persistent, Bioaccumulative, Toxic

PEC

Predicted Effect Concentration

PNEC

Predicted No Effect Concentration

RID

Regulations concerning the International Carriage of Dangerous Goods by Rail

TA

Technical Instructions (German Ordinance)

TPR

Third Party Representative (Art. 4)

TRGS

Technical Rules for Hazardous Substances (German Regulations)

VCI

German "Verband der Chemischen Industrie e. V."

vPvB

Very Persistent, Very Bioaccumulative

VOC

Volatile Organic Compounds

VwVwS

German Administrative Regulation on the Classification of Substances Hazardous to Waters into Water Hazard Classes

WGK

German Water Hazard Class

WHO

World Health Organization

EU-GHS(P04/001) / 06.09.2011 04:44

Bijlage XXI

Mac OS 9.2J illustrator 10J CM-2600d_cover.ai 2003.9.12

SPECTROPHOTOMETER

CM-2600d Portable, Compact, Easy to Use Performs Like a Desktop Spectrophotometer World's first portable spectrophotometer equipped with automatic UV adjustment function. Advanced Numerical UV Control dramatically reduces evaluation time.

illustrator 10J CM-2600d_inside.ai 2003.9.12

The CM-2600d is a portable integrating sphere spectrophotometer designed for versatility in various applications. Promotes accurate color communication. Conforms to all widely accepted industry standards and allows measurements in all commonly used color spaces.

Simultaneous measurement of SCI (specular component included) and SCE (specular component excluded). Advanced Numerical Gloss Control. Simultaneous measurement of SCI and SCE displays data on the LCD in 1.5 seconds. Unlike conventional spectrophotometers, there is no need to switch between SCI and SCE mode. This improves working efficiency, and provides stable measured data since the measurement area does not shift when the mode is switched. And also Relativity Gloss Value can be displayed by using Numerical Gloss Control. • SCI is a method in which measurements are taken with the specular reflection included. For this reason, it minimizes influences of the surface condition of a sample, and is especially suitable for color quality control and Computer Color Matching. Relativity Gloss Value • SCE is a method in which measurements are taken The LCD specifications are subject to excluding the specular reflection. For this reason, it change without prior notice. provides measurement results similar to those observed by the human eye.

High reliability and long life. Maintenance-free design.

Light source for evaluation of specular component Light source for SCI

The optics use an integrating sphere to provide diffuse illumination/8-degree viewing system. The CM-2600d conforms to all widely accepted industry standards including ISO, JIS, DIN, CIE and ASTM, and generates measurements in color spaces such as L*a*b*, Yxy, Munsell and CMC.

For plastics, paints, resins and consumer products

Powerful partnership between CM-2600d and SpectraMagic Color Quality Control Software

SpectraMagic (Optional) Supports Windows®98/2000,Windows NT ®4.0 Consistent color communication. Since automatic setting of color difference tolerances is possible, accurate Pass/Fail information can be given to customers and manufacturers. Enables color analysis from various viewpoints. Detailed, easy-tosee spectral graph. Exports data to spreadsheet applications.

In various applications

Expanded LCD display (64 x 240 dots)

The number of moving parts used in the instrument is minimized through the introduction of numerical control technology. The CM-2600d can be used with confidence, since it has been developed, manufactured and calibrated to meet ISO 9001 requirements.

Displays a large quantity of information (simultaneous display of SCI and SCE data etc.)

High-accuracy sensor Measures at 10nm intervals for the full wavelength range. Excellent repeatability

World's first portable spectrophotometer equipped with instantaneous UV adjustment function. UV evaluation time has been reduced revolutionarily due to the introduction of advanced Numerical UV Control.

Illuminated viewfinder

Light sources including and excluding UV component flash sequentially to provide sample data taken with UV-included energy as well as UV-excluded energy (UV400nm cutoff filter)

Measurement procedure can be downloaded to the CM-2600d from SpectraMagic. Since standard color difference for each part can be entered, human setting errors can be prevented.

Since the instrument has a built-in instantaneous Example of data taken with UV-excluded energy

Procedures are displayed in the form of messages, to eliminate in-process mistakes. Task function by CM-2600d and SpectraMagic.

Example of data taken after UV adjustment

UV adjustment function, data can be easily taken using the desired light source (e.g. D65, D50, C). UV calibration can be performed simply by measuring a standard with known fluorescent values under the desired light source. Once the UV calibration is completed, sample data can be taken by measuring UV included the sample under the desired light source. Since the conventional UV adjustment that requires the UV cutoff filter to be moved is not necessary, UV excluded measurement time can be reduced drastically. (Note on UV-Adjustment : Numerical UVFor textile, paper, fluorescent and consumerproducts calibration requires for the adjustment calculation SpectraMagic.)

Allows measurement in any position. Compact, lightweight with an easy-to-operate navigation wheel and large LCD display. The battery-powered small, compact body allows the instrument to be placed in any position at the sample surface. The large LCD reverse video display provides easy reading, irrespective of which hand it is held in. Using your finger, the navigation wheel allows simple and user-friendly operation. ( Turn) ( Push) For paints, plastics, automobiles, ceramics, architectural interiors, textile, paper, food etc.

Display example

Numerical Gloss Control

JOB1 MEAS.1 Measure the door of the car.

Numerical UV Control

d/8 integrating sphere optics that conform to industry standards

CM-2600 displays "Measure the car door".

CM-2600 displays "Measure the car seat".

Easy-to-carry, compact and lightweight

CM-2600 displays "Measure the inside of the car door".

670g (without batteries)

Measures the target with high accuracy. Easy-to-carry stylish body with an illuminated viewfinder. The instrument is portable and it allows measurements to be taken using two different areas of view (ø8mm and ø3mm). The user can choose the most suitable measurement area for the target. The lightweight, easy-to-carry body with the illuminated viewfinder enables the user to position the instrument on the target quickly and accurately.

The LCD specifications are subject to change without prior notice.

SAV ø3mm

By connecting the CM-2600d to the computer via SpectraMagic, data can be downloaded for color quality control analysis. MAV ø8mm Finder

<Main Specifications> Color space / L*a*b*, L*c*h, L*u*v*, Hunter Lab,FMC-2,CMC,CIE-94,XYZ,Yxy Color difference scales Color indices Metamerism, Whiteness/Whiteness Difference,Yellowness/ Yellowness Difference, Tint/Tint Difference, Brightness, opacity, Haze, Dominant Wavelength, g Excitation Purity, y Ganz WI, Ganz Tint Observer Conditions 2°,10° Illuminant Conditions A, C, D65, D50, D55, D75, F2, F6, F7, F8, F10, F11, F12, U50 Displays Spectral plot, Color plot, Tolerance plot, Statistical report, Real color, K/S, Multi-view displayy Tolerance Settings Elliptical, Box, Pass / Warn / Fail

For pharmaceuticals, cosmetics, printing, building materials, textiles etc.

Microsoftt®,Windows®,Windows®2000,Windows®98,Windows NT T® are trademarks of Microsoft Corporation in the USA.

Mac OS 9.2J illustrator 10J CM-2600d(E)_back.ai 2003.12.11

Specifications

System Diagram Standard Accessories

Target mask ø8mm CM-A146 AA-size battery (x4)

AC adapter AC-A17

Personal Computer (commercially available)

RS232C cable IF-A16

SpectraMagic CM-S9w

Zero calibration box CM-A32

Hard case

CM-A148

Dust cover set

CM-A149

Vinyl cover Dust cover

CM-A152

Dimensions (Units:mm) CM-2600d

96 193 * The specifications and drawings given here are subject to change without prior notice. CM-3700d CM-3600d

CM-2600d

CM-2600d

R&D

R&D Quality

Production R&D

Quality control

Production

In-house color control

SAFETY PRECAUTIONS To ensure correct use of the instrument, please adhere to the following. Before using the instrument, be sure to read the instruction manual. Always use the specified power. Use of inappropriate power may result in afire or electric shock.

CM-2600d

White calibration plate CM-A145

Color control network by spectrophotometer High inter-instrument agreement between the portable CM-2600d spectrophotometer and the desk top CM-3000 series make it easy to build a total color control network.

Target mask ø3mm CM-A147

Optional Accessories

69

Illumination/ d/8 (diffuse illumination, 8-degree viewing ), equipped with simultaneous observation system measurement of SCI (specular component included)/SCE (specular component excluded) Conforms to CIE No.15,ISO 7724/1,ASTM E1164, DIN 5033 Teil7 and JIS Z8722 Condition C standard. Sphere Size ø52mm Light-receiving element Silicon photodiode array (dual 40 elements) Spectral separation device Diffraction grating Wavelength range 360nm to 740nm Wavelength pitch 10nm Half bandwidth Approx. 10nm Reflectance range 0 to 175%, resolution: 0.01% Light source 3 pulsed xenon lamps Measurement time Approx. 1.5 seconds (approx. 2 seconds for fluorescent measurement) Minimum interval 3 seconds for SCI/SCE (4 seconds for fluorescent measurement) between measurements Battery perfomance Alkaline manganese:approx. 1000 measurements Measurement/ MAV: ø8mm/ø11mm illumination area SAV: ø3mm/6mm (Selectable between MAV and SAV) Repeatability Spectral Reflectance:Standard deviation within 0.1% (360 to 380nm within 0.2%) Colorimetric Value : Standard deviation within ∆E*ab 0.04(Measurement conditions:White calibration plate measured 30 times at 10-second intervals after white calibration was performed) Inter instrument within ∆E*ab 0.2 (MAV/SCI) based on 12BCRA Series II color tiles agreement compared to values measured with master body. UV adjustment Instantaneous numerical adjustment (no mechanical adjustment required) With UV400nm cut filter Measurement Single measurement/automatic averaging of multiple measurements mode (auto mode: 3, 5, 8 times/manual mode) Interface RS-232C standard Observer 2/10 degrees (CIE 1931/2°,CIE 1964/10°) Illuminant A, C, D50, D65, F2, F6, F7, F8, F10, F11, F12 (simultaneous evaluation is possible using two light sources) Display data Spectral value/graph, colorimetric value, color difference value/graph, PASS/FAIL result Color space/ L*a*b*, L*C*h, CMC (1:1), CMC (2:1), CIE94, Hunter Lab, Yxy, Munsell, XYZ, colorimetric data MI, WI (ASTM E313), YI (ASTM E313/ASTM D1925), ISO Brightness (ISO 2470), Density status A/T, L99C99h99, L99a99b99, WI/Tint (CIE/Ganz&Grisser) Data memory 700 (SCI/SCE as a set) Tolerance judgment Tolerance for color difference (both box and eliptical tolerances can be set) Power source 4 AA-size battery or AC adapter Size (WxHxD) 69 x 96 x 193mm Weight Approx. 670g (without batteries) Operating temperature/ 5 to 40˚C, relative humidity 80% or less (at 35˚C) with no condensation humidity range Storage temperature/ 0 to 45˚C, relative humidity 80% or less (at 35˚C) with no humidity range condensation Standard White calibration plate, Target mask ø8mm, Target mask ø3mm , accessories RS-232C cable, AC adapter, AA-size battery (x4) Optional Hard case, Dust cover set, Dust cover, SpectraMagic(software), Zero calibration box Accessories

CERTIFIED

Quality

Production

Company A

Company B

Color control among companies

The manufacturing center of Konica Minolta Sensing Inc. (Location: Aichi Pref., Japan) was approved by the British certification organization Lloyd’s Register Quality Assurance for certification under the ISO 9001: 1994 international quality management system standards on March 3, 1995. Since its establishment in 1990, the center has carried out the development and production of precision instruments and associated application software for the measurement of color, light, and shape. Certification was awarded to the center’s quality management system, including design, manufacturer, management of manufacture, calibration and servicing.Certification was carried over to the ISO 9001: 2000 standards in February, 2003.

3-91, Daisennishimachi, Sakai.Osaka 590-8551, Japan Konica Minolta Photo Imaging U.S.A., Inc. Konica Minolta Photo Imaging Canada, Inc. Konica Minolta Photo Imaging Europe GmbH Konica Minolta Photo Imaging France S.A.S. Konica Minolta Photo Imaging UK Ltd. Konica Minolta Photo Imaging Austria GmbH Konica Minolta Photo Imaging Benelux B.V. Konica Minolta Photo Imaging (Schweiz)AG Konica Minolta Business Solutions Italia S.p.A. Konica Minolta Photo Imaging Svenska AB Konica Minolta Photo Imaging (HK)Ltd. Shanghai Office Konica Minolta Photo Imaging Asia HQ Pte Ltd. KONICA MINOLTA SENSING, INC. Seoul Office

2001 KONICA MINOLTA SENSING, INC.

725 Darlington Avenue, Mahwah, NJ 07430, U.S.A. Phone: 888-473-2656 (in USA), 201-529-6060 (outside USA) FAX: 201-529-6070 1329 Meyerside Drive,Mississauga, Ontario L5T 1C9, Canada Phone: 905-670-7722 FAX: 905-795-8234 Europaallee 17, 30855 Langenhagen, Germany Phone: 0511-740440 FAX: 0511-741050 Paris Nord II, 385, rue de la Belle-Etoile, B.P. 50077, F-95948 Roissy C.D.G. Cedex, France Phone: 01-49386550 / 01-30866161 FAX: 01-48638069 / 01-30866280 Precedent Drive, Rooksley Park, Milton Keynes United Kingdom Phone: 01-908200400 FAX: 01-908618662 Amalienstrasse 59-61, 1131 Vienna, Austria Phone: 01-87882-430 FAX: 01-87882-431 Postbus 6000, 3600 HA Maarssen, The Netherlands Phone: 030-2470860 FAX: 030-2470861 Riedstrasse 6, 8953 Dietikon, Switzerland Phone: 01-7403727 FAX: 01-7422350 Via Stephenson 37, 20157, Milano, Italy Phone: 02-39011-1 FAX: 02-39011-219 Solnastrandvägen 3, P.O.Box 9058 S-17109, Solna, Sweden Phone: 08-627-7650 FAX: 08-627-7685 Room 1818, Sun Hung Kai Centre, 30 Harbour Road, Wanchai, Hong Kong Phone: 852-34137508 FAX: 852-34137509 Rm 1211, Ruijin Building No.205 Maoming Road (S) Shanghai 20020, China Phone: 021-64720496 FAX: 021-64720214 10, Teban Gardens Crescent, Singapore 608923 Phone: +65 6563-5533 FAX: +65 6560-9721 801, Chung-Jin Bldg., 475-22, BangBae-Dong, Seocho-ku, Seoul, Korea Phone: 02-523-9726 FAX: 02-523-9729

9242-4879-11 AEFDPK 5

Printed in Japan

Filenaam Word: Analysedatum: Golden Gate Single Reflection Diamond ATR. cm-1

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