BAB 5 KESIMPULAN DAN SARAN 5.1 Kesimpulan Dari hasil penelitian dapat disimpulkan bahwa: 1. Peningkatan jumlah lemak nabati yang disubtitusikan, menurunkan titik leleh coklat bar. 2. Penurunan titik leleh coklat bar dipengaruhi oleh sifat fisiko-kimia lemak campuran, polymorphism kristal lemak, dan adanya pembentukan fat blooming sebagai akibat dari ketidakhomogennya campuran lemak. 3. Model matematis yang digunakan untuk menggambarkan perubahan titik leleh coklat sebagai fungsi rasio substitusi adalah y = 6E-07x4 - 0,0001x3 + 0,0052x2 0,1325x + 33,421 pada substitusi lemak sawit dan y = 5E-08x5 - 1E-05x4 + 0,0009x3 - 0,0262x2 + 0,1926x + 33,383 pada substitusi lemak kelapa. 4. Coklat hasil substitusi terbaik dengan titik leleh tinggi adalah coklat bar dengan substitusi 20% lemak sawit dan coklat dengan substitusi 10% lemak kelapa. 5. Substitusi dalam jumlah yang tinggi akan menurunkan titik leleh dan memerlukan bantuan emulsifier untuk meningkatkan kestabilan dari coklat yang dihasilkan. 6. Coklat dengan substitusi lemak sawit dapat menghasilkan coklat dengan titik leleh yang lebih tinggi daripada coklat dengan substitusi lemak kelapa.
95
96
5.2 Saran Adapun saran yang dapat ditambahkan sebagai eksplorasi pada penelitian selanjutnya adalah: 1. Pengaruh ukuran partikel kristal gula terhadap pembentukan kristal pada coklat bar serta sifat amorphous crystal. 2. Pengaruh CBA lainnya terhadap pembuatan coklat bar. 3. Perubahan bentuk fasa kristal pada campuran lemak dan fat incompatibility pada titik eutektik dari campuran kedua lemak pada coklat substitusi. 4. Pengaruh pembentukan fat blooming dalam coklat 5. Pengaruh faktor fisik proses berupa, shear stress selama proses pengadukan, temperatur pendinginan, dan laju pendinginan selama proses kristalisasi. 6. Pengaruh kondisi lingkungan dan penyimpanan sampel terhadap titik leleh dan fasa kristal yang dihasilkan. 7. Pengaruh asam lemak laurat dalam perubahan tingkat kestabilan lemak baik dalam bentuk titik leleh, dan penyebab terjadinya fat incompatibility.
DAFTAR PUSTAKA A.M.Marina, Man, Y. C. & Amin, I., 2009. Virgin Coconut Oil: Emerging Functional Food Oil. Trends In Food Science and Technology, pp. 481-487. ADM, 2009. Chocovit Plus : Cocoa Butter Equivalents and Cocoa Butter Improvers, Hamburg: ADM Noblee. Afoakwa, E., 2010. Tempering, Lipid Crystallisation and Continuous Phase Character during Chocolate Manufacture. Dalam: Chocolate Science and Technology. Singapore: A John Wiley & Sons, Ltd., pp. 55-57. Afoakwa, E. O., 2010. Chocolate Science and Technology. Singapore: A John Wiley & Sons, Ltd., Publication. Afoakwa, E. O., Paterson, A., Fowler, M. & Vieira, J., 2008. Characterization of Melting Properties in Dark Chocolates from Varying Particle Size Distribution and Composition Using Differential Scanning Calorimetry. Food Research International, Volume 41, pp. 751-757. Almarinaket, 2014. Cocoa Butter Alternative. [Online] [Diakses 25 january 2016]. Anklam, M. L. &. E., 1998. Review of Cocoa Butter and Alternatives Fats for Use in Chocolate- Part A. Compositional Data. Volume 62. Anon., 2016. Simple Cooking Club. [Online] Available at: http://simplecookingclub.com/ Augusto, P. E., M.C.Soares, B., Chiu, M. C. & Goncalves, L. A., 2012. Modelling the effect of temperature on the lipid solid fat content (SFC). Food Research International, Volume 45, pp. 132-135. Badan Statistik Indonesia, 2014. Produksi Perkebunan Besar menurut Jenis Tanaman, Indonesia (Ton), 1995 - 2014, Indonesia: Badan Statistik Indonesia. Badan Statistik Indonesia, 2015. Produksi Biji Coklat di Indonesia. [Online] [Diakses 23 April 2016]. Beckett, S. T., 2004. Dalam: The Science of Chocolate. Cambridge: The Royal Society of Chemistry, pp. 47-48. Beckett, S. T., 2004. Dalam: The Science of Chocolate. Cambridge: The Royal Society of Chemistry, pp. 85-86.
97
98
Beckett, S. T., 2004. In: The Science of Chocolate. Cambridge: The Royal Society of Chemistry, pp. 167-168. Beckett, S. T., 2004. Dalam: The Science of Chocolate. Cambridge: The Royal Society of Chemistry, p. 109. Beckett, S. T., 2004. The Science of Chocolate. Cambridge: The Royal Society of Chemistry. Berg, T. O. & Bimberg, U., 1983. U¨ ber die Kinetik der Fettkristallisation. Fette Seifen Anstrichmittel, Volume 85, pp. 142-149. Berk, Z., 2009. Crystallization and Dissolution . Dalam: Food Process Engineering and Technology. New York: Elsevier Inc., pp. 320-324. Bockisch, M., 1998. Fats and Oils Handbook. Hamburg: AOCS Press Champaign. Bradbury, S., 2012. CX31-P Polarized Light Microscope Configuration, s.l.: OLYMPUS: Mi. CacaoWeb.net, 2014. Nutrition Facts for Cocoa and Chocolate. Cargill, 2011. Tempering Chocolate: Basic Tempering Principles. Cocoa and Chocolate, 2 11, pp. 1-2. Chocolate Alchemy, 2016. Tempering-Deconstruction and Reconstruction and Illustrated Tempering. [Online] Available at: http://chocolatealchemy.com/illustrated-tempering/ [Diakses 20 Oktober 2016]. Clercq, N. D., 2013. Crystallization of Fat and Oils, Gent: Universiteit Gent. Dayrit, F. M., 2014. Lauric Acid is Medium-Chan Fatty Acid, Coconut oil is a Medium-Chain Triglyceride. Phillipine Journal of Science, 143(2), pp. 157166. Delbaere, C., 2013. Production of Chocolate : Mixing, Refining, and Conching, Gent: Universiteit Gent. Depoortere, L., 2011. The Use and Capability of CBEs in Chocolate Products, Gent: Universiteit Gent. Ehlers, D., 2012. Controlled Crystallization of Complex Confectionary Fats, Zurich,Switzerland: Laboratory of Food Process Engineering. F. H. Messerli, M., 2012. Chocolate Consumption, Cognitive Function, and Nobel Laureates. the New England Journal of Medicine, pp. 1-3.
99
Federation of Malaysia, 2007. Malaysian Standard: Palm Stearin-Specification. Selangor, Department of Standards Malaysia. Food Safety and Standards Authority of India, 2012. Manual of Methods of Analysis of Foods: Oils and Fats, New Delhi: Ministry of Health and Family Welfare. Food Standart Agency, 2009. Guidance on the Cocoa and Chocolate Product Regulation 2003, United Kingdom: Food Standart Agency. Foubert, I., Dewettinck, K. & Vanrolleghem, P. A., 2003. Modelling of Crystallization Kinetics of Fats. Trends in Food Science & Technology , Volume 14, pp. 79-92. Foubert, I. I. & Leenheer, P. d. A. D., 2003. Modelling Isothermal Cocoa Butter Crystallization: Influence of Temperature and Chemical Composition, Gent: Universiteit Gent. Group, Nature Publishing, 2003. Plasma Antioxidant from Chocolate. [Online]. Hanselmann, W., 2013. Chocolate Products Containing Amorphous Solids and Methods of Producing Same. United States, Paten No. US 8617635 B2. Hartel, R., 2011. Crystallization. Food Engineering, Volume III. HB Ingredient, 2014. www.bean-to-bar.co.uk. [Online] [Diakses 24 February 2016]. Karleskind, A., 1992. Manuel Des Corps Gras. Paris : s.n. Kelishadi, R., 2005. Cacao to Cocoa to Chocolate: Healthy Food. ARYA Journal , Volume 1, pp. 29-35. Kumar, B. N. &. V., 2014. Cocoa Butter and Its Alternatives: A Review. Volume 1. Lipp, M. & Anklam, E., 1997. Review of Cocoa Butter and Alternative Fats for Use in Chocolate- Part A. Compositional Data. Food Chemistry. Loisel, C. et al., 1998. Phase Transition and Polymorphism of Cocoa Butter. JAOCS, 75(4), pp. 425-439. Loisel, C. et al., 1998. Phase Transition and Polymorphism of Cocoa Butter. AOCS Press, Volume 75, pp. 425-439. Ludescher, R. D., 2010. Science of Candy, New Jersey: Departement of Food Science Rutgers University. Malssen, K. V., Langevelde, K., Peschar, R. & Schenk, H. &., 1999. Phase Behaviour and Extended Phase Scheme of Static Cocoa Butter Investigated with Real-time
100
X-Ray Powder Diffraction. Journal of The American Oil Chemistry Society, 76(6), pp. 669-676. Marangoni, A. G. & Ghazani, S. M., 2012. Trends in Interesterification of Fats and Oil, North America: ILSI. MONARCH, 2006. MONARCH Catalyst for Growth , s.l.: MONARCH. Montgomery, D. C., 2005. Design and Analysis of Experiment. United State of America: John Wiley & Sons. Montgomery, D. C., 2009. Regression Modelling. Dalam: Design and Analysis of Experiments. Tempe, Arizona: John Wiley & Sons, Inc., pp. 388-403. Naessens, L., 2012. Production of Cocoa Butter Equivalent through Enzymatic Acidolysis, Ghent: UNIVERSITEIT GENT. Owen, G., 2013. How Chocolate is Made. [Online] [Diakses 2 April 2016]. Padar, S., Jeelani, S. & Windhab, E., 2008. Crystallization Kinetics of Cocoa Fat Systems: Experiment and Modelling. J Am Oil Chem Soc, Volume 85, pp. 1115-1126. Pasaribu, N., 2004. Minyak Buah Kelapa Sawit, Medan: Universitas Sumatera Utara. Perkin Elmer Inc., 2013. Differential Scanning Calorimetry (DSC), Waltham: Perkin Elmer Inc.. Radosavljevic, S. & Schlunk, A., 2000. Melting Chocolate. Commerical and in Confidence, pp. 1-15. Ramayana, 2003. Pembuatan Lemak Margarin dari Minyak Kelapa, Minyak Kelapa Sawit, dan Stearin Kelapa Sawit Melalui Proses Inesterifikasi dan Blending Berkecepatan Tinggi pada Suhu Kamar, Medan: Universitas Sumatera Utara. Ramayana, 2003. Pembuatan Lemak Margarin dari Minyak Kelapa, Minyak Kelapa Sawit, dan Stearin Kelapa Sawit Melalui Proses Interesterifikasi dan Blending Berkecepatan Tinggi pada Suhu Kamar, Medan: Universitas Sumatera Utara. Reichert, B. W., 2007. Pulsed Nuclear Magnetic Resonance, Wisconsin: University of Wisconsin. Reverend, B., 2009. Modelling Phase Change Kinetics of Cocoa Butter in Chocolate in Application to Confectionery Manufacturing, Birmingham: University of Birmingham.
101
Rucker, R., 2009. Nutritional Properties of Cocoa. Dalam: G. a. Shapiro, penyunt. Chocolate: History, Culture, and Heritage. s.l.:John Wiley & Sons, Inc., pp. 944-946. S. Padar, S. J. E. W., 2008. Crystallization Kinetics of Cocoa Fat Systems: Experiment and Modelling. Shan, L., Meng, Z., Jin, Q. & Wang, X., 2010. Effect of Fat Composition on Texture and Bloom of Lauric Compound Chocolate. European Journal of Lipid Science and Technology, Volume 112, pp. 1270-1276. Siew, W. L. & MPOB, J. M., 2007. Palm Oil and Fractions. [Online] Available at: http://www.soci.org/~/media/Files/Conference%20Downloads/2007/SCI%20Ca iro%20Conference%20Mar%2007/SiewWaiLin.ashx Silaban, R., Manullang, R. S. & Hutapea, V., 2014. Pembuatan Virgin Coconut Oil (VCO) Melalui Kombinasi Teknik Fermentasi dan Enzimatis Menggunakan Ekstrak Nenas, Medan: Universitas Negeri Medan. Smith, K., 2008. Chocolate Tempering. Brussels, Confectionery Manufacturing Expo. The Chocolat Bar, 2016. Chocolate Tempering. [Online] Available at: https://www.thechocolatbar.com/chocolate-tempering [Diakses 20 Oktober 2016]. The Guardian, 2011. Hope and Greenwood: How and why to temper chocolate. [Online] Available at: https://www.theguardian.com/lifeandstyle/2011/apr/15/how-whytemper-chocolate [Diakses 22 Oktober 2016]. Timms, R., 2003. Confectionery Fats Handbook: Properties, Production, and Application. Bridgwater: The Oily Press. Tisoncik, M., 2013. Chocolate Fat Bloom, Chicago: The Manufacturing Confectioner.