podniku

Vytisknuto: 31.08.2011 Zpracováno: 24.08.2011 podle Nařízení (ES) č. 1907/2006 a Nařízení (EU) č. 453/2010 (REACH) Založeno: 11.03.2008

BEZPEČNOSTNÍ LIST EU Nafta Číslo materiálu N001

Verze 6 / Strana 1 z 14

ODDÍL 1: Identifikace látky/směsi a společnosti/podniku 1.1 Identifikátor výrobku Obchodní název: Nafta Registrační číslo REACH:

01-2119475133-43-XXXX č. č. č. č. č.

37 38 39 41 42

-

Lehký benzín LSR (RB) Lehký benzín (BK) Nafta (RB) Virgin Nafta (RB) Virgin Nafta (BK)

1.2 Příslušná určená použití látky nebo směsi a nedoporučená použití Obecné použití

Vsázkový materiál pro petrochemii

Identifikované použití

1. Výroba látek 1a. Rozdělení látek 1b. Použití jako meziprodukt 2. Příprava a (pře)balení látek a sloučenin 3a. Použítí při potahování 4a. Použití v čisticích prostředcích 12a. Použití jako palivo: Průmysl 12b. Použití jako palivo: Průmysl 12c. Použití jako palivo: Spotřebitel 13. Produkce a zpracování gumy: Průmysl

1.3 Podrobné údaje o dodavateli bezpečnostního listu Název firmy: Ulice/poštovní číslo: Země, PSČ, obec: Telefon: Telefax:

Eni Deutschland GmbH Sonnenstr. 23 D-80331 Muenchen +49 (0)89-59 07-0 +49 (0)89-59 63-03

Odbor poskytující informace:

Herr Hückinghaus, Telefon: +49 (0)89-59 07-344, Email: [email protected]

1.4 Telefonní číslo pro naléhavé situace Beratungsstelle für Vergiftungserscheinungen (GIZ) Telefon: +49 (0)228-19240

vytištěný z Eni Deutschland

... s Qualisys SUMDAT




ODDÍL 2: Identifikace nebezpečnosti 2.1 Klasifikace látky nebo směsi Klasifikace podle předpisu ES 1272/2008 (CLP): STOT SE 3; H336 Může způsobit ospalost nebo závratě. Repr. 2; H361 Může podle doměnek způsobit omezení plodnosti nebo poškodit dítě v mateřském lůně. Aquatic Chronic 2; H411 Toxický pro vodní organismy, s dlouhodobými účinky. Asp. Tox. 1; H304 Při požití a vniknutí do dýchacích cest může způsobit smrt. Skin Irrit. 2; H315 Dráždí kůži. Flam. Liq. 2; H225 Vysoce hořlavá kapalina a páry. Carc. 1B; H350 Může vyvolat rakovinu. Muta. 1B; H340 Může vyvolat genetické poškození. Klasifikace podle směrnice 67/548/EHS: Carc. Cat. 2; R45 Může vyvolat rakovinu. Muta. Cat. 2; R46 Může vyvolat poškození dědičných vlastností. F; R11 Vysoce hořlavý. Xn; R65 Zdraví škodlivý: při požití může vyvolat poškození plic. Xi; R38 Dráždí kůži. R67 Vdechování par může způsobit ospalost a závratě. N; R51-53 Toxický pro vodní organismy, může vyvolat dlouhodobé nepříznivé účinky ve vodním prostředí.

2.2 Prvky označení Značení (CLP)

Signální slovo Standardní věty

Nebezpečí H225 H304 H315 H336 H340 H350 H361 H411

Bezpečnostní pokyny

P201 P210 P280

Vysoce hořlavá kapalina a páry. Při požití a vniknutí do dýchacích cest může způsobit smrt. Dráždí kůži. Může způsobit ospalost nebo závratě. Může vyvolat genetické poškození. Může vyvolat rakovinu. Může podle doměnek způsobit omezení plodnosti nebo poškodit dítě v mateřském lůně. Toxický pro vodní organismy, s dlouhodobými účinky. Před použitím si obstarejte speciální instrukce. Chraňte před teplem/jiskrami/otevřeným plamenem/horkými povrchy. - Zákaz kouření. Používejte ochranné rukavice/ochranný oděv/ochranné brýle/obličejový štít.

P301+P310

PŘI POŽITÍ: Okamžitě volejte TOXIKOLOGICKÉ INFORMAČNÍ STŘEDISKO nebo lékaře.

P403+P233

Skladujte na dobře větraném místě. Uchovávejte obal těsně uzavřený.

P501

Odstraňte obsah/obal ve sbirném místi pro zvláštní nebo nebezpeené odpady.






Značení (67/548/EHS nebo 1999/45/ES) F T

vysoce hořlavý R-věty:

R 45 R 46 R 11 R 38 R 51/53 R 65 R 67

S-věty:

S 53 S2 S 23 S 24 S 29 S 36/37 S 43 S 45 S 51 S 61 S 62

N

nebezpečný pro životní prostředí

Může vyvolat rakovinu. Může vyvolat poškození dědičných vlastností. Vysoce hořlavý. Dráždí kůži. Toxický pro vodní organismy, může vyvolat dlouhodobé nepříznivé účinky ve vodním prostředí. Zdraví škodlivý: při požití může vyvolat poškození plic. Vdechování par může způsobit ospalost a závratě. Zamezte expozici - před použitím si obstarejte speciální instrukce. Uchovávejte mimo dosah dětí. Nevdechujte páry. Zamezte styku s kůží. Nevylévejte do kanalizace. Používejte vhodný ochranný oděv a ochranné rukavice. V případě požáru použijte Pěna, suché hasivo, proud vody nebo použít oxid uhličitý. V případě nehody, nebo necítíte-li se dobře, okamžitě vyhledejte lékařskou pomoc. Používejte pouze v dobře větraných prostorách. Zabraňte uvolnění do životního prostředí. Viz speciální pokyny nebo bezpečnostní listy. Při požití nevyvolávejte zvracení: okamžitě vyhledejte lékařskou pomoc a ukažte tento obal nebo označení.

2.3 Další nebezpečnost Páry jsou těžší než vzduch, šíří se při zemi. I při nízkých teplotách okolního prostředí mohou vznikat výbušné směsi par/vzduchu.

ODDÍL 3: Složení/ informace o složkách 3.1 Látky Chemická charakteristika (látka):

nafta, s nízkým bodem varu UVCB látka - Informace o složkách:

Obsažená látka EINECS 265-065-1 CAS 64741-63-5

REACH 01-2119474679-18-xxxx EINECS 265-042-6 CAS 64741-42-0


Označení Benzinova frakce (ropna), lehka katalyticky reformovana Benzinova frakce (ropna), primarni siroka frakce

Obsah 0-100 %

0-100 %

Značení EU: Carc. Cat. 2; R45. Muta. Cat. 2; R46. Xn; R65. CLP: Muta. 1B; H340. Carc. 1B; H350. Asp. Tox. 1; H304. EU: Carc. Cat. 2; R45. Muta. Cat. 2; R46. Xn; R65. CLP: Muta. 1B; H340. Carc. 1B; H350. Asp. Tox. 1; H304. ... s Qualisys SUMDAT




Obsažená látka EINECS 265-151-9 CAS 64742-49-0

Označení Nafta (petrolej), mírně upravená vodíkem

Obsah 0-100 %

EINECS 265-046-8 CAS 64741-46-4

Benzinova frakce (ropna), lehka primarni

0-100 %

EINECS 265-041-0 CAS 64741-41-9

Benzinova frakce (ropna), tezka primarni

0-100 %

EINECS 270-690-8 CAS 68476-50-6

Uhlovodiky, C >=5, bohate na C5-6

0-100 %

REACH 01-2119447106-44-xxxx EINECS 200-753-7 CAS 71-43-2

Benzen

>= 0,1 %

Dodatečná upozornění:

Značení EU: Carc. Cat. 2; R45. Muta. Cat. 2; R46. Xn; R65. CLP: Muta. 1B; H340. Carc. 1B; H350. Asp. Tox. 1; H304. EU: Carc. Cat. 2; R45. Muta. Cat. 2; R46. Xn; R65. CLP: Muta. 1B; H340. Carc. 1B; H350. Asp. Tox. 1; H304. EU: Carc. Cat. 2; R45. Muta. Cat. 2; R46. Xn; R65. CLP: Muta. 1B; H340. Carc. 1B; H350. Asp. Tox. 1; H304. EU: Carc. Cat. 2; R45. Muta. Cat. 2; R46. Xn; R65. CLP: Muta. 1B; H340. Carc. 1B; H350. Asp. Tox. 1; H304. EU: Carc. Cat. 1; R45. F; R11. Muta. Cat. 2; R46. Xn; R65. T; R48/23/24/25. Xi; R36/38. CLP: Asp. Tox. 1; H304. Carc. 1A; H350. Eye Irrit. 2; H319. Flam. Liq. 2; H225. Muta. 1B; H340. STOT RE 1; H372. Skin Irrit. 2; H315.

Může podle doměnek způsobit omezení plodnosti nebo poškodit dítě v mateřském lůně. test CAS 64741-63-5 - Chemiebenzin: Směs uhlovodíků, C5-C11, Rozmezí varu 35°C do 190°C CAS 64741-42-0 - Full Range Naphtha: Směs uhlovodíků, C4-C11, Rozmezí varu-20°C do 220°C CAS 64742-49-0 - Light Distillate Feedstock: Směs uhlovodíků, C4-C11, Rozmezí varu-20°C do 190°C CAS 64741-46-4-5 - Light Virgin Naphtha: Směs uhlovodíků, C4-C10, Rozmezí varu-20°C do 180°C CAS 64741-41-9 - Mittelbenzin: Směs uhlovodíků, C6-C12, Rozmezí varu 65°C do 230°C CAS 68476-50-6 - Leichtbenzin: Směs uhlovodíků, >= C5






ODDÍL 4: Pokyny pro první pomoc 4.1 Popis první pomoci Všeobecné pokyny:

Vdechování:

Při styku s pokožkou:

Při styku s očima:

Po polknutí:

První pokyn : Dbát vlastní ochrany Inhalace větších množství způsobí: Porucha koordinace, opojení, bolest hlavy, nutkání ke zvracení. Při delší expozici: závrať, bezvědomí a zástava dechu možný. Postižené přivést na čerstvý vzduch. Při dýchacích obtížích zabezpečit přísun kyslíku. při nepravidelném dýchání nebo při zástavě dechu poskytněte umělé dýchání. Okamžitě přivolejte lékaře. Při nebezpečí ztráty vědomí uložit a transportovat ve stabilizované poloze. Okamžitě odložte veškeré kontaminované oblečení. Při styku s pokožkou okamžitě opláchnout proudem vody a mýdlem. Při podráždění pokožky vyhledat lékaře. Při otevřených víčkách vyplachovat 10-15 minut tekoucí vodou. Potom se poradit s očním lékařem. Nevyvolávat zvracení. Při spolknutí resp. zvracení nebezpečí vniknutí do plic. V případě zvracení a při bezvědomí uvést do stabilizované polohy. Udržovat volný průchod dýchácích cest. Okamžitě přivolejte lékaře.

4.2 Nejdůležitější akutní a opožděné symptomy a účinky Vdechování: Bolest hlavy, stav opojení, nevolnost, otupělost, závrať, dýchací potíže. Při vyšších koncentracích se vyskytuje: Poruchy CNS, bezvědomí, narkóza, zástava dechu. Po polknutí: žaludeční-střevní-poruchy, průjem.

4.3 Pokyn týkající se okamžité lékařské pomoci a zvláštního ošetření Můžou nastat následující symptomy: Bolest hlavy, stav opojení, nevolnost, nutkání ke zvracení, otupělost, závrať, dýchací potíže, bezvědomí, zástava dechu. Při polknutí s následným dávením může dojít k vdechnutí do plic, což může vést k chemické pneumonii nebo k zadušení. Ošetření: Případné kyslíkové umělé dýchání. Při podráždění plic nejdříve ošetřete sprejem Dexamethason.

ODDÍL 5: Opatření pro hašení požáru 5.1 Hasiva Vhodné hasicí prostředky:

Pěna, suché hasivo (ABC-prášek), proud vody, oxid uhličitý. Z bezpečnostních důvodů nevhodné hasicí prostředky:

Silný vodní proud

5.2 Zvláštní nebezpečnost vyplývající z látky nebo směsi Vysoce hořlavý. Mohou vznikat výbušné směsi par/vzduchu. Pozor na zpětný zápal. V případě požáru mohou vznikat: Oxidy dusíku (NOx), oxidy síry, oxid uhelnatý a oxid uhličitý.






5.3 Pokyny pro hasiče Zvláštní ochranné vybavení při hašení požáru:


Použijte autonomní dýchací přístroj a protichemický ochranný oděv. Ohrožené nádoby ochlazovat vodním proudem. V případě požáru nebo výbuchu nevdechujte dýmy. Kontaminovanou vodu na hašení sbírejte odděleně. Zamezit vniknutí hasící vody do povrchové a podzemní vody.

ODDÍL 6: Opatření v případě náhodného úniku 6.1 Opatrení na ochranu osob, ochranné prostredky a nouzové postupy Zamezit kontaktu s látkou. Nosit vhodný ochranný oděv. Přiveďte osoby do bezpečí. Nechráněné osoby musí zůstat v dostatečné vzdálenosti. Zajistěte dostatečné větrání. Nevdechujte páry.

6.2 Opatření na ochranu životního prostředí Zamezte plošné expanzi (např. zahrazením nebo zablokováním). Zabránit vniknutí do půdy, vody a kanalizace. Nebezpečí exploze! Při uvolnění informovat úřady.

6.3 Metody a materiál pro omezení úniku a pro čištění


Odstraňte z povchu vody (např. odčerpáním, odsátím). Odklízet nehořlavým, kapaliny sajícím materiálem (např. písek/ zemina/křemelina/Vermiculit) a podle předpisu likvidovat. Nevymývat vodou nebo vodou zředěnou čisticími prostředky. Odstraňte všechny zdroje vznícení. Pozor na zpětný zápal. Použijte jiskrově bezpečné nářadí. Zvláštní nebezpečí uklouznutí na rozsypaném/vylitém produktu.

6.4 Odkaz na jiné oddíly nepotřebný

ODDÍL 7: Zacházení a skladování 7.1 Opatření pro bezpečné zacházení Pokyny k bezpečnému zacházení

Dbát na dobré větrání a vyvětrání skladu a pracoviště. Při manipulaci zabránit vystříknutí a rozlití. Zamezit tvorbě aerosolu a mlhy. Nevdechujte páry. Nejezte, nepijte a nekuřte při používání. Nikdy nepoužívejte k čistícím účelům. Pokyny k ochraně před požárem a explozí:

Uchovávejte mimo dosah zdrojů zapálení - Zákaz kouření. Proveďte preventivní opatření proti výbojům statické elektřiny. Pamatujte na uzemnění nádrže, aparatur, čerpadel a odsávacích zařízení. Používejte jen antistaticky vybavené (nejiskřící) nářadí. Je potřebné použít antistatický pracovní oděv.






7.2 Podmínky pro bezpečné skladování látek a směsí včetně neslučitelných látek a směsí Požadavky na skladovací prostory a nádoby:

Uchovávejte obal těsně uzavřený , na dobře větraném místě. Dodržujte dostatečnou vzdálenost od zápalných a tepelných zdrojů. Vhodný materiál: ocel, Povolené rezervní kanystry Přístup do skladu povolen pouze odborníkům. Pokyny pro společné skladování

Třída skladování VCI:

Neskladovat společně s látkami podporujícími hoření, se samovznětlivými látkami a se snadno vznětlivými pevnými látkami. 3 = Zápalné kapalné látky

7.3 Specifické konečné / specifická konečná použití Vsázkový materiál pro petrochemii

ODDÍL 8: Omezování expozice/osobní ochranné prostředky 8.1 Kontrolní parametry CAS-číslo 71-43-2

Označení Druh Benzen Česká republika: PEL Česká republika: NPK-L Evropa, BOELV: TWA

Hraniční hodnota D, P 3 mg/m3; 0,939 ppm D, P 10 mg/m3; 3,13 ppm Pokožka 3,25 mg/m3; 1 ppm


hraniční hodnota motorový benzín (Analogický závěr): 250 mg/m3 (Mezní hodnota pro motorová paliva podle DIN EN 228 je mezní hodnota součtu všech uhlovodíků včetně benzolu a všech složek obsahujících kyslík.)

DNEL

DNEL Krátkodobý, pracovník, inhalativní: 1300 mg/m3 / 15 (4320 mg/m3/h) DNEL Krátkodobý, pracovník, inhalativní: 1110 mg/m3 / 15 (2400 mg/m3/h) DNEL Dlouhodobý, pracovník, inhalativní: 840 mg/m3 / 8h (10000 mg/m3/6 h) DNEL Krátkodobý, spotřebitel, inhalativní: 1200 mg/m3 / 15 (4320 mg/m3/h) DNEL Krátkodobý, spotřebitel, inhalativní: 640 mg/m3 / 15 (2400 mg/m3/h) DNEL Dlouhodobý, spotřebitel, inhalativní: 180 mg/m3 / 8h (10000 mg/m3/6 h)

8.2 Omezování expozice Zajistit dobré větrání místnosti, odsávání/vyvětrání. Nouzová sprcha a prostředky na výplach očí by měly být v pracovním prostoru snadno přístupné. Látka by měla být zpracovávána jen v uzavřeném zařízení nebo systému. Omezování expozice pracovníků Ochrana dýchacích orgánů:

Při vyšších koncentracích se vyskytuje: Ochranný dýchací přístroj s filtr A (charakteristické zbarvení hnědý) podle EN 141. (Páry do 0,1 Vol.-%: A1, do 0,5 Vol.-% A2, do 1 Vol.-% A3.) Při nejasných podmínkách a koncentracích kyslíků nižších než 17 % použijte autonomní dýchací přístroj. Kontrola vdechovaného vzduchu: Indikační trubice Auer Benzin A, BNZ, Gasolin 30, QL. vytištěný z Eni Deutschland



BEZPEČNOSTNÍ LIST EU Nafta Číslo materiálu N001 Ochrana rukou:

Ochrana očí:

Ochrana těla:


Nepropustné ochranné rukavice podle EN 374. Materiál rukavic: Nitrilkaučuku. Nevhodný materiál: Kůže, tkanina. rezistenčni doba: > 480 min. Dbejte informací od výrobce ochranných rukavic týkající se propustnosti a rezistenční doby rukavic. Těsně přiléhavé ochranné brýle podle EN 166. Při zvýšeném ohrožení dodatečně Ochranný obličejový štít Antistatický ochranný oděv/ochranné holínky.

Ochranná a hygienická opatření:

Na pracovišti nejíst, nepít, nekouřit, nešňupat. Okamžitě odložte veškeré kontaminované oblečení. Hadry na čištění napuštěné produktem nebrat s sebou do kapes u kalhot. Po práci kůži důkladně čistit a ošetřit.

ODDÍL 9: Fyzikální a chemické vlastnosti 9.1 Informace o základních fyzikálních a chemických vlastnostech kapalný bezbarvý do žlutý charakteristický

Skupenství: Barva Zápach:

Rozdělovací koeficient n-oktanol/voda:

51 - 186 °C (DIN EN ISO3405) <= -60 °C (Eaton 1990) <0 do <55 stupňě Celsia (EN ISO 13736) cca 200 °C 280 - 470 °C (Eaton 1990) LEL (dolní mez výbušnosti): 0,60 Vol % HHE (horní hranice exploze): 9,50 Vol % u 38 °C: CONCAWE (2010) 40-2400 hPa (EN 13016-1) u 15 °C: 0,7434 g/mL (ISO 3675/EN ISO 12185) u 20 °C: nepatrný >= 3 log P(o/w)

Viskozita, kinematický:

u 20 °C: cca 0,68 mm2/s

Bod varu / rozmezí bodu varu Bod tání / rozmezí bodu tání Bod vzplanutí / dosah plamenu: Teplota vznícení Samovznětlivost: Explozní meze:

Tlak páry: Hustota: Rozpustnost ve vodě:

9.2 Další informace Obsah síra (DIN 51400 T.6): max. 1500 mg/kg

ODDÍL 10: Stálost a reaktivita 10.1 Reaktivita Vysoce hořlavá kapalina a páry.

10.2 Chemická stabilita Produkt je za normálních skladovacích podmínek stabilní.

10.3 Možnost nebezpečných reakcí Žádná příkazová data






10.4 Podmínky, kterým je třeba zabránit Vysoce hořlavý. Zamezit otevřenému světlu, ohni a jiným zdrojem hoření. Při silném zahřívání: Nebezpečí požáru/Nebezpečí samovznícení. Mohou vznikat výbušné směsi par/vzduchu. Páry jsou těžší než vzduch, šíří se při zemi.

10.5 Neslučitelné materiály oxidační činidla

10.6 Nebezpečné produkty rozkladu V případě požáru mohou vznikat: Oxidy dusíku (NOx), oxidy síry, oxid uhelnatý a oxid uhličitý.

ODDÍL 11: Toxikologické informace 11.1 Informace o toxikologických úeincích Akutní toxicita:

LD50 Krysa, orální: > 5000 mg/[m3] (OECD TG 401) LC50 Krysa, inhalativní: > 5,61 mg/L (OECD TG 403) LD50 Králík, kožní: > 2000 mg/kg (OECD TG 402) NOAEL Krysa, kožní: 3750 mg/kg/28d (OECD TG 410) NOAEL Krysa, inhalativní: 9840 mg/m3 (OECD TG 412) Vdechování: Vdechování par může způsobit ospalost a závratě. Po polknutí: Zdraví škodlivý: při požití může vyvolat poškození plic. Při styku s pokožkou: Dráždivý. Při dlouhodobé expozici nebezpečí vážného poškození zdraví. Odmašťuje pokožku. Při styku s očima: Při delší a/nebo častější expozici nelze vyloučit podráždění očí. rakovinotvorné účinky, účinky měnící dědičnost jakož i ohrožující rozmnožování

Repr. 2 - Může podle doměnek způsobit omezení plodnosti nebo poškodit dítě v mateřském lůně. Carc. 1B - Může vyvolat rakovinu. Muta. 1B - Může vyvolat genetické poškození. Symptomy Vdechování: Bolest hlavy, stav opojení, nevolnost, otupělost, závrať, dýchací potíže. Při vyšších koncentracích se vyskytuje: Poruchy CNS, bezvědomí, narkóza, zástava dechu. Po polknutí: žaludeční-střevní-poruchy, průjem.



Vytisknuto: Zpracováno: podle Nařízení (ES) č. 1907/2006 a Nařízení (EU) č. 453/2010 (REACH) Založeno:

BEZPEČNOSTNÍ LIST EU

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Nafta Číslo materiálu N001


Všeobecné poznámky Požití nebo vdechnutí způsobuje u krys nefrotoxické změny. Toxický účinek na krvetvorné orgány. Výrobek obsahuje benzol, který způsobuje leukémii. Mutagenita: nemutagenní v bakteriální mutagenitě, in-vitro (OECD TG 471 ) Genová mutace buněk savců, in-vitro (OECD TG 476): negativní Zkouška mikrojádra in-vivo, Krysa (OECD TG 474): negativní Chromozomální odchylka, in-vivo, Krysa (OECD 475): negativní Karcinogenita: Chronický (dlouhodobý), kožní použití Myš, NOEL: 0,5 ml (blended gasoline): no significantly changes compared to negative and historical controls Chronická inhalační toxicita, Krysa, NOEL: 292 ppm. V pokusu s hlodavci při vysoké chronické inhalační expozici byl pozorován rest tumore na játrech. Význam tychto výsledků pro člověka nebyly objasněny. Toxicita pro reprodukci: NOAEL >24700 mg/m3 (OECD TG 421). Žádné poškození schopnosti rozmnožování při testu na zvířatech. Neurotoxicity: Exposure to high level can produce deprese centrálního nervového systému in humans or in experimental animals. imunotoxicitu: Gasoline exposure does not affect the immune system in experimental animals u Koncentrace > 20000 mg/m3.





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ODDÍL 12: Ekologické informace 12.1 Toxicita Vodní toxicita:

Toxický pro vodní organismy, může vyvolat dlouhodobé nepříznivé účinky ve vodním prostředí. Akutní účinky: Algenová toxicita: sladkovodní vzorky: 72h EL50 pseudokirchneriella subcapitata (zelená řasa): 3,1 mg/L (OEDC 201, based on: stupeň růstu) (pramen: CONCAWE 1995o) sladkovodní vzorky: 72h NOELR pseudokirchneriella subcapitata (zelená řasa): 0,5 mg/L (OEDC 201, based on: stupeň růstu) (pramen: CONCAWE 1996a) Toxicita ryb: sladkovodní vzorky: 96h LC50 (Oncorhynchus mykiss (pstruh duhový)): 10 mg/L (OEDC 203) (pramen: CONCAWE 1995a, 1996a,b) sladkovodní vzorky: 96h LC50 (omezená štěrbina): 8,2 mg/L (EPA 66013-75-009) (pramen: PPSC 1995a) Toxicita bezobratlých druhů: sladkovodní vzorky: 48h EC50 (Daphnia magna (velká vodní blecha)): 4,5 mg/L (OEDC 202, based on: Mobilita) (pramen: CONCAWE 1995h, 1996j,k) Bakteriální toxicita:: sladkovodní vzorky Tetrahymena pyriformis: 72h LL50 15,41 mg/L (Metoda: QSAR PETROTOX) (pramen: Redman et al. 2010b) Dlouhodobé efekty: sladkovodní vzorky: Daphnia magna (velká vodní blecha): 21d NOEL: 2,6 mg/L (OEDC 211, based on: reprodukce) (pramen: Springborn Laboratories Inc. 1999d)

Třída ohrožení vody:

3 = silně ohrožující vody

12.2. Perzistence a rozložitelnost Jiná upozornění:

Inherentně biologicky odbouratelný (Solano-Serena, F. et al (1999)). Hydrolýza není očekávatelná. (Neely, W.B., Blau, G.E. (1985))

12.3 Bioakumulační potenciál Rozdělovací koeficient n-oktanol/voda:

>= 3 log P(o/w)

12.4 Mobilita v půdě Rozdělení do životního prostředí po model výpočtu (PETRORISK): vzduch: 93,02 % voda: 5,83 % zemina: 0,34 % sediment: 0,81 % (pramen: Redman et al., 2010a)

12.5 Výsledky posouzení PBT a vPvB Tato látka nesplňuje PBT-/vPvB kriteria REACH nařízení,dodatku XIII.

12.6 Jiné nepříznivé účinky Obecné pokyny:

Nesmí se dostat do podzemní vody, do vodních toků a do kanalizace.





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ODDÍL 13: Pokyny pro odstraňování 13.1 Metody nakládání s odpady Produkt Klíč třídy odpadu

Doporučení:

13 07 02* = Odpady z tekutých paliv: Benzin * = povinný důkazem Odevzdat schválené likvidační firmě. Možné alternativy: Spalování podle platných místních, krajských a národních předpisů.

další údaje Přeprava cisternou. Opatrně a úplně vyprázdnit. Pozor na prázdné nádoby. Při vznícení možnost výbuchu. Vyvarovat se zásahu do životního prostředí.

ODDÍL 14: Informace pro přepravu 14.1 Číslo OSN ADR/RID, IMDG, IATA:

1268

14.2 Příslušný název OSN pro zásilku ADR/RID: IMDG, IATA:

DESTILÁTY ROPNÉ, J.N. PETROLEUM DISTILLATES, N.O.S.

14.3 Třída/třídy nebezpečnosti pro přepravu ADR/RID: IMDG: IATA:

třída 3, kód: F1 Class 3, Code Class 3

14.4 Obalová skupina ADR/RID, IMDG, IATA:

I

14.5 Nebezpečnost pro životní prostředí Marine Pollutant

Yes

14.6 Zvláštní bezpečnostní opatření pro uživatele Pozemní přeprava (ADR/RID) Výstražná tabule: ADR/RID: Poplachové číslo 33, Číslo OSN 1268 Výstražná nálepka 3 Omezená množství 500 mL EQ E3 Obal: Pokyny P001 Zvláštní předpisy pro společné balení MP7 MP17 Pojízdné cisterny: Pokyny T11 Pojízdné cisterny: Zvláštní předpisy TP1 TP8 Kódování nádrží L4BN Kód omezení vjezdu do tunelu: D/E





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Doprava po moři (IMDG) EmS: Zvláštní předpisy Omezená množství EQ Obal: Pokyny Obal: Předpisy IBC: Pokyny IBC: Předpisy Pokyny pro tankování: IMO Pokyny pro tankování: UN Pokyny pro tankování Předpisy Stowage and segregation Properties and observations

F-E, S-E 500 mL E3 P001 T11 TP1, TP8 Category E. Immiscible with water.

Letecká přeprava (IATA) Flamm. liquid E3 Forbidden Pack.Instr. 351 - Max.Qty. 1 L Pack.Instr. 361 - Max.Qty. 30 L A3 3H

Hazard EQ Passenger Ltd.Qty.: Passenger: Cargo: Special Provisioning ERG

14.7 Hromadná přeprava podle přílohy II MARPOL73/78 a předpisu IBC Žádná příkazová data

ODDÍL 15: Informace o předpisech 15.1 Nařízení týkající se bezpečnosti, zdraví a životního prostředí/specifické právní předpisy týkající se látky nebo směsi Národní předpisy - Německo Třída skladování VCI: 3 = Zápalné kapalné látky Třída ohrožení vody: 3 = silně ohrožující vody Nařízení v případě poruchy:

dodatek I, Seznam látek Nr. 8 Pokyny k omezení práce:

Dodržujte pracovní omezení pro nezletilé. Dodržujte pracovní omezení pro nastávající a kojící matky. Další předpisy, omezení a nařízení:

Nikdy nepoužívejte k čistícím účelům. Národní předpisy - Švýcarsko Obsahuje prchavé ogranické látky (VOC):

743 g/L Národní předpisy - Velká Británie Hazchemův kód: 3YE Národní předpisy - ES- členský stát Obsahuje prchavé ogranické látky (VOC):

100 hm. %





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Národní předpisy - USA Systém hodnocení nebezpečí

4 3

0

NFPA Hazard Rating: Health: 3 (Serious) Fire: 4 (Severe) Reactivity: 0 (Minimal) HMIS Version III Rating: Health: 3 (Serious) - Chronic effects Flammability: 4 (Severe) Physical Hazard: 0 (Minimal) Personal Protection: X = Consult your supervisor

HEALTH

*

3

FLAMMABILITY

4

PHYSICAL HAZARD

0 X

15.2 Posouzení chemické bezpečnosti Hodnocení neporušenosti látek bude provedeno na látkach.

ODDÍL 16: Další informace Další informace důvod posledních změn: Změna v odstavci 1: Nouzové číslo volání Literatura: CONCAWE (Madouplein 1, B-1030 Brussels, Belgium): - CSR Low Boiling Point Naphthas (Gasoline) 06/2010 - Dossier 'Liquified Petroleum Gas', 92/102 - Report 01/54 (Environmental Classification of Petroleum Substances Summary data and Rationale) - Report 01/53 (Classification and of Labelling of Petroleum Substances Directive) - CONCAWE Dossier 'Liquified Petroleum Gas', 92/102 (Madouplein 1, B-1030 Brussels, Belgium) - CONCAWE Report 01/54 (Environmental Classification of Petroleum Substances - Summary data and Rationale) - CONCAWE Report 01/53 (Classification and of Labelling of Petroleum Substances Directive) Datový list zobrazené oblasti Kontaktní osoba: viz kapitola 1, informativní část. Údaje v tomto datovém listu jsou sestaveny dle nejlepšího vědomí a na základě znalostí odpovídajících dat zpracování. Nezajišťují však záruku určitých vlastností ve smyslu právní závaznosti.



Anhang

Section 1 Exposure Scenario Title Title: Manufacture of substance Use Descriptor Sector(s) of Use Process Categories

SU3, SU8, SU9 PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b ERC1, ERC4 ESVOC 1.1.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Manufacture of the substance or use as an intermediate, process chemical or extracting agent. Includes recycling/ recovery, material transfers, storage, maintenance and loading (ncluding marine vessel/barge, road/rail car and bulk container). Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC1 Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC1 Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. General exposures (closed systems) PROC1 Handle substance within a closed system. General exposures (closed systems) PROC2 Wear suitable gloves tested to EN374. Sample via a closed loop or other system to avoid exposure. Handle substance within a closed system. General exposures (closed systems) PROC3 Seite 1 von 21

Ensure operation is undertaken outdoors. Handle substance within a closed system. Laboratory activities PROC15 Handle in a fume cupboard or under extract ventilation. Bulk transfers (closed systems) PROC8b Ensure material transfers are under containment or extract ventilation. Equipment cleaning and maintenance PROC8a Drain down and flush system prior to equipment break-in or maintenance. Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC2 Ensure operation is undertaken outdoors. Store substance within a closed system. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 600000 tons/yr Continuous release. Emission Days (days/year): 300 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 0.03 Maximum daily site tonnage (kg/d): 2000000 kg / day Regional use tonnage (tonnes/year): 18700000 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.05 Release fraction to soil from process (regional only): 0.0001 Release fraction to wastewater from process: 0.003 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: 80.4 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: 99 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of =: 95.2 % Organisation measures to prevent/limit release from site Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 10000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 2000000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 99.1 % Seite 2 von 21

Conditions and measures related to external treatment of waste for disposal During manufacturing no waste of the substance is generated [ETW4] Conditions and measures related to external recovery of waste During manufacturing no waste of the substance is generated [ERW2]

Seite 3 von 21

Section 3 Exposure Estimation 3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination. Section 1 Exposure Scenario Title Title: Distribution of substance Use Descriptor Sector(s) of Use Process Categories

SU3, SU8, SU9 PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b ERC1, ERC2 ESVOC 1.1b.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Loading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) of substance, including its sampling, storage, unloading, distribution and associated laboratory activities. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Assumes use at not more than 20°C above ambient tem perature[G15] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC1 Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC1 Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems Seite 4 von 21

of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. General exposures (closed systems) PROC1 Handle substance within a closed system. Process sampling PROC3 Sample via a closed loop or other system to avoid exposure. Laboratory activities PROC15 Handle in a fume cupboard or under extract ventilation. Bulk transfers (closed systems) PROC8b Ensure material transfers are under containment or extract ventilation. Bulk transfers (open systems) PROC8b Ensure material transfers are under containment or extract ventilation. Equipment cleaning and maintenance PROC8a Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. Drain down and flush system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC2 Ensure operation is undertaken outdoors. Store substance within a closed system. General exposures (closed systems) with sample collection PROC2 Wear suitable gloves tested to EN374. Handle substance within a closed system. Sample via a closed loop or other system to avoid exposure. General exposures (closed systems) Outdoor. PROC3 Handle substance within a closed system. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 37500 tons/yr Continuous release. Emission Days (days/year): 300 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 0.002 Maximum daily site tonnage (kg/d): 120000 kg / day Regional use tonnage (tonnes/year): 18700000 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.001 Release fraction to soil from process (regional only): 1e-005 Release fraction to wastewater from process: 1e-005 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: 90 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) Seite 5 von 21

efficiency of =: >= 12 % Organisation measures to prevent/limit release from site Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 1100000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3] Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1] Section 3 Exposure Estimation 3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.

Seite 6 von 21

Section 1 Exposure Scenario Title Title: Formulation and (re)packing of substances and mixtures Use Descriptor Sector(s) of Use Process Categories

SU10 PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b ERC2 ESVOC 2.2.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Formulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage, materials transfers, mixing, tabletting, compression, pelletisation, extrusion, large and small scale packing, sampling, maintenanance and associated laboratory activities. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Assumes use at not more than 20°C above ambient tem perature[G15] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC1 Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC1 Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. General exposures (closed systems) PROC1 Handle substance within a closed system. General exposures (closed systems) PROC2 Wear suitable gloves tested to EN374. Handle substance within a closed system. Sample via a closed loop or other system to avoid exposure. General exposures (closed systems) PROC3 Handle substance within a closed system. Process sampling PROC3 Sample via a closed loop or other system to avoid exposure. Laboratory activities PROC15 Handle in a fume cupboard or under extract ventilation. Bulk transfers PROC8b Seite 7 von 21

Ensure material transfers are under containment or extract ventilation. Drum/batch transfers PROC8b Ensure material transfers are under containment or extract ventilation. Equipment cleaning and maintenance PROC8a Drain down and flush system prior to equipment break-in or maintenance. Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC2 Wear suitable gloves tested to EN374. Store substance within a closed system. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 30000 tons/yr Continuous release. Emission Days (days/year): 300 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 0.0018 Maximum daily site tonnage (kg/d): 100000 kg / day Regional use tonnage (tonnes/year): 16500000 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.025 Release fraction to soil from process (regional only): 0.0001 Release fraction to wastewater from process: 0.002 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: 0 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: 56.5 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of =: 94.7 % Organisation measures to prevent/limit release from site Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 100000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations Seite 8 von 21

[ETW3] Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1] Section 3 Exposure Estimation 3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.

Section 1 Exposure Scenario Title Title: Use in Coatings - Industrial Use Descriptor Sector(s) of Use Process Categories

SU3 PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b ERC4 ESVOC 4.3a.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including materials receipt, storage, preparation and transfer from bulk and semi-bulk, application by spray, roller, spreader, dip, flow, fluidised bed on production lines and film formation) and equipment cleaning, maintenance and associated laboratory activities. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Assumes use at not more than 20°C above ambient tem perature[G15] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC2 Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC2 Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local Seite 9 von 21

exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. Film formation - force drying (50-100°C). stoving (>100°C). UV/EB radiation curing PROC2 Provide extract ventilation to points where emissions occur. General exposures (closed systems) PROC3 provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Handle substance within a closed system. Material transfers PROC8b Ensure material transfers are under containment or extract ventilation. Laboratory activities PROC15 Handle in a fume cupboard or under extract ventilation. Equipment cleaning and maintenance PROC8a Drain down and flush system prior to equipment break-in or maintenance. Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC1 Store substance within a closed system. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 6200 tons/yr Continuous release. Emission Days (days/year): 300 Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 1 Maximum daily site tonnage (kg/d): 21000 kg / day Regional use tonnage (tonnes/year): 6200 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.98 Release fraction to soil from process (regional only): 0 Release fraction to wastewater from process: 0.007 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: 0 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: 94.1 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of =: 92.6 % Organisation measures to prevent/limit release from site Seite 10 von 21

Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 21000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3] Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1] Section 3 Exposure Estimation 3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.

Section 1 Exposure Scenario Title Title: Use as a fuel - Industrial Use Descriptor Sector(s) of Use Process Categories

SU3 PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b ERC7, ERC8B ESVOC 7.12a.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Covers the use as a fuel (or fuel additive), and includes activities associated with its transfer, use, equipment maintenance and handling of waste. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Seite 11 von 21

Assumes use at not more than 20°C above ambient tem perature[G15] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC8b Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC8b Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. Bulk transfers (closed systems) PROC8b Ensure material transfers are under containment or extract ventilation. Drum/batch transfers PROC8b Ensure material transfers are under containment or extract ventilation. General exposures (closed systems) Use in contained batch processes Outdoor. PROC3 Handle substance within a closed system. General exposures (closed systems) PROC1 Handle substance within a closed system. General exposures (closed systems) PROC2 Wear suitable gloves tested to EN374. Handle substance within a closed system. Equipment cleaning and maintenance PROC8a Drain down system prior to equipment break-in or maintenance. provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC2 provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Store substance within a closed system. Use as a fuel (closed systems) PROC16 Handle substance within a closed system. refuelling PROC8b Ensure material transfers are under containment or extract ventilation. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 1400000 tons/yr Continuous release. Emission Days (days/year): 300 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 1 Maximum daily site tonnage (kg/d): 4600000 kg / day Seite 12 von 21

Regional use tonnage (tonnes/year): 1400000 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.0025 Release fraction to soil from process (regional only): 0 Release fraction to wastewater from process: 1e-005 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: 99.4 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of =: >= 76.9 % Organisation measures to prevent/limit release from site Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 4600000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 % Conditions and measures related to external treatment of waste for disposal Combustion emissions considered in regional exposure assessment [ETW2] Combustion emissions limited by required exhaust emission controls [ETW1] Conditions and measures related to external recovery of waste This substance is consumed during use and no waste of the substance is generated [ERW3] Section 3 Exposure Estimation 3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.

Section 1 Exposure Scenario Title Title: Rubber production and processing Use Descriptor

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Sector(s) of Use Process Categories

SU10, SU3 PROC1, PROC15, PROC2, PROC3, PROC8a, PROC8b, PROC9 ERC7 ESVOC 4.19.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Manufacture of tyres and general rubber articles, including processing of raw (uncured) rubber, handling and mixing of rubber additives, vulcanising, cooling and finishing. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC2 Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC2 Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. Material transfers (closed systems) PROC2 Ensure material transfers are under containment or extract ventilation. Store substance within a closed system. Material transfers PROC8b Ensure material transfers are under containment or extract ventilation. Bulk weighing PROC2 Wear suitable gloves tested to EN374. Handle substance within a closed system. Laboratory activities PROC15 Handle in a fume cupboard or under extract ventilation. Equipment maintenance PROC8a Drain down system prior to equipment break-in or maintenance. provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Wear chemically resistant gloves (tested to EN374) in combination with 'basic' employee training. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC2 Store substance within a closed system. provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Seite 14 von 21

General exposures (closed systems) PROC1 Handle substance within a closed system. General exposures (closed systems) Outdoor. PROC3 Handle substance within a closed system. Small scale weighing PROC9 Carry out in a vented booth or extracted enclosure. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 94 tons/yr Continuous release. Emission Days (days/year): 20 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 1 Maximum daily site tonnage (kg/d): 4700 kg / day Regional use tonnage (tonnes/year): 94 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.003 Release fraction to soil from process (regional only): 0.0001 Release fraction to wastewater from process: 0.01 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: 0 % Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of =: >= 23.9 % Organisation measures to prevent/limit release from site Do not apply industrial sludge to natural soils. Prevent discharge of undissolved substance to or recover from wastewater. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 42000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is =: 95.5 % Conditions and measures related to external treatment of waste for disposal External treatment and disposal of waste should comply with applicable local and/or national regulations [ETW3] Conditions and measures related to external recovery of waste External recovery an recycling of waste should comply with applicable local and/or national regulations [ERW1] Section 3 Exposure Estimation Seite 15 von 21

3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.

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Section 1 Exposure Scenario Title Title: Use as a fuel - Professional Use Descriptor Sector(s) of Use Process Categories

SU22 PROC1, PROC16, PROC2, PROC3, PROC8a, PROC8b ERC8B, ERC8E, ERC9A, ERC9B ESVOC 9.12b.v1

Environmental Release Categories Specific Environmental Release Category Processes, tasks, activities covered Covers the use as a fuel (or fuel additive), and includes activities associated with its transfer, use, equipment maintenance and handling of waste. Section 2 Operational conditions and risk management measures Section 2.1 Control of worker exposure Product Characteristic Liquid Duration, frequency and amount Covers daily exposures up to 8 hours (unless stated differently)[G2] Covers percentage substance in the product up to 100 %[G13 ] Other given operational conditions affecting workers exposure Assumes a good basic standard of occupational hygiene is implemented [G1] Assumes use at not more than 20°C above ambient tem perature[G15] Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) General measures (skin irritants) PROC8b Avoid direct skin contact with product. Identify potential areas for indirect skin contact. Wear gloves (tested to EN374) if hand contact with substance likely. Clean up contamination/spills as soon as they occur. wash off any skin contamination immediately. provide basic employee training to prevent / minimise exposures and to report any skin problems that may develop. General measures (carcinogens) PROC8b Consider technical advances and process upgrades (including automation) for the elimination of releases. minimise exposure using measures such as closed systems, dedicated facilities and suitable general/local exhaust ventilation. Drain down systems and clear transfer lines prior to breaking containment. Clean/flush equipment, where possible, prior to maintenance Where there is potential for exposure: restrict access to authorised persons; provide specific activity training to operators to minimise exposures; wear suitable gloves and coveralls to prevent skin contamination; wear respiratory protection when its use is identified for certain contributing scenario; clear up spills immediately and dispose of wastes safely. Ensure safe systems of work or equivalent arrangements are in place to manage risks. Regularly inspect, test and maintain all control measures. Consider the need for risk based health surveillance. Drum/batch transfers PROC8b Ensure material transfers are under containment or extract ventilation. General exposures (closed systems) PROC1 Handle substance within a closed system. General exposures (closed systems) PROC2 Wear suitable gloves tested to EN374. Handle substance within a closed system. General exposures (closed systems) PROC3 Handle substance within a closed system. Use as a fuel (closed systems) PROC16 Handle substance within a closed system. refuelling PROC8b Ensure material transfers are under containment or extract ventilation. Equipment maintenance PROC8a Seite 17 von 21

Drain down system prior to equipment break-in or maintenance. provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Ensure operatives are trained to minimise exposures. Wear chemically resistant gloves (tested to EN374) in combination with intensive management supervision controls. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Clear spills immediately. Storage PROC2 provide a good standard of general ventilation Natural ventilation is from doors, windows etc. Controlled ventilation means air is supplied or removed by a powered fan. Store substance within a closed system. Bulk transfers (closed systems) PROC8b Ensure material transfers are under containment or extract ventilation. Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 590 tons/yr Continuous release. Emission Days (days/year): 365 Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 0.0005 Maximum daily site tonnage (kg/d): 1600 Regional use tonnage (tonnes/year): 1190000 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.01 Release fraction to soil from process (regional only): 1e-005 Release fraction to wastewater from process: 1e-005 Technical conditions and measures at process level (source) to prevent release Common practices vary across sites thus conservative process release estimates used. Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil If discharging to domestic sewage treatment plant, no onsite wastewater treatment required. If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of =: >= 0 % Risk from environmental exposure is driven by humans via indirect exposure (primarily inhalation). Treat air emissions to provide a typical removal (or abatement?) efficiency of: Not Applicable Treat onsite wastewater (prior to receiving water discharge) to provide the required removal (or abatement) efficiency of =: >= 3.4 % Organisation measures to prevent/limit release from site Do not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed. Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 15000 kg / day Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs is: 95.5 % Seite 18 von 21

Conditions and measures related to external treatment of waste for disposal Combustion emissions considered in regional exposure assessment [ETW2] Combustion emissions limited by required exhaust emission controls [ETW1] Conditions and measures related to external recovery of waste This substance is consumed during use and no waste of the substance is generated [ERW3] Section 3 Exposure Estimation 3.1. Health The ECETOC TRA tool has been used to estimate workplace exposures unless otherwise indicated [G21] 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario 4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.

Section 1 Exposure Scenario Title Title: Use as a fuel - Consumer Use Descriptor Sector(s) of Use SU21 Product Categories PC13 Environmental Release Categories ERC8B Specific Environmental Release Category ESVOC 9.12c.v1 Processes, tasks, activities covered Covers consumer uses in liquid fuels. Section 2 Operational conditions and risk management measures Section 2.1 Control of consumer exposure Product Characteristic Liquid Duration, frequency and amount Covers concentrations up to 1 % Covers daily use up to 1 times per day Other given operational conditions affecting consumer exposure Covers use at ambient temperatures. Contributing Scenarios/Specific Risk Management Measures and Operating Conditions (only required controls to demonstrate safe use listed) Liquid: Automotive Refuelling PC13 Covers annual use up to 52 days/yr Covers skin contact area up to 210 cm2 For each use event, covers use amounts up to 37500 grams Covers outdoor use. 0.6 Air changes per hour Covers use in room size of 100 m³ Covers exposure up to 0.05 hour(s) Liquid Scooter Refuelling PC13 Covers annual use up to 52 days/yr Covers skin contact area up to 210 cm2 Seite 19 von 21

For each use event, covers use amounts up to 3750 grams Covers outdoor use. 0.6 Air changes per hour Covers use in room size of 100 m³ Covers exposure up to 0.03 hour(s) Liquid, Garden Equipment - Use PC13 Covers annual use up to 26 days/yr For each use event, covers use amounts up to 750 grams Covers outdoor use. 0.6 Air changes per hour Covers use in room size of 100 m³ Covers exposure up to 2 hour(s) Covers skin contact area up to 420 cm2 Liquid: Garden Equipment - Refueling PC13 Covers annual use up to 26 days/yr Covers skin contact area up to 420 cm2 For each use event, covers use amounts up to 750 grams Covers use in a one car garage (34 m3) under typical ventilation. 1.5 Air changes per hour Covers use in room size of 34 m³ Covers exposure up to 0.03 hour(s) Section 2.2 Control of environmental exposure Product characteristics Predominantly hydrophobic. Substance is complex UVCB. Duration, frequency and amount Annual site tonnage (tonnes/year): 7000 tons/yr Continuous release. Emission Days (days/year): 365 days/yr Fraction of EU tonnage used in region: 0.1 Fraction of Regional tonnage used Locally: 0.0005 Maximum daily site tonnage (kg/d): 19000 kg / day Regional use tonnage (tonnes/year): 13900000 tons/yr Environmental factors not influenced by risk management Local freshwater dilution factor [EF1] 10 Local marine water dilution factor: [EF2] 100 Other given operational conditions affecting environmental exposure Release fraction to air from process: 0.01 Release fraction to soil from process (regional only): 1e-005 Release fraction to wastewater from process: 1e-005 Conditions and measures related to municipal sewage treatment plant Assumed domestic sewage treatment plant effluent flow is:[STP5] 2000 m3/day Estimated substance removal from wastewater via domestic sewage treatment is: 95.5 % The maximum allowable site tonnage (MSafe) based on domestic sewage plant effluent release is: 180000 kg / day Conditions and measures related to external treatment of waste for disposal Combustion emissions considered in regional exposure assessment [ETW2] Combustion emissions limited by required exhaust emission controls [ETW1] Conditions and measures related to external recovery of waste This substance is consumed during use and no waste of the substance is generated [ERW3] Section 3 Exposure Estimation 3.1. Health Not applicable 3.2. Environment The Hydrocarbon Block Method has been used to calculate environmental exposrue with the Petrorisk model.[EE2] Section 4 Guidance to check compliance with the Exposure Scenario Seite 20 von 21

4.1. Health Where other Risk Management Measures/Operational Conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] 4.2. Environment Maximum Risk Characterisation Ratio for Wastewater Emisions [RCRwater] 0.039321

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